Abstract: Environmental investments, including ecological
projects, relating to the protection of atmosphere are today a need.
However, investing in the environment should be based on rational
management rules. This comes across a problem of selecting a
method to assess substances reduced during projects. Therefore, a
method allowing for the assessment of decision rationality has to be
found.
The purpose of this article is to present and systematise pollution
reduction assessment methods and illustrate theoretical analyses with
empirical data.
Empirical results confirm theoretical considerations, which proved
that the only method for judging pollution reduction, free of apparent
disadvantages, is the Eco 99-ratio method. To make decisions on
environmental projects, financing institutions should take into
account a rationality rule. Therefore the Eco 99-ratio method could
be applied to make decisions relating to environmental investments in
the area of air protection.
Abstract: The purpose of this study is to investigate the chemical
degradation of the organophosphorus pesticide of parathion and
carbamate insecticide of methomyl in the aqueous phase through
Fenton process. With the employment of batch Fenton process, the
degradation of the two selected pesticides at different pH, initial
concentration, humic acid concentration, and Fenton reagent dosages
was explored. The Fenton process was found effective to degrade
parathion and methomyl. The optimal dosage of Fenton reagents (i.e.,
molar concentration ratio of H2O2 to Fe2+) at pH 7 for parathion
degradation was equal to 3, which resulted in 50% removal of
parathion. Similarly, the optimal dosage for methomyl degradation
was 1, resulting in 80% removal of methomyl. This study also found
that the presence of humic substances has enhanced pesticide
degradation by Fenton process significantly. The mass spectroscopy
results showed that the hydroxyl free radical may attack the single
bonds with least energy of investigated pesticides to form smaller
molecules which is more easily to degrade either through
physio-chemical or bilolgical processes.
Abstract: Horseradish (Armoracia rusticana) is a perennial herb belonging to the Brassicaceae family and contains biologically active substances. The aim of the current research was to determine best method for extraction of phenolic compounds from horseradish roots showing high antiradical activity. Three genotypes (No. 105; No. 106 and variety ‘Turku’) of horseradish roots were extracted with eight different solvents: n-hexane, ethyl acetate, diethyl ether, 2-propanol, acetone, ethanol (95%), ethanol / water / acetic acid (80/20/1 v/v/v) and ethanol / water (80/20 by volume) using two extraction methods (conventional and Soxhlet). As the best solvents ethanol and ethanol / water solutions can be chosen. Although in Soxhlet extracts TPC was higher, scavenging activity of DPPH˙ radicals did not increase. It can be concluded that using Soxhlet extraction method more compounds that are not effective antioxidants.
Abstract: The submitted paper deals with the problems of
trapping and enriching the gases and aerosols of the substances to be
determined in the ambient atmosphere. Further, the paper is focused
on the working principle of the miniaturized portable continuous
concentrator we have designed and the possibilities of its
application in air sampling and accumulation of organic and
inorganic substances with which the air is contaminated. The stress is
laid on trapping vapours and aerosols of solid substances with the
comparatively low vapour tension such as explosive compounds.
Abstract: Biodisel is a type of biofuel having similar properties of diesel fuel but lacks substances (undesirable emissions) such as sulfur, nitrogen and aromatic polycyclic. Upon filtration of waste oil, the biodiesel fuel was produced via carrying out transestrification reaction of triglycerides followed by conducting viscosity, density, flash point, cloud point, pour point and copper strip corrosion tests on the samples and comparing with EN14214 and ASTM 6751 standards and all results were found in the permitted limit. The highest yield of biodiesel production reaction was found 46.6435 g when Sodium Hydroxide catalyst in amount of 0.375g was employed, 44.2347 g when Sodium methoxide catalyst in amount of 0.5g was employed and 56.5124 g when acid sulfuric catalyst in amount of 1g was employed and 47.3290 g when two stage reaction was done.
Abstract: This paper proposes the use of Bayesian belief
networks (BBN) as a higher level of health risk assessment for a
dumping site of lead battery smelter factory. On the basis of the
epidemiological studies, the actual hospital attendance records and
expert experiences, the BBN is capable of capturing the probabilistic
relationships between the hazardous substances and their adverse
health effects, and accordingly inferring the morbidity of the adverse
health effects. The provision of the morbidity rates of the related
diseases is more informative and can alleviate the drawbacks of
conventional methods.
