Abstract: The effect of additional magnesium oxide (MgO) was
investigated by using the tungsten oxide supported on silica catalyst
(WOx/SiO2) physically mixed with MgO in a weight ratio 1:1. The
both fresh and spent catalysts were characterized by FT-Raman
spectrometer, UV-Vis spectrometer, X-Ray diffraction (XRD) and
temperature programmed oxidation (TPO). The results indicated that
the additional MgO could enhance the conversion of trans-2-butene
due to isomerization reaction. However, adding MgO would increase
the amount of coke deposit on the WOx/SiO2 catalyst. The TPO
profile presented two peaks when the WOx/SiO2 catalyst was
physically mixed with MgO. The further peak was suggested that
came from coke precursor could be produced by isomerization
reaction of undesired product. Then, the occurred coke precursor
could deposit and form coke on the acid catalyst.
Abstract: Failure of typical seismic frames has been found by
plastic hinge occurring on beams section near column faces. On the
other hand, the seismic capacity of the frames can be enhanced if the
plastic hinges of the beams are shifted away from the column faces.
This paper presents detailing of reinforcements in the interior beam–
column connections aiming to relocate the plastic hinge of reinforced
concrete and precast concrete frames. Four specimens were tested
under quasi-static cyclic load including two monolithic specimens
and two precast specimens. For one monolithic specimen, typical
seismic reinforcement was provided and considered as a reference
specimen named M1. The other reinforced concrete frame M2
contained additional intermediate steel in the connection area
compared with the specimen M1. For the precast specimens,
embedded T-section steels in joint were provided, with and without
diagonal bars in the connection area for specimen P1 and P2,
respectively. The test results indicated the ductile failure with beam
flexural failure in monolithic specimen M1 and the intermediate steel
increased strength and improved joint performance of specimen M2.
For the precast specimens, cracks generated at the end of the steel
inserts. However, slipping of reinforcing steel lapped in top of the
beams was seen before yielding of the main bars leading to the brittle
failure. The diagonal bars in precast specimens P2 improved the
connection stiffness and the energy dissipation capacity.
Abstract: Ibeno, Nigeria hosts the operational base of Mobil
Producing Nigeria Unlimited (MPNU), a subsidiary of ExxonMobil
and the current highest oil & condensate producer in Nigeria. Besides
MPNU, other oil companies operate onshore, on the continental shelf
and deep offshore of the Atlantic Ocean in Ibeno, Nigeria. This study
was designed to delineate oil polluted sites in Ibeno, Nigeria using
geophysical methods of electrical resistivity (ER) and ground
penetrating radar (GPR). Results obtained revealed that there have
been hydrocarbon contaminations of this environment by past crude
oil spills as observed from high resistivity values and GPR profiles
which clearly show the distribution, thickness and lateral extent of
hydrocarbon contamination as represented on the radargram reflector
tones. Contaminations were of varying degrees, ranging from slight
to high, indicating levels of substantial attenuation of crude oil
contamination over time. Moreover, the display of relatively lower
resistivities of locations outside the impacted areas compared to
resistivity values within the impacted areas and the 3-D Cartesian
images of oil contaminant plume depicted by red, light brown and
magenta for high, low and very low oil impacted areas, respectively
confirmed significant recent pollution of the study area with crude
oil.
Abstract: This paper analyzes the conceptual framework of three
statistical methods, multiple regression, path analysis, and structural
equation models. When establishing research model of the statistical
modeling of complex social phenomenon, it is important to know the
strengths and limitations of three statistical models. This study
explored the character, strength, and limitation of each modeling and
suggested some strategies for accurate explaining or predicting the
causal relationships among variables. Especially, on the studying of
depression or mental health, the common mistakes of research
modeling were discussed.
Abstract: An unconventional composite inorganic ceramic
membrane capable of enhancing carbon dioxide emission decline was
fabricated and tested at laboratory scale in conformism to various
environmental guidelines and also to mitigate the effect of global
warming. A review of the existing membrane technologies for carbon
capture including the relevant gas transport mechanisms is presented.
