Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: Carbon dioxide is one of the major greenhouse gas
(GHG) contributors. It is an obligation of the industry to reduce the
amount of carbon dioxide emission to the acceptable limits.
Tremendous research and studies are reported in the past and still the
quest to find the suitable and economical solution of this problem
needed to be explored in order to develop the most plausible absorber
for carbon dioxide removal. Amino acids can be potential alternate
solvents for carbon dioxide capture from gaseous streams. This is due
to its ability to resist oxidative degradation, low volatility and its
ionic structure. In addition, the introduction of promoter-like
piperazine to amino acid helps to further enhance the solubility. In
this work, the effect of piperazine on thermo physical properties and
solubility of β-Alanine aqueous solutions were studied for various
concentrations. The measured physicochemical properties data was
correlated as a function of temperature using least-squares method
and the correlation parameters are reported together with it respective
standard deviations. The effect of activator piperazine on the CO2
loading performance of selected amino acid under high-pressure
conditions (1bar to 10bar) at temperature range of (30 to 60)oC was
also studied. Solubility of CO2 decreases with increasing temperature
and increases with increasing pressure. Quadratic representation of
solubility using Response Surface Methodology (RSM) shows that
the most important parameter to optimize solubility is system
pressure. The addition of promoter increases the solubility effect of
the solvent.
Abstract: A myriad of environmental issues face the Nigerian
industrial region, resulting from; oil and gas production, mining,
manufacturing and domestic wastes. Amidst these, much effort has
been directed by stakeholders in the Nigerian oil producing regions,
because of the impacts of the region on the wider Nigerian economy.
Although collaborative environmental management has been noted as
an effective approach in managing environmental issues, little
attention has been given to the roles and practices of stakeholders in
effecting a collaborative environmental management framework for
the Nigerian oil-producing region. This paper produces a framework
to expand and deepen knowledge relating to stakeholders aspects of
collaborative roles in managing environmental issues in the Nigeria
oil-producing region. The knowledge is derived from analysis of
stakeholders’ practices – studied through multiple case studies using
document analysis. Selected documents of key stakeholders –
Nigerian government agencies, multi-national oil companies and host
communities, were analyzed. Open and selective coding was
employed manually during document analysis of data collected from
the offices and websites of the stakeholders. The findings showed
that the stakeholders have a range of roles, practices, interests, drivers
and barriers regarding their collaborative roles in managing
environmental issues. While they have interests for efficient resource
use, compliance to standards, sharing of responsibilities, generating
of new solutions, and shared objectives; there is evidence of major
barriers and these include resource allocation, disjointed policy,
ineffective monitoring, diverse socio- economic interests, lack of
stakeholders’ commitment and limited knowledge sharing. However,
host communities hold deep concerns over the collaborative roles of
stakeholders for economic interests, particularly, where government
agencies and multi-national oil companies are involved. With these
barriers and concerns, a genuine stakeholders’ collaboration is found
to be limited, and as a result, optimal environmental management
practices and policies have not been successfully implemented in the
Nigeria oil-producing region. A framework is produced that describes
practices that characterize collaborative environmental management
might be employed to satisfy the stakeholders’ interests. The
framework recommends critical factors, based on the findings, which
may guide a collaborative environmental management in the oil
producing regions. The recommendations are designed to re-define
the practices of stakeholders in managing environmental issues in the
oil producing regions, not as something wholly new, but as an
approach essential for implementing a sustainable environmental
policy. This research outcome may clarify areas for future research as
well as to contribute to industry guidance in the area of collaborative
environmental management.
Abstract: The change in orbit evolution between collocated
satellites (X, Y) inside +/-0.09° E/W and +/- 0.07° N/S cluster, after
one of these satellites is placed in an inclined orbit (satellite X) and
the effect of this change in the collocation safety inside the cluster
window has been studied and evaluated. Several collocation scenarios had been studied in order to adjust
the location of both satellites inside their cluster to maximize the
separation between them and safe the mission.
Abstract: In this paper, according to the classical algorithm
LSQR for solving the least-squares problem, an iterative method is
proposed for least-squares solution of constrained matrix equation. By
using the Kronecker product, the matrix-form LSQR is presented to
obtain the like-minimum norm and minimum norm solutions in a
constrained matrix set for the symmetric arrowhead matrices. Finally,
numerical examples are also given to investigate the performance.
