Abstract: As a by-product of the biodiesel industries, glycerol
has been vastly generated which surpasses the market demand. It is
imperative to develop an efficient glycerol valorization processes in
minimizing the net energy requirement and intensifying the biodiesel
production. In this study, base-catalyzed transesterification of
glycerol with dimethyl carbonate using microwave irradiation as
heating method to produce glycerol carbonate was conducted by
varying grades of glycerol, i.e. 70%, 86% and 99% purity, that is
obtained from biodiesel plant. Metal oxide catalysts were used with
varying operating parameters including reaction time, DMC/glycerol
molar ratio, catalyst weight %, temperature and stirring speed. From
the study on the effect of different operating parameters it was found
that the type of catalyst used has the most significant effect on the
transesterification reaction. Amidst the metal oxide catalysts
examined, CaO gave the best performance. This study indicates the
feasibility of producing glycerol carbonate using different grade of
glycerol in both conventional thermal activation and microwave
irradiation with CaO as catalyst. Microwave assisted
transesterification (MAT) of glycerol into glycerol carbonate has
demonstrated itself as an energy efficient route by achieving 94.2%
yield of GC at 65°C, 5 minutes reaction time, 1 wt% CaO and
DMC/glycerol molar ratio of 2. The advantages of MAT
transesterification route has made the direct utilization of bioglycerol
from biodiesel production without the need of purification. This has
marked a more economical and less-energy intensive glycerol
carbonate synthesis route.
Abstract: Graphene was dispersed using a tip sonicator and the
effect of surfactants were analysed. Sodium Dodecyl Sulphate (SDS)
and Polyvinyl Alcohol (PVA) were compared to observe whether or
not they had any effect on any de-wrinkling, and secondly whether
they aided to achieve better dispersions. There is a huge demand for
wrinkle free graphene as this will greatly increase its usefulness in
various engineering applications. A comprehensive literature on dewrinkling
graphene has been discussed. Low magnification Scanning
Electronic Microscopy (SEM) was conducted to assess the quality of
graphene de-wrinkling. The utilization of the PVA has significant
effect on de-wrinkling whereas SDS had minimal effect on the dewrinkling
of graphene.
Abstract: Consumers are demanding novel beverages that are
healthier, convenient and have appealing consumer acceptance. The
objectives of this study were to investigate the effects of adding grape
polyphenols and the influence of presenting health claims on the
sensory acceptability of wines. Fresh red sorrel calyces were
fermented into wines. The total soluble solids of the pectinase-treated
sorrel puree were from 4°Brix to 23.8°Brix. Polyphenol in the form
of grape pomace extract was added to sorrel wines (w/v) in specified
levels to give 0. 25. 50 and 75 ppm. A focus group comprising of 12
panelists was use to select the level of polyphenol to be added to
sorrel wines for sensory preference The sensory attributed of the
wines which were evaluated were colour, clarity, aroma, flavor,
mouth-feel, sweetness, astringency and overall preference. The sorrel
wine which was most preferred from focus group evaluation was
presented for hedonic rating. In the first stage of hedonic testing, the
sorrel wine was served chilled at 7°C for 24 h prior to sensory
evaluation. Each panelist was provided with a questionnaire and was
asked to rate the wines on colour, aroma, flavor, mouth-feel,
sweetness, astringency and overall acceptability using a 9-point
hedonic scale. In the second stage of hedonic testing, the panelist
were instructed to read a health abstract on the health benefits of
polyphenolic compounds and again to rate sorrel wine with added 25
ppm polyphenol. Paired t-test was used for the analysis of the
influence of presenting health information on polyphenols on hedonic
scoring of sorrel wines. Focus groups found that the addition of
polyphenol addition had no significant effect on sensory color and
aroma but affected clarity and flavor. A 25 ppm wine was liked
moderately in overall acceptability. The presentation of information
on the health benefit of polyphenols in sorrel wines to panelists had
no significant influence on the sensory acceptance of wine. More
than half of panelists would drink this wine now and then. This wine
had color L 19.86±0.68, chroma 2.10±0.12, hue° 16.90 ±3.10 and
alcohol content of 13.0%. The sorrel wine was liked moderately in
overall acceptability with the added polyphenols.