Abstract: Microcirculation is essential for the proper supply of
oxygen and nutritive substances to the biological tissue and the
removal of waste products of metabolism. The determination of
blood flow in the capillaries is therefore of great interest to clinicians.
A comparison has been carried out using the developed non-invasive,
non-contact and whole field laser speckle contrast imaging (LSCI)
based technique and as well as a commercially available laser
Doppler blood flowmeter (LDF) to evaluate blood flow at the finger
tip and elbow and is presented here. The LSCI technique gives more
quantitative information on the velocity of blood when compared to
the perfusion values obtained using the LDF. Measurement of blood
flow in capillaries can be of great interest to clinicians in the
diagnosis of vascular diseases of the upper extremities.
Abstract: Chlorine is one of the most abundant elements in
nature, which undergoes a complex biogeochemical cycle. Chlorine
bound in some substances is partly responsible for atmospheric ozone
depletion and contamination of some ecosystems. As due to
international regulations anthropogenic burden of volatile
organochlorines (VOCls) in atmosphere decreases, natural sources
(plants, soil, abiotic formation) are expected to dominate VOCl
production in the near future. Examples of plant VOCl production are
methyl chloride, and bromide emission from (sub)tropical ferns,
chloroform, 1,1,1-trichloroethane and tetrachloromethane emission
from temperate forest fern and moss. Temperate forests are found to
emit in addition to the previous compounds tetrachloroethene, and
brominated volatile compounds. VOCls can be taken up and further
metabolized in plants. The aim of this work is to identify and
quantitatively analyze the formed VOCls in temperate forest
ecosystems by a cryofocusing/GC-ECD detection method, hence
filling a gap of knowledge in the biogeochemical cycle of chlorine.
Abstract: The sanitary sewerage connection rate becomes an
important indicator of advanced cities. Following the construction of
sanitary sewerages, the maintenance and management systems are
required for keeping pipelines and facilities functioning well. These
maintenance tasks often require sewer workers to enter the manholes
and the pipelines, which are confined spaces short of natural
ventilation and full of hazardous substances. Working in sewers could
be easily exposed to a risk of adverse health effects. This paper
proposes the use of Bayesian belief networks (BBN) as a higher level
of noncarcinogenic health risk assessment of sewer workers. On the
basis of the epidemiological studies, the actual hospital attendance
records and expert experiences, the BBN is capable of capturing the
probabilistic relationships between the hazardous substances in sewers
and their adverse health effects, and accordingly inferring the
morbidity and mortality of the adverse health effects. The provision of
the morbidity and mortality rates of the related diseases is more
informative and can alleviate the drawbacks of conventional methods.
Abstract: The main purpose of this research is the calculation of implicit prices of the environmental level of air quality in the city of Moscow on the basis of housing property prices. The database used contains records of approximately 20 thousand apartments and has been provided by a leading real estate agency operating in Russia. The explanatory variables include physical characteristics of the houses, environmental (industry emissions), neighbourhood sociodemographic and geographic data: GPS coordinates of each house. The hedonic regression results for ecological variables show «negative» prices while increasing the level of air contamination from such substances as carbon monoxide, nitrogen dioxide, sulphur dioxide, and particles (CO, NO2, SO2, TSP). The marginal willingness to pay for higher environmental quality is presented for linear and log-log models.
Abstract: This study aims to identify the current situation and
problems of environmental statement for major four home appliances
(refrigerators, washing machines, air conditioners and television
receivers) sold at online stores in Japan, and then to suggest how to
improve the situation, through a questionnaire survey conducted
among businesses that operate online stores and online malls with
multiple online stores. Results of the study boil down to:
(1) It is found out that environmental statement for the home
appliances at online stores have four problems; (i) less information
on “three Rs" and “chemical substances" than the one on “energy
conservation", (ii) cost for providing environmental statement, (iii)
issues associated with a label and mark placement, and (iv) issues
associated with energy conservation statement.
(2) Improvements are suggested for each of the four problems listed
above, and shown are (i) the effectiveness of, and need to promote, a
label and mark placement, (ii) cost burden on buyers, and (iii) need
of active efforts made by businesses and of dissemination of legal
regulations to businesses.