Abstract: Prior literature in the field of adaptive and
personalized learning sequence in e-learning have proposed and
implemented various mechanisms to improve the learning process
such as individualization and personalization, but complex to
implement due to expensive algorithmic programming and need of
extensive and prior data. The main objective of personalizing
learning sequence is to maximize learning by dynamically selecting
the closest teaching operation in order to achieve the learning
competency of learner. In this paper, a revolutionary technique has
been proposed and tested to perform individualization and
personalization using modified reversed roulette wheel selection
algorithm that runs at O(n). The technique is simpler to implement
and is algorithmically less expensive compared to other revolutionary
algorithms since it collects the dynamic real time performance matrix
such as examinations, reviews, and study to form the RWSA single
numerical fitness value. Results show that the implemented system is
capable of recommending new learning sequences that lessens time
of study based on student's prior knowledge and real performance
matrix.
Abstract: In this paper, von Mises and Drucker-Prager yield criteria, as typical ones that consider the effect of intermediate principal stress σ2, have been selected and employed for investigating the influence of σ2 on the solution of a typical stability problem. The bearing capacity factors have been calculated under plane strain condition (strip footing) and axisymmetric condition (circular footing) using the method of stress characteristics together with the criteria mentioned. Different levels of σ2 relative to the other two principal stresses have been considered. While a higher σ2 entry in yield criterion gives a higher bearing capacity; its entry in equilibrium equations (axisymmetric) causes substantial reduction.
Abstract: In this paper, de Laval rotor system has been
characterized by a hinge model and its transient response numerically
treated for a dynamic solution. The effect of the ensuing non-linear
disturbances namely rub and breathing crack is numerically
simulated. Subsequently, three analysis methods: Orbit Analysis, Fast
Fourier Transform (FFT), and Wavelet Transform (WT) are
employed to extract features of the vibration signal of the faulty
system. An analysis of the system response orbits clearly indicates
the perturbations due to the rotor-to-stator contact. The sensitivities
of WT to the variation in system speed have been investigated by
Continuous Wavelet Transform (CWT). The analysis reveals that
features of crack, rubs and unbalance in vibration response can be
useful for condition monitoring. WT reveals its ability to detect nonlinear
signal, and obtained results provide a useful tool method for
detecting machinery faults.
Abstract: When evaluating the capacity of a generation park to
cover the load in transmission systems, traditional Loss of Load
Expectation (LOLE) and Expected Energy not Served (EENS)
indices can be used. If those indices allow computing the annual
duration and severity of load non covering situations, they do not take
into account the fact that the load excess is generally shifted from one
penury state (hour or quarter of an hour) to the following one. In this
paper, a sequential Monte Carlo framework is introduced in order to
compute adjusted LOLE and EENS indices. Practically, those
adapted indices permit to consider the effect of load excess transfer
on the global adequacy of a generation park, providing thus a more
accurate evaluation of this quantity.
Abstract: Lead being a toxic heavy metal that mankind is
exposed to the highest levels of this metal. There are different sources
of environmental pollution with lead as lead alkyl additives in petrol
and manufacturing processes. The contaminated atmosphere in urban
and industrial areas by lead in Egypt may lead to the contamination
of foods beside the other different sources. The present investigation
studied the risk assessment of lead in some Egyptian edible
vegetables and fruits collected from different environments in Greater
Cairo Governorate, i.e. industrial, heavy traffic and rural areas. A
total of 325 leafy and fruity vegetables and fruits samples belonging
to 11, 6 and 4 different species, respectively were randomly collected
from markets of the three main models. Data indicated the variation
of lead levels in different three areas. The highest levels of lead were
detected in the samples collected from industrial and traffic areas.
However, the lowest levels were found in the rural areas. It could be
concluded that determination of lead levels in foods from different
localities and environments at regularly is very important.
Abstract: This study aims to establish function point process
based on stochastic distribution. In order to demonstrate effectiveness
of the study we present a case study that it applies suggested method
on an automotive electrical and electronics system software
development based on Monte Carlo Simulation. It is expected that the
result of this paper is used as guidance for establishing function point
process in organizations and tools for helping project managers make
decisions correctly.