Abstract: The global demand for long-tailed macaques for
medical experimentation has continued to increase. Fulfillment of
Indonesian export demands has been mostly from natural habitats,
based on a harvesting quota. This quota has been determined
according to the total catch for a given year, and not based on
consideration of any demographic parameters or physical
environmental factors with regard to the animal; hence threatening
the sustainability of the various populations. It is therefore necessary
to formulate a method for calculating a sustainable harvesting quota,
based on population parameters in natural habitats. Considering the
possibility of variations in habitat characteristics and population
parameters, a time series observation of demographic and
physical/biotic parameters, in various habitats, was performed on 13
groups of long-tailed macaques, distributed throughout the West
Java, Lampung and Yogyakarta areas of Indonesia. These provinces
were selected for comparison of the influence of human/tourism
activities. Data on population parameters that was collected included
data on life expectancy according to age class, numbers of
individuals by sex and age class, and ‘ratio of infants to reproductive
females’. The estimation of population growth was based on a
population dynamic growth model: the Leslie matrix. The harvesting
quota was calculated as being the difference between the actual
population size and the MVP (minimum viable population) for each
sex and age class. Observation indicated that there were variations within group size
(24–106 individuals), gender (sex) ratio (1:1 to 1:1.3), life expectancy
value (0.30 to 0.93), and ‘ratio of infants to reproductive females’
(0.23 to 1.56). Results of subsequent calculations showed that
sustainable harvesting quotas for each studied group of long-tailed
macaques, ranged from 29 to 110 individuals. An estimation model
of the MVP for each age class was formulated as Log Y = 0.315 +
0.884 Log Ni (number of individual on ith age class). This study also
found that life expectancy for the juvenile age class was affected by
the humidity under tree stands, and dietary plants’ density at sapling,
pole and tree stages (equation: Y=2.296 – 1.535 RH + 0.002 Kpcg –
0.002 Ktg – 0.001 Kphn, R2 = 89.6% with a significance value of
0.001). By contrast, for the sub-adult-adult age class, life expectancy
was significantly affected by slope (equation: Y=0.377 = 0.012 Kml,
R2 = 50.4%, with significance level of 0.007). The infant-toreproductive-
female ratio was affected by humidity under tree stands,
and dietary plant density at sapling and pole stages (equation: Y = -
1.432 + 2.172 RH – 0.004 Kpcg + 0.003 Ktg, R2 = 82.0% with
significance level of 0.001). This research confirmed the importance
of population parameters in determining the minimum viable
population, and that MVP varied according to habitat characteristics
(especially food availability). It would be difficult therefore, to
formulate a general mathematical equation model for determining a
harvesting quota for the species as a whole.
Abstract: Indonesia has experienced annual forest fires that have
rapidly destroyed and degraded its forests. Fires in the peat swamp
forests of Riau Province, have set the stage for problems to worsen,
this being the ecosystem most prone to fires (which are also the most
difficult, to extinguish). Despite various efforts to curb deforestation,
and forest degradation processes, severe forest fires are still
occurring. To find an effective solution, the basic causes of the
problems must be identified. It is therefore critical to have an indepth
understanding of the underlying causal factors that have
contributed to deforestation and forest degradation as a whole, in
order to attain reductions in their rates. An assessment of the drivers of deforestation and forest
degradation was carried out, in order to design and implement
measures that could slow these destructive processes. Research was
conducted in Giam Siak Kecil–Bukit Batu Biosphere Reserve
(GSKBB BR), in the Riau Province of Sumatera, Indonesia. A
biosphere reserve was selected as the study site because such reserves
aim to reconcile conservation with sustainable development. A
biosphere reserve should promote a range of local human activities,
together with development values that are in line spatially and
economically with the area conservation values, through use of a
zoning system. Moreover, GSKBB BR is an area with vast peatlands,
and is experiencing forest fires annually. Various factors were
analysed to assess the drivers of deforestation and forest degradation
in GSKBB BR; data were collected from focus group discussions
with stakeholders, key informant interviews with key stakeholders,
field observation and a literature review. Landsat satellite imagery was used to map forest-cover changes
for various periods. Analysis of landsat images, taken during the
period 2010-2014, revealed that within the non-protected area of core
zone, there was a trend towards decreasing peat swamp forest areas,
increasing land clearance, and increasing areas of community oilpalm
and rubber plantations. Fire was used for land clearing and most
of the forest fires occurred in the most populous area (the transition
area). The study found a relationship between the deforested/
degraded areas, and certain distance variables, i.e. distance from
roads, villages and the borders between the core area and the buffer
zone. The further the distance from the core area of the reserve, the
higher was the degree of deforestation and forest degradation. Research findings suggested that agricultural expansion may be
the direct cause of deforestation and forest degradation in the reserve,
whereas socio-economic factors were the underlying driver of forest
cover changes; such factors consisting of a combination of sociocultural,
infrastructural, technological, institutional (policy and governance), demographic (population pressure) and economic
(market demand) considerations. These findings indicated that local
factors/problems were the critical causes of deforestation and
degradation in GSKBB BR. This research therefore concluded that
reductions in deforestation and forest degradation in GSKBB BR
could be achieved through ‘local actor’-tailored approaches such as
community empowerment.