Single gas permeation experiments using silica modified ceramic
membrane with internal diameter 20mm, outside diameter 25mm and
length of 368mm deposited on a macro porous support was carried
out to investigate individual gas permeation behaviours at different
pressures at room temperature. Membrane fabrication was achieved
using after a dip coating method. Nitrogen, Carbon dioxide, Argon,
Oxygen and Methane pure gases were used to investigate their
individual permeation rates at various pressures. Results show that
the gas flow rate increases with pressure drop. However above a
pressure of 3bar, CO2 permeability ratio to that of the other gases
indicated control of a more selective surface adsorptive transport
mechanism.
Abstract: Design concepts of real-time embedded system can be
realized initially by introducing novel design approaches. In this
literature, model based design approach and in-the-loop testing were
employed early in the conceptual and preliminary phase to formulate
design requirements and perform quick real-time verification. The
design and analysis methodology includes simulation analysis, model
based testing, and in-the-loop testing. The design of conceptual driveby-
wire, or DBW, algorithm for electronic control unit, or ECU, was
presented to demonstrate the conceptual design process, analysis, and
functionality evaluation. The concepts of DBW ECU function can be
implemented in the vehicle system to improve electric vehicle, or EV,
conversion drivability. However, within a new development process,
conceptual ECU functions and parameters are needed to be evaluated.
As a result, the testing system was employed to support conceptual
DBW ECU functions evaluation. For the current setup, the system
components were consisted of actual DBW ECU hardware, electric
vehicle models, and control area network or CAN protocol. The
vehicle models and CAN bus interface were both implemented as
real-time applications where ECU and CAN protocol functionality
were verified according to the design requirements. The proposed
system could potentially benefit in performing rapid real-time
analysis of design parameters for conceptual system or software
algorithm development.
Abstract: We evaluate the performance of a numerical method
for global optimization of expensive functions. The method is using a
response surface to guide the search for the global optimum. This
metamodel could be based on radial basis functions, kriging, or a
combination of different models. We discuss how to set the cyclic
parameters of the optimization method to get a balance between local
and global search. We also discuss the eventual problem with Runge
oscillations in the response surface.
Abstract: Rehabilitation of dam components such as foundations, buttresses, spillways and overtopping protection require a wide range of construction and design methodologies. Geotechnical Engineering considerations play an important role in the design and construction of foundations of new dams. Much investigation is required to assess and evaluate the existing dams. The application of roller compacting concrete (RCC) has been accepted as a new method for constructing new dams or rehabilitating old ones. In the past 40 years there have been so many changes in the usage of RCC and now it is one of most satisfactory solutions of water and hydropower resource throughout the world. The considerations of rehabilitation and construction of dams might differ due to upstream reservoir and its influence on penetrating and dewatering of downstream, operations requirements and plant layout. One of the advantages of RCC is its rapid placement which allows the dam to be operated quickly. Unlike ordinary concrete it is a drier mix, and stiffs enough for compacting by vibratory rollers. This paper evaluates some different aspects of RCC and focuses on its preparation progress.
Abstract: An adaptive nonparametric method is proposed for
stable real-time detection of seismoacoustic sources in multichannel
C-OTDR systems with a significant number of channels. This
method guarantees given upper boundaries for probabilities of Type I
and Type II errors. Properties of the proposed method are rigorously
proved. The results of practical applications of the proposed method
in a real C-OTDR-system are presented in this report.
Abstract: Latin hypercube designs (LHDs) have been applied in
many computer experiments among the space-filling designs found in
the literature. A LHD can be randomly generated but a randomly
chosen LHD may have bad properties and thus act poorly in
estimation and prediction. There is a connection between Latin
squares and orthogonal arrays (OAs). A Latin square of order s
involves an arrangement of s symbols in s rows and s columns, such
that every symbol occurs once in each row and once in each column
and this exists for every non-negative integer s. In this paper, a
computer program was written to construct orthogonal array-based
Latin hypercube designs (OA-LHDs). Orthogonal arrays (OAs) were
constructed from Latin square of order s and the OAs constructed
were afterward used to construct the desired Latin hypercube designs
for three input variables for use in computer experiments. The LHDs
constructed have better space-filling properties and they can be used
in computer experiments that involve only three input factors.