Abstract: In order to utilize results from global climate models,
dynamical and statistical downscaling techniques have been
developed. For dynamical downscaling, usually a limited area
numerical model is used, with associated high computational cost.
This research proposes dynamic equation for specific space-time
regional climate downscaling from the Educational Global Climate
Model (EdGCM) for Southeast Asia. The equation is for surface air
temperature. This equation provides downscaling values of surface
air temperature at any specific location and time without running a
regional climate model. In the proposed equations, surface air
temperature is approximated from ground temperature, sensible heat
flux and 2m wind speed. Results from the application of the equation
show that the errors from the proposed equations are less than the
errors for direct interpolation from EdGCM.
Abstract: This study focuses on the stress analysis of Mandibular
Advancement Devices (MADs), which are considered as a standard
treatment of snoring that promoted by American Academy of Sleep
Medicine (AASM). Snoring is the most significant feature of
sleep-disordered breathing (SDB). SDB will lead to serious problems
in human health. Oral appliances are ensured in therapeutic effect and
compliance, especially the MADs. This paper proposes a new MAD
design, and the finite element analysis (FEA) is introduced to precede
the stress simulation for this MAD.
Abstract: A psychological contract is an agreement between the
employer and an employee that covers the parties’ informal and
frequently non-verbalized obligations and expectations towards each
other. The contract is a cognitive pattern-governing employee’s
behaviour in the organization. A gap between employee’s
expectations and the organizational reality may lead to difficult-to-solve
conflicts or cause the employee to modify their behaviour
towards organizational values and goals, if they are willing and ready
to verbalize their expectations. The article discusses psychological contracts in the financial
institutions in Poland. Its theoretical part outlines the types of
psychological contracts in organizations (relational, transactional, and
balanced) and shows the process of their verbalization. The purpose
of the article is to present how the type of the psychological contract
relates to employee’s readiness to verbalize it. The article ends with
conclusions arising from the study.
Abstract: Opportunistic Routing (OR) increases the
transmission reliability and network throughput. Traditional routing
protocols preselects one or more predetermined nodes before
transmission starts and uses a predetermined neighbor to forward a
packet in each hop. The opportunistic routing overcomes the
drawback of unreliable wireless transmission by broadcasting one
transmission can be overheard by manifold neighbors. The first
cooperation-optimal protocol for Multirate OR (COMO) used to
achieve social efficiency and prevent the selfish behavior of the
nodes. The novel link-correlation-aware OR improves the
performance by exploiting the miscellaneous low correlated forward
links. Context aware Adaptive OR (CAOR) uses active suppression
mechanism to reduce packet duplication. The Context-aware OR
(COR) can provide efficient routing in mobile networks. By using
Cooperative Opportunistic Routing in Mobile Ad hoc Networks
(CORMAN), the problem of opportunistic data transfer can be
tackled. While comparing to all the protocols, COMO is the best as it
achieves social efficiency and prevents the selfish behavior of the
nodes.
Abstract: This paper aimed to introduce the solution of concrete
slump recovery using chemical admixture type-F (superplasticizer,
naphthalene base) to the practice in order to solve unusable concrete
problem due to concrete loss its slump, especially for those tropical
countries that have faster slump loss rate. In the other hand, randomly
adding superplasticizer into concrete can cause concrete to segregate.
Therefore, this paper also develops the estimation model used to
calculate amount of second dose of superplasticizer need for concrete
slump recovery. Fresh properties of ordinary Portland cement
concrete with volumetric ratio of paste to void between aggregate
(paste content) of 1.1-1.3 with water-cement ratio zone of 0.30 to
0.67 and initial superplasticizer (naphthalene base) of 0.25%-1.6%
were tested for initial slump and slump loss for every 30 minutes for
one and half hour by slump cone test. Those concretes with slump
loss range from 10% to 90% were re-dosed and successfully
recovered back to its initial slump. Slump after re-dosed was tested
by slump cone test. From the result, it has been concluded that, slump
loss was slower for those mix with high initial dose of
superplasticizer due to addition of superplasticizer will disturb
cement hydration. The required second dose of superplasticizer was
affected by two major parameters, which were water-cement ratio
and paste content, where lower water-cement ratio and paste content
cause an increase in require second dose of superplasticizer. The
amount of second dose of superplasticizer is higher as the solid
content within the system is increase, solid can be either from cement
particles or aggregate. The data was analyzed to form an equation use
to estimate the amount of second dosage requirement of
superplasticizer to recovery slump to its original.