Abstract: This paper is concerned with the single-item
continuous review inventory system in which demand is stochastic
and discrete. The budget consumed for purchasing the ordered items
is not restricted but it incurs extra cost when exceeding specific
value. The unit purchasing price depends on the quantity ordered
under the all-units discounts cost structure. In many actual systems,
the budget as a resource which is occupied by the purchased items is
limited and the system is able to confront the resource shortage by
charging more costs. Thus, considering the resource shortage costs as
a part of system costs, especially when the amount of resource
occupied by the purchased item is influenced by quantity discounts,
is well motivated by practical concerns. In this paper, an optimization
problem is formulated for finding the optimal (r, Q) policy, when the
system is influenced by the budget limitation and a discount pricing
simultaneously. Properties of the cost function are investigated and
then an algorithm based on a one-dimensional search procedure is
proposed for finding an optimal (r, Q) policy which minimizes the
expected system costs.
Abstract: Industries produce millions of cubic meters of effluent
every year and the wastewater produced may be released into the
surrounding water bodies, treated on-site or at municipal treatment
plants. The determination of organic matter in the wastewater
generated is very important to avoid any negative effect on the
aquatic ecosystem. The scope of the present work is to assess the
physicochemical composition of the wastewater produced from one
of the brewery industry in South Africa. This is to estimate the
environmental impact of its discharge into the receiving water bodies
or the municipal treatment plant. The parameters monitored for the
quantitative analysis of brewery wastewater include biological
oxygen demand (BOD5), chemical oxygen demand (COD), total
suspended solids, volatile suspended solids, ammonia, total oxidized
nitrogen, nitrate, nitrite, phosphorus and alkalinity content. In
average, the COD concentration of the brewery effluent was 5340.97
mg/l with average pH values of 4.0 to 6.7. The BOD5 and the solids
content of the wastewater from the brewery industry were high. This
means that the effluent is very rich in organic content and its
discharge into the water bodies or the municipal treatment plant could
cause environmental pollution or damage the treatment plant. In
addition, there were variations in the wastewater composition
throughout the monitoring period. This might be as a result of
different activities that take place during the production process, as
well as the effects of peak period of beer production on the water
usage.
Abstract: Efficient use of energy, the increase in demand of
energy and also with the reduction of natural energy sources, has
improved its importance in recent years. Most of the losses in the
system from electricity produced until the point of consumption is
mostly composed by the energy distribution system. In this study,
analysis of the resulting loss in power distribution transformer and
distribution power cable is realized which are most of the losses in
the distribution system. Transformer losses in the real distribution
system are analyzed by CYME Power Engineering Software
program. These losses are disclosed for different voltage levels and
different loading conditions.
Abstract: This paper applied factor conditions from Porter’s
Diamond Model (1990) to understand the various challenges facing
the AMISA. Factor conditions highlighted in Porter’s model are
grouped into two groups namely, basic and advance factors. Two
AMISA associations representing over 10 000 employees were
interviewed. The largest Clothing, Textiles and Leather (CTL)
apparel retail group was also interviewed with a government
department implementing the industrialization policy were
interviewed. The paper points out that AMISA have basic factor conditions
necessary for competitive advantage in the apparel industries.
However advance factor creation has proven to be a challenge for
AMISA, Higher Education Institutions (HEIs) and government. Poor
infrastructural maintenance has contributed to high manufacturing
costs and poor quick response technologies. The use of Porter’s
Factor Conditions as a tool to analyze the sector’s competitive
advantage challenges and opportunities has increased knowledge
regarding factors that limit the AMISA’s competitiveness. It is
therefore argued that other studies on Porter’s Diamond model
factors like Demand conditions, Firm strategy, structure and rivalry
and Related and supporting industries can be used to analyze the
situation of the AMISA for the purposes of improving competitive
advantage.
Abstract: The objective of the study is to assess the
implementation of LED lighting into forest machine work in the dark.