Abstract: There is a complex situation on the transport environment in the cities of the world. For the analysis and prevention of environmental problems an accurate calculation hazardous substances concentrations at each point of the investigated area is required. In the turbulent atmosphere of the city the wellknown methods of mathematical statistics for these tasks cannot be applied with a satisfactory level of accuracy. Therefore, to solve this class of problems apparatus of mathematical physics is more appropriate. In such models, because of the difficulty as a rule the influence of uneven land surface on streams of air masses in the turbulent atmosphere of the city are not taken into account. In this paper the influence of the surface roughness, which can be quite large, is mathematically shown. The analysis of this problem under certain conditions identified the possibility of areas appearing in the atmosphere with pressure tending to infinity, i.e. so-called "wall effect".
Abstract: In order to enhance the knowledge of certain
phytochemical Algerian plants that are widely used in traditional
medicine and to exploit their therapeutic potential in modern
medicine, we have done a specific extraction of terpenes and
alkaloids from the leaves of Euphorbia granulata to evaluate the
antioxidant and antibacterial activity of this extracts. After the
extraction it was found that the terpene extract gave the highest yield
59.72% compared with alkaloids extracts.
The disc diffusion method was used to determine the antibacterial
activity against different bacterial strains: Escherichia coli
(ATCC25922), Pseudomonas aeruginosa (ATCC27853) and
Staphylococcus aureus (ATCC25923). All extracts have shown
inhibition of growth bacteria. The different zones of inhibition have
varied from (7 -10 mm) according to the concentrations of extract
used.
Testing the antiradical activity on DPPH-TLC plates indicated the
presence of substances that have potent anti-free radical. As against,
the BC-TLC revealed that only terpenes extract which was reacted
positively. These results can validate the importance of Euphorbia
granulata in traditional medicine.
Abstract: This paper presents the study of parameters affecting
the environment protection in the printing industry. The paper has
also compared LCA studies performed within the printing industry in
order to identify common practices, limitations, areas for
improvement, and opportunities for standardization. This comparison
is focused on the data sources and methodologies used in the printing
pollutants register. The presented concepts, methodology and results
represent the contribution to the sustainable development
management. Furthermore, the paper analyzes the result of the
quantitative identification of hazardous substances emitted in printing
industry of Novi Sad.
Abstract: Trihalomethanes (THMs) were among the first
disinfection byproducts to be discovered in chlorinated water. The
substances form during a reaction between chlorine and organic
matter in the water. Trihalomethanes are suspected to have negative
effects on birth such as, low birth weight, intrauterine growth
retardation in term births, as well as gestational age and preterm
delivery. There are also some evidences showing these by-products to
be mutagenic and carcinogenic, the greatest amount of evidence being
related to the bladder cancer. However, there exist inconsistencies
regarding such effects of THMs as different studies have provided
different results in this regard. The aim of the present study is to
provide a review of the related researches about the above mentioned
health effects of THMs.
Abstract: Crystallization has been used for the separation of
chloronitrobenzene or CNBs, which are isomeric substances (o-, mand
p-CNB) and important intermediates in chemical productions. Effects of feed composition on the crystallization of m- and p-CNB was first studied. The results conform to the binary phase diagram of
m- and p-CNB. After that, effects of FAU zeolites (NaX, CaX, BaX, NaY and CaY) above the eutectic composition (63.5 and 65.0 wt% m-CNB in the feed) was also investigated. The results showed that
the FAU zeolites significantly affected the precipitates, the
composition of which was shifted from being rich in m-CNB to rich
in p-CNB. Effects of the number of FAU zeolites on the precipitate composition was then studied. The results revealed that the
precipitates from the lower number of the zeolites had higher p-CNB purity than those from the higher number of zeolite.
Abstract: Biochemical Oxygen Demand (BOD) is a measure of
the oxygen used in bacteria mediated oxidation of organic substances
in water and wastewater. Theoretically an infinite time is required for
complete biochemical oxidation of organic matter, but the
measurement is made over 5-days at 20 0C or 3-days at 27 0C test
period with or without dilution. Researchers have worked to further
reduce the time of measurement.
The objective of this paper is to review advancement made in
BOD measurement primarily to minimize the time and negate the
measurement difficulties. Survey of literature review in four such
techniques namely BOD-BARTTM, Biosensors, Ferricyanidemediated
approach, luminous bacterial immobilized chip method.
Basic principle, method of determination, data validation and their
advantage and disadvantages have been incorporated of each of the
methods.
In the BOD-BARTTM method the time lag is calculated for the
system to change from oxidative to reductive state. BIOSENSORS
are the biological sensing element with a transducer which produces
a signal proportional to the analyte concentration. Microbial species
has its metabolic deficiencies. Co-immobilization of bacteria using
sol-gel biosensor increases the range of substrate. In ferricyanidemediated
approach, ferricyanide has been used as e-acceptor instead
of oxygen. In Luminous bacterial cells-immobilized chip method,
bacterial bioluminescence which is caused by lux genes was
observed. Physiological responses is measured and correlated to
BOD due to reduction or emission.