MATLAB 2012a computer package (www.mathworks.com/) was
used for the development of the program that constructs the designs.
Abstract: One of the main challenges in using the Discrete
Element Method (DEM) is to specify the correct input parameter
values. In general, the models are sensitive to the input parameter
values and accurate results can only be achieved if the correct values
are specified. For the linear contact model, micro-parameters such as
the particle density, stiffness, coefficient of friction, as well as the
particle size and shape distributions are required. There is a need for
a procedure to accurately calibrate these parameters before any
attempt can be made to accurately model a complete bulk materials
handling system. Since DEM is often used to model applications in
the mining and quarrying industries, a calibration procedure was
developed for materials that consist of relatively large (up to 40 mm
in size) particles. A coarse crushed aggregate was used as the test
material. Using a specially designed large shear box with a diameter
of 590 mm, the confined Young’s modulus (bulk stiffness) and
internal friction angle of the material were measured by means of the
confined compression test and the direct shear test respectively. DEM
models of the experimental setup were developed and the input
parameter values were varied iteratively until a close correlation
between the experimental and numerical results was achieved. The
calibration process was validated by modelling the pull-out of an
anchor from a bed of material. The model results compared well with
experimental measurement.
Abstract: An experimental and analytical research on shear
buckling of a comparably large polymer composite I-section is
presented. It is known that shear buckling load of a large span
composite beam is difficult to determine experimentally. In order to
sensitively detect shear buckling of the tested I-section, twenty strain
rosettes and eight displacement sensors were applied and attached on
the web and flange surfaces. The tested specimen was a pultruded
composite beam made of vinylester resin, E-glass, carbon fibers and
micro-fillers. Various coupon tests were performed before the shear
buckling test to obtain fundamental material properties of the Isection.
An asymmetric four-point bending loading scheme was
utilized for the shear test. The loading scheme resulted in a high shear
and almost zero moment condition at the center of the web panel. The
shear buckling load was successfully determined after analyzing the
obtained test data from strain rosettes and displacement sensors. An
analytical approach was also performed to verify the experimental
results and to support the discussed experimental program.
Abstract: This paper investigates the benefits of deliberately
unbalancing both operation time means (MTs) and unreliability
(failure and repair rates) for non-automated production lines. The
lines were simulated with various line lengths, buffer capacities,
degrees of imbalance and patterns of MT and unreliability imbalance.
Data on two performance measures, namely throughput (TR) and
average buffer level (ABL) were gathered, analyzed and compared to
a balanced line counterpart. A number of conclusions were made
with respect to the ranking of configurations, as well as to the
relationships among the independent design parameters and the
dependent variables. It was found that the best configurations are a
balanced line arrangement and a monotone decreasing MT order,
coupled with either a decreasing or a bowl unreliability configuration,
with the first generally resulting in a reduced TR and the second
leading to a lower ABL than those of a balanced line.
Abstract: During the post-Civil War era, the city of Nashville,
Tennessee, had the highest mortality rate in the United States. The
elevated death and disease rates among former slaves were
attributable to lack of quality healthcare. To address the paucity of
healthcare services, Meharry Medical College, an institution with the
mission of educating minority professionals and serving the
underserved population, was established in 1876.
Purpose: The social ecological framework and partial least squares
(PLS) path modeling were used to quantify the impact of
socioeconomic status and adverse health outcome on primary care
professionals serving the disadvantaged community. Thus, the study
results could demonstrate the accomplishment of the College’s
mission of training primary care professionals to serve in underserved
areas.
