Abstract: The aim of this research was to calculate the thermal
properties of Au3Ni Nanowire. The molecular dynamics (MD)
simulation technique was used to obtain the effect of radius size on
the energy, the melting temperature and the latent heat of fusion at
the isobaric-isothermal (NPT) ensemble. The Quantum Sutton-Chen
(Q-SC) many body interatomic potentials energy have been used for
Gold (Au) and Nickel (Ni) elements and a mixing rule has been
devised to obtain the parameters of these potentials for nanowire
stats. Our MD simulation results show the melting temperature and
latent heat of fusion increase upon increasing diameter of nanowire.
Moreover, the cohesive energy decreased with increasing diameter of
nanowire.
Abstract: The mechanical properties including flexural and
tensile of neat vinyl ester and polymer based on layered silicate
nanocomposite materials are discussed. The addition of layered
silicate into the polymer matrix increased the tensile and flexural
modulus up to 1 wt.% clay loading. The incorporation of more clay
resulted in decreasing the mechanical properties which was traced to
the existence of aggregation layers. Likewise, up to 1 wt.% clay
loading, the thermal behaviour showed significant improvements and
at higher clay loading the thermal pattern was reduced. The
aggregation layers imparted a negative impact on the overall
mechanical and thermal properties. Wide Angle X-ray Diffraction,
Scanning Electron Microscopy and Transmission Electron
Microscopy were utilised in order to characterise the interlamellar
structure of nanocomposites.
Abstract: This report shows the performance of composite
biodegradable film from chitosan, starch and sawdust fiber. The main
objectives of this research are to fabricate and characterize composite
biodegradable film in terms of morphology and physical properties.
The film was prepared by casting method. Sawdust fiber was used as
reinforcing agent and starch as polymer matrix in the casting
solution. The morphology of the film was characterized using atomic
force microscope (AFM). The result showed that the film has
smooth structure. Chemical composition of the film was investigated
using Fourier transform infrared (FTIR) where the result revealed
present of starch in the film. The thermal properties were
characterized using thermal gravimetric analyzer (TGA) and
differential scanning calorimetric (DSC) where the results showed
that the film has small difference in melting and degradation
temperature.
Abstract: In this study, an ablation, mechanical and thermal properties of a rocket motor insulation from phenolic/ fiber matrix composites forming a laminate with different fiber between fiberglass and locally available synthetic fibers. The phenolic/ fiber matrix composites was mechanics and thermal properties by means of tensile strength, ablation, TGA and DSC. The design of thermal insulation involves several factors.Determined the mechanical properties according to MIL-I-24768: Density >1.3 g/cm3, Tensile strength >103 MPa and Ablation
Abstract: Polymers are one of the most widely used materials in our every day life. The subject of renewable resources has attracted great attention in the last period of time. New polymeric materials derived from renewable resources, like carbohydrates draw attention to public eye especially because of their biocompatibility and biodegradability. The aim of our paper was to obtain environmentally compatible polymers from monosaccharides. Novel glycopolymers based on D-glucose have been obtained from copolymerization of a new monomer carrying carbohydrate moiety with methyl methacrylate (MMA) via free radical bulk polymerization. Differential scanning calorimetry (DSC) was performed in order to study the copolymerization process of the monomer into the chosen co-monomer; the activation energy of this process was evaluated using Ozawa method. The copolymers obtained were characterized using ATR-FTIR spectroscopy. The thermal stability of the obtained products was studied by thermogravimetry (TG).
Abstract: Composites based on a biodegradable polycaprolactone (PCL) containing 0.5, 1.0 and 2.0 wt % of titanium dioxide (TiO2) micro and nanoparticles were prepared by melt mixing and the effect of filler type and contents on the thermal properties, dynamic-mechanical behaviour and morphology were investigated. Measurements of storage modulus and loss modulus by dynamic mechanical analysis (DMA) showed better results for microfilled PCL/TiO2 composites than nanofilled composites, with the same filler content. DSC analysis showed that the Tg and Tc of micro and nanocomposites were slightly lower than those of neat PCL. The crystallinity of the PCL increased with the addition of TiO2 micro and nanoparticles; however, the cc for the PCL was unchanged with micro TiO2 content. The thermal stability of PCL/TiO2 composites were characterized using thermogravimetric analysis (TGA). The initial weight loss (5 wt %) occurs at slightly higher temperature with micro and nano TiO2 addition and with increasing TiO2 content.
Abstract: The leaching behavior and structure of Li2O-CeO2- Fe2O3-P2O5 glasses incorporated with simulated high level nuclear wastes (HLW) were studied. The leach rates of gross and each constituent element were determined from the total weight loss of the specimen and the leachate analyses by inductively coupled argon plasma spectroscopy (ICP). The gross leach rate of the 4.5Li2O- 9.7CeO2-34.7Fe2O3-51.5P2O5 glass waste form containing 45 mass% simulated HLW is of the order of 10