There is a scope to further probe into the rapid estimation of BOD.
Abstract: Ants are fascinating creatures that demonstrate the
ability to find food and bring it back to their nest. Their ability as a
colony, to find paths to food sources has inspired the development of
algorithms known as Ant Colony Systems (ACS). The principle of
cooperation forms the backbone of such algorithms, commonly used
to find solutions to problems such as the Traveling Salesman
Problem (TSP). Ants communicate to each other through chemical
substances called pheromones. Modeling individual ants- ability to
manipulate this substance can help an ACS find the best solution.
This paper introduces a Dynamic Ant Colony System with threelevel
updates (DACS3) that enhance an existing ACS. Experiments
were conducted to observe single ant behavior in a colony of
Malaysian House Red Ants. Such behavior was incorporated into the
DACS3 algorithm. We benchmark the performance of DACS3 versus
DACS on TSP instances ranging from 14 to 100 cities. The result
shows that the DACS3 algorithm can achieve shorter distance in
most cases and also performs considerably faster than DACS.
Abstract: Reactiondiffusion systems are mathematical models that describe how the concentration of one or more substances distributed in space changes under the influence of local chemical reactions in which the substances are converted into each other, and diffusion which causes the substances to spread out in space. The classical representation of a reaction-diffusion system is given by semi-linear parabolic partial differential equations, whose general form is ÔêétX(x, t) = DΔX(x, t), where X(x, t) is the state vector, D is the matrix of the diffusion coefficients and Δ is the Laplace operator. If the solute move in an homogeneous system in thermal equilibrium, the diffusion coefficients are constants that do not depend on the local concentration of solvent and of solutes and on local temperature of the medium. In this paper a new stochastic reaction-diffusion model in which the diffusion coefficients are function of the local concentration, viscosity and frictional forces of solvent and solute is presented. Such a model provides a more realistic description of the molecular kinetics in non-homogenoeus and highly structured media as the intra- and inter-cellular spaces. The movement of a molecule A from a region i to a region j of the space is described as a first order reaction Ai k- → Aj , where the rate constant k depends on the diffusion coefficient. Representing the diffusional motion as a chemical reaction allows to assimilate a reaction-diffusion system to a pure reaction system and to simulate it with Gillespie-inspired stochastic simulation algorithms. The stochastic time evolution of the system is given by the occurrence of diffusion events and chemical reaction events. At each time step an event (reaction or diffusion) is selected from a probability distribution of waiting times determined by the specific speed of reaction and diffusion events. Redi is the software tool, developed to implement the model of reaction-diffusion kinetics and dynamics. It is a free software, that can be downloaded from http://www.cosbi.eu. To demonstrate the validity of the new reaction-diffusion model, the simulation results of the chaperone-assisted protein folding in cytoplasm obtained with Redi are reported. This case study is redrawing the attention of the scientific community due to current interests on protein aggregation as a potential cause for neurodegenerative diseases.
Abstract: An experimental study of anaerobic treatment was performed by hybrid upflow anaerobic sludge blanket (HUASB) reactor to treat produced water (PW) of an onshore crude oil terminal (COD: 1597 mg/L, NH3-N: 14.7 mg/L, phenol: 13.8 mg/L, BOD5: 862 mg/L, sodium: 6240 mg/L and chloride 9530 mg/L). The produced water with high salinity and other toxic substances will inhibit the methanogens performance if there is no adaptation on biomass before anaerobic digestion. COD removal from produced water was investigated at five different dilutions of produced water and tap water (TW) without any nutrient addition and pre-treatment. The dilution ratios were 1PW:4TW, 2PW:3TW, 3PW:2TW, 4PW:1TW and 5PW:0TW. The reactor was evaluated at mesophilic operating condition (35 ± 2 °C) at 5 days of HRT for 250 days continuous feed. The average COD removals for 1PW:4TW, 2PW:3TW, 3PW:2TW, 4PW:1TW and 5PW:0TW were found to be approximately 76.1%, 73.8%, 70.3%, 46.3% and 61.82% respectively, with final average effluent COD of 123.7 mg/L, 240 mg/L, 294 mg/L, 589 mg/L and 738 mg/L, respectively.