Methods: Various statistical methods were used to analyze alumni
data from 1975 – 2013. K-means cluster analysis was utilized to
identify individual medical and dental graduates in the cluster groups
of the practice communities (Disadvantaged or Non-disadvantaged
Communities). Discriminant analysis was implemented to verify the
classification accuracy of cluster analysis. The independent t-test was
performed to detect the significant mean differences of respective
clustering and criterion variables. Chi-square test was used to test if
the proportions of primary care and non-primary care specialists are
consistent with those of medical and dental graduates practicing in
the designated community clusters. Finally, the PLS path model was
constructed to explore the construct validity of analytic model by
providing the magnitude effects of socioeconomic status and adverse
health outcome on primary care professionals serving the
disadvantaged community.
Results: Approximately 83% (3,192/3,864) of Meharry Medical
College’s medical and dental graduates from 1975 to 2013 were
practicing in disadvantaged communities. Independent t-test confirmed the content validity of the cluster analysis model. Also, the
PLS path modeling demonstrated that alumni served as primary care
professionals in communities with significantly lower socioeconomic
status and higher adverse health outcome (p < .001). The PLS path
modeling exhibited the meaningful interrelation between primary
care professionals practicing communities and surrounding
environments (socioeconomic statues and adverse health outcome),
which yielded model reliability, validity, and applicability.
Conclusion: This study applied social ecological theory and
analytic modeling approaches to assess the attainment of Meharry
Medical College’s mission of training primary care professionals to
serve in underserved areas, particularly in communities with low
socioeconomic status and high rates of adverse health outcomes. In
summary, the majority of medical and dental graduates from Meharry
Medical College provided primary care services to disadvantaged
communities with low socioeconomic status and high adverse health
outcome, which demonstrated that Meharry Medical College has
fulfilled its mission. The high reliability, validity, and applicability of
this model imply that it could be replicated for comparable
universities and colleges elsewhere.
Abstract: Introduction: There are multiple social, individual and
cultural factors that influence an individual’s decision to adopt family
planning methods especially among non-users in patriarchal societies
like Pakistan. Non-users, if targeted efficiently, can contribute
significantly to country’s CPR. A research study showed that nonusers
if convinced to adopt lactational amenorrhea method can shift
to long term methods in future. Research shows that if non users are
targeted efficiently a 59% reduction in unintended pregnancies in
Saharan Africa and South-Central and South-East Asia is anticipated.
Methods: We did secondary data analysis on Pakistan
Demographic Heath Survey (2012-13) dataset. Use of contraception
(never-use/ever-use) was the outcome variable. At univariate level
Chi-square/Fisher Exact test was used to assess relationship of
baseline covariates with contraception use. Then variables to be
incorporated in the model were checked for multicollinearity,
confounding and interaction. Then binary logistic regression (with an
urban-rural stratification) was done to find relationship between
contraception use and baseline demographic and social variables.
Results: The multivariate analyses of the study showed that
younger women (≤ 29 years)were more prone to be never users as
compared to those who were >30 years and this trend was seen in
urban areas (AOR 1.92, CI 1.453-2.536) as well as rural areas (AOR
1.809, CI 1.421-2.303). While looking at regional variation, women
from urban Sindh (AOR 1.548, CI 1.142-2.099) and urban
Balochistan (AOR 2.403, CI 1.504-3.839) had more never users as
compared to other urban regions. Women in the rich wealth quintile
were more never users and this was seen both in urban and rural
localities (urban (AOR 1.106 CI .753-1.624); rural areas (AOR 1.162,
CI .887-1.524)) even though these were not statistically significant.
Women idealizing more children (>4) are more never users as
compared to those idealizing less children in both urban (AOR 1.854,
CI 1.275-2.697) and rural areas (AOR 2.101, CI 1.514-2.916).
Women who never lost a pregnancy were more inclined to be nonusers
in rural areas (AOR 1.394, CI 1.127-1.723) .Women familiar
with only traditional or no method had more never users in rural areas
(AOR 1.717, CI 1.127-1.723) but in urban areas it wasn’t significant.