In addition, the paper includes a wide variety of important and
relevant safety and health parameters. In modern, computerized work
in the cab of forest machines, artificial illumination is a demanding
task when performing duties, such as the visual inspections of wood
and computer calculations. We interviewed entrepreneurs and
gathered the following as the most pertinent themes: (1) safety, (2)
practical problems, and (3) work with LED lighting. The most
important comments were in regards to the practical problems of
LED lighting. We found indications of technical problems in
implementing LED lighting, like snow and dirt on the surfaces of
lamps that dim the emission of light. Moreover, service work in the
dark forest is dangerous and increases the risks of on-site accidents.
We also concluded that the amount of blue light to the eyes should be
assessed, especially, when the drivers are working in a semi-dark cab.
Abstract: The design of Reverse logistics Network has attracted
growing attention with the stringent pressures from both
environmental awareness and business sustainability. Reverse
logistical activities include return, remanufacture, disassemble and
dispose of products can be quite complex to manage. In addition,
demand can be difficult to predict, and decision making is one of the
challenges task in such network. This complexity has amplified the
need to develop an integrated architecture for product return as an
enterprise system. The main purpose of this paper is to design Multi
Agent System (MAS) architecture using the Prometheus
methodology to efficiently manage reverse logistics processes. The
proposed MAS architecture includes five types of agents: Gate
keeping Agent, Collection Agent, Sorting Agent, Processing Agent
and Disposal Agent which act respectively during the five steps of
reverse logistics Network.
Abstract: Mobile Adhoc Networks (MANETs) are
infrastructure-less, dynamic network of collections of wireless mobile
nodes communicating with each other without any centralized
authority. A MANET is a mobile device of interconnections through
wireless links, forming a dynamic topology. Routing protocols have a
big role in data transmission across a network. Routing protocols,
two major classifications are unipath and multipath. This study
evaluates performance of an on-demand multipath routing protocol
named Adhoc On-demand Multipath Distance Vector routing
(AOMDV). This study proposes Energy Aware AOMDV (EAAOMDV)
an extension of AOMDV which decreases energy
consumed on a route.
Abstract: The current paper presents an extensive bottom-up
framework for assessing building sector-specific vulnerability to
climate change: energy supply and demand. The research focuses on
the application of downscaled seasonal models for estimating energy
performance of buildings in Greece. The ARW-WRF model has
been set-up and suitably parameterized to produce downscaled
climatological fields for Greece, forced by the output of the CFSv2
model. The outer domain, D01/Europe, included 345 x 345 cells of
horizontal resolution 20 x 20 km2 and the inner domain, D02/Greece,
comprised 180 x 180 cells of 5 x 5 km2 horizontal resolution. The
model run has been setup for a period with a forecast horizon of 6
months, storing outputs on a six hourly basis.
Abstract: Distillery spentwash contains high chemical oxygen
demand (COD), biological oxygen demand (BOD), color, total
dissolved solids (TDS) and other contaminants even after biological
treatment. The effluent can’t be discharged as such in the surface
water bodies or land without further treatment. Reverse osmosis (RO)
treatment plants have been installed in many of the distilleries at
tertiary level in many of the distilleries in India, but are not properly
working due to fouling problem which is caused by the presence of
high concentration of organic matter and other contaminants in
biologically treated spentwash. In order to make the membrane
treatment a proven and reliable technology, proper pre-treatment is
mandatory. In the present study, ultra-filtration (UF) for pretreatment
of RO at tertiary stage has been performed. Operating
parameters namely initial pH (pHo: 2–10), trans-membrane pressure
(TMP: 4-20 bars) and temperature (T: 15-43°C) were used for
conducting experiments with UF system. Experiments were
optimized at different operating parameters in terms of COD, color,
TDS and TOC removal by using response surface methodology
(RSM) with central composite design. The results showed that
removal of COD, color and TDS was 62%, 93.5% and 75.5%
respectively, with UF, at optimized conditions with increased
permeate flux from 17.5 l/m2/h (RO) to 38 l/m2/h (UF-RO). The
performance of the RO system was greatly improved both in term of
pollutant removal as well as water recovery.
Abstract: Accurate forecasting of fresh produce demand is one
the challenges faced by Small Medium Enterprise (SME)
wholesalers. This paper is an attempt to understand the cause for the
high level of variability such as weather, holidays etc., in demand of
SME wholesalers. Therefore, understanding the significance of
unidentified factors may improve the forecasting accuracy. This
paper presents the current literature on the factors used to predict
demand and the existing forecasting techniques of short shelf life
products. It then investigates a variety of internal and external
possible factors, some of which is not used by other researchers in the
demand prediction process. The results presented in this paper are
further analysed using a number of techniques to minimize noise in
the data. For the analysis past sales data (January 2009 to May 2014)
from a UK based SME wholesaler is used and the results presented
are limited to product ‘Milk’ focused on café’s in derby. The
correlation analysis is done to check the dependencies of variability
factor on the actual demand. Further PCA analysis is done to
understand the significance of factors identified using correlation.
