Abstract: Pentachlorophenol (PCP) is a polychlorinated
aromatic compound that is widespread in industrial effluents and is
considered to be a serious pollutant. Among the variety of industrial
effluents encountered, effluents from tanning industry are very
important and have a serious pollution potential. PCP is also formed
unintentionally in effluents of paper and pulp industries. It is highly
persistent in soils and is lethal to a wide variety of beneficial
microorganisms and insects, human beings and animals. The natural
processes that breakdown toxic chemicals in the environment have
become the focus of much attention to develop safe and environmentfriendly
deactivation technologies. Microbes and plants are among
the most important biological agents that remove and degrade waste
materials to enable their recycling in the environment. The present
investigation was carried out with the aim of developing a microbial
system for bioremediation of PCP polluted soils. A number of plant
species were evaluated for their ability to tolerate different
concentrations of pentachlorophenol (PCP) in the soil. The
experiment was conducted for 30 days under pot culture conditions.
The toxic effect of PCP on plants was studied by monitoring seed
germination, plant growth and biomass. As the concentration of PCP
was increased to 50 ppm, the inhibition of seed germination, plant
growth and biomass was also increased. Although PCP had a
negative effect on all plant species tested, maize and groundnut
showed the maximum tolerance to PCP. Other tolerating crops
included wheat, safflower, sunflower, and soybean. From the
rhizosphere soil of the tolerant seedlings, as many as twenty seven
PCP tolerant bacteria were isolated. From soybean, 8; sunflower, 3;
safflower 8; maize 2; groundnut and wheat, 3 each isolates were
made. They were screened for their PCP degradation potentials.
HPLC analyses of PCP degradation revealed that the isolate MAZ-2
degraded PCP completely. The isolate MAZ-1 was the next best
isolate with 90 per cent PCP degradation. These