Women unaware of Lady Health Worker’s presence in their area
were more never users especially in rural areas (AOR 1.276, CI
1.014-1.607). Women who did not visit any care provider were more
never users (urban (AOR 11.738, CI 9.112-15.121) rural areas (AOR
7.832, CI 6.243-9.826)).
Discussion/Conclusion: This study concluded that government,
policy makers and private sector family planning programs should
focus on the untapped pool of never users (younger women from underserved provinces, in higher wealth quintiles, who desire more
children.). We need to make sure to cover catchment areas where
there are less LHWs and less providers as ignorance to modern
methods and never been visited by an LHW are important
determinants of never use. This all is in sync with previous literate
from similar developing countries.
Abstract: Crosstalk among interconnects and printed-circuit
board (PCB) traces is a major limiting factor of signal quality in highspeed
digital and communication equipments especially when fast
data buses are involved. Such a bus is considered as a planar
multiconductor transmission line. This paper will demonstrate how
the finite difference time domain (FDTD) method provides an exact
solution of the transmission-line equations to analyze the near end
and the far end crosstalk. In addition, this study makes it possible to
analyze the rise time effect on the near and far end voltages of the
victim conductor. The paper also discusses a statistical analysis,
based upon a set of several simulations. Such analysis leads to a
better understanding of the phenomenon and yields useful
information.
Abstract: The effect of N2 pretreatment on the catalytic activity
of tungsten-based catalysts was investigated in the metathesis of
ethylene and trans-2-butene at 450oC and atmospheric pressure. The
presence of tungsten active species was confirmed by UV-Vis and
Raman spectroscopy. Compared to the WO3-based catalysts treated
in air, higher amount of WO4 2-tetrahedral species and lower amount
of WO3 crystalline species were observed on the N2-treated ones.
These contribute to the higher conversion of 2-butene and propylene
selectivity during 10 h time-on-stream. Moreover, N2 treatment led to
lower amount of coke formation as revealed by TPO of the spent
catalysts.
Abstract: The model tests were conducted in the laboratory
without and with Plastic recycled polymer in fly ash steep slopes
overlaying soft foundation soils like fly ash and powai soil in order to
check the stability of steep slope. In this experiment, fly ash is used
as a filling material and Plastic Recycled Polymers of diameter =
3mm and length = 4mm were made from waste plastic product (lower
grade plastic product). The properties of fly ash and Plastic recycled
polymers are determined. From the experiments, load and settlement
have measured. From these data, load –settlement curves have
reported. It has been observed from test results that load carrying
capacity of mixture fly ash with Plastic Recycled Polymers slope is
more than that of fly ash slope. The deformation of Plastic Recycled
Polymers slope is slightly more than that of fly ash slope. A Finite
Element Method (F.E.M.) was also evaluated using PLAXIS 3D
version. The failure pattern, deformations and factor of safety are
reported based on analytical programme. The results from
experimental data and analytical programme are compared and
reported.
Abstract: ABC classification is widely used by managers for
inventory control. The classical ABC classification is based on Pareto
principle and according to the criterion of the annual use value only.
Single criterion classification is often insufficient for a closely
inventory control. Multi-criteria inventory classification models have
been proposed by researchers in order to consider other important
criteria. From these models, we will consider a specific model in
order to make a sensitive analysis on the composite score calculated
for each item. In fact, this score, based on a normalized average
between a good and a bad optimized index, can affect the ABC-item
classification. We will focus on items differently assigned to classes
and then propose a classification compromise.
Abstract: The following article presents Technology Centre of
Ostrava (TCO) in the Czech Republic describing the structure and
main research areas realized by the project ENET - Energy Units for
Utilization of non Traditional Energy Sources. More details are
presented from the research program dealing with transformation,
accumulation and distribution of electric energy. Technology Centre
has its own energy mix consisting of alternative sources of fuel
sources that use of process gases from the storage part and also the
energy from distribution network. The article will be focus on the
properties and application possibilities SiC semiconductor devices for
power semiconductor converter for photovoltaic systems.