The PCA results suggest that the cloud cover, weather summary and
temperature are the most significant factors that can be used in
forecasting the demand. The correlation of the above three factors
increased relative to monthly and becomes more stable compared to
the weekly and daily demand.
Abstract: The rapid growth of multimedia technology demands
the secure and efficient access to information. This fast growing lose
the confidence of unauthorized duplication. Henceforth the protection
of multimedia content is becoming more important. Watermarking
solves the issue of unlawful copy of advanced data. In this paper,
blind video watermarking technique has been proposed. A luminance
layer of selected frames is interlaced into two even and odd rows of
an image, further it is deinterlaced and equalizes the coefficients of
the two shares. Color watermark is split into different blocks, and the
pieces of block are concealed in one of the share under the wavelet
transform. Stack the two images into a single image by introducing
interlaced even and odd rows in the two shares. Finally, chrominance
bands are concatenated with the watermarked luminance band. The
safeguard level of the secret information is high, and it is
undetectable. Results show that the quality of the video is not
changed also yields the better PSNR values.
Abstract: This paper proposes a linear model for optimizing
domestic energy consumption in Romania. The particularity of the
model is that it is putting in competition both tangible technologies
and thermal insulation projects with different financing modes.
The model is optimizing the energy system by minimizing the
global discounted cost in household sector, by integrating residential
lighting, space heating, hot water, combined space heating – hot
water, as well as space cooling, in a monolithic model. Another
demand sector included is the passenger transport.
This paper focuses on space heating part, analyzing technical and
economic issues related to investment decisions to envelope and
insulate buildings, in order to minimize energy consumption.
Abstract: Aging infrastructures became a serious social problem.
This brought out the increased need for the legislation of a new strict
guideline for infrastructure management. Although existing guidelines
provided basics of how to evaluate and manage the condition of
infrastructures, they needed improvements for their evaluation
procedures. Most guidelines mainly focused on the structural
condition of infrastructures and did not properly reflect service aspects
of infrastructures such as performance, public demand, capacity, etc.,
which were significantly valuable to public. Regardless of the
importance, these factors were often neglected in infrastructure
evaluations, because they were quite subjective and difficult to
quantify in rational manner. Thus, this study proposed a framework to
properly identify and evaluate the service indicators. This study
showed that service indicators could be grouped into two categories
and properly evaluated using AHP and Fuzzy. Overall, proposed
framework is expected to assist governmental agency in establishing
effective investment strategies for infrastructure improvements.
Abstract: Due to the resultant leachate from waste
decomposition in landfills has polluter potential hundred times
greater than domestic sewage, this is considered a problem related to
the depreciation of environment requiring pre-disposal treatment.In
seeking to improve this situation, this project proposes the treatment
of landfill leachate using natural fibers intercropped with advanced
oxidation processes. The selected natural fibers were palm, coconut
and banana fiber.These materials give sustainability to the project
because, besides having adsorbent capacity, are often part of waste
discarded. The study was conducted in laboratory scale.In trials, the
effluents were characterized as Chemical Oxygen Demand (COD),
Turbidity and Color. The results indicate that is technically
promising since that there were extremely oxidative conditions, the
use of certain natural fibers in the reduction of pollutants in leachate
have been obtained results of COD removals between 67.9% and
90.9%, Turbidity between 88.0% and 99.7% and Color between
67.4% and 90.4%.The expectation generated is to continue evaluating
the association of efficiency of other natural fibers with other landfill
leachate treatment processes.
Abstract: Market is an important factor for start-ups to look into
during decision-making in product development and related areas.
Emerging country markets are more uncertain in terms of information
availability and institutional supports. The literature review of market
uncertainty reveals the need for identifying factors representing the
market uncertainty. This paper identifies factors for market
uncertainty using Exploratory Factor Analysis (EFA) and confirmed
the number of factor retention using an alternative factor retention
criterion ‘Parallel Analysis’. 500 entrepreneurs, engaged in start-ups
from all over India participated in the study. This paper concludes
with the factor structure of ‘market uncertainty’ having dimensions of
uncertainty in industry orientation, uncertainty in customer
orientation and uncertainty in marketing orientation.