Abstract: The main purpose of this study is to assess the
sediment quality and potential ecological risk in marine sediments in
Gymea Bay located in south Sydney, Australia. A total of 32 surface
sediment samples were collected from the bay. Current track
trajectories and velocities have also been measured in the bay. The
resultant trace elements were compared with the adverse biological
effect values Effect Range Low (ERL) and Effect Range Median
(ERM) classifications. The results indicate that the average values of
chromium, arsenic, copper, zinc, and lead in surface sediments all
reveal low pollution levels and are below ERL and ERM values. The
highest concentrations of trace elements were found close to
discharge points and in the inner bay, and were linked with high
percentages of clay minerals, pyrite and organic matter, which can
play a significant role in trapping and accumulating these elements.
The lowest concentrations of trace elements were found to be on the
shoreline of the bay, which contained high percentages of sand
fractions. It is postulated that the fine particles and trace elements are
disturbed by currents and tides, then transported and deposited in
deeper areas. The current track velocities recorded in Gymea Bay had
the capability to transport fine particles and trace element pollution
within the bay. As a result, hydrodynamic measurements were able to
provide useful information and to help explain the distribution of
sedimentary particles and geochemical properties. This may lead to
knowledge transfer to other bay systems, including those in remote
areas. These activities can be conducted at a low cost, and are
therefore also transferrable to developing countries. The advent of
portable instruments to measure trace elements in the field has also
contributed to the development of these lower cost and easily applied
methodologies available for use in remote locations and low-cost
economies.
Abstract: Large quantities of solid wastes being generated
worldwide from sources such as household, domestic, industrial,
commercial and construction demolition activities, leads to
environmental concerns. Utilization of these wastes in making
building construction materials can reduce the magnitude of the
associated problems. When these waste products are used in place of
other conventional materials, natural resources and energy are
preserved and expensive and/or potentially harmful waste disposal is
avoided. Recycling which is regarded as the third most preferred waste
disposal option, with its numerous environmental benefits, stand as a
viable option to offset the environmental impact associated with the
construction industry. This paper reviews the results of laboratory tests and important
research findings, and the potential of using these wastes in building
construction materials with focus on sustainable development.
Research gaps, which includes; the need to develop standard mix
design for solid waste based building materials; the need to develop
energy efficient method of processing solid waste use in concrete; the
need to study the actual behavior or performance of such building
materials in practical application and the limited real life application
of such building materials have also been identified. A research is being proposed to develop an environmentally
friendly, lightweight building block from recycled waste paper,
without the use of cement, and with properties suitable for use as
walling unit. This proposed research intends to incorporate,
laboratory experimentation and modeling to address the identified
research gaps.
Abstract: Common Platform for Automated Programming
(CPAP) is defined in details. Two versions of CPAP are described:
Cloud based (including set of components for classic programming,
and set of components for combined programming); and Knowledge
Based Automated Software Engineering (KBASE) based (including
set of components for automated programming, and set of
components for ontology programming). Four KBASE products
(Module for Automated Programming of Robots, Intelligent Product
Manual, Intelligent Document Display, and Intelligent Form
Generator) are analyzed and CPAP contributions to automated
programming are presented.
Abstract: Software quality issues require special attention
especially in view of the demands of quality software product to meet
customer satisfaction. Software development projects in most
organisations need proper defect management process in order to
produce high quality software product and reduce the number of
defects. The research question of this study is how to produce high
quality software and reducing the number of defects. Therefore, the
objective of this paper is to provide a framework for managing
software defects by following defined life cycle processes. The
methodology starts by reviewing defects, defect models, best
practices, and standards. A framework for defect management life
cycle is proposed. The major contribution of this study is to define a
defect management roadmap in software development. The adoption
of an effective defect management process helps to achieve the
ultimate goal of producing high quality software products and
contributes towards continuous software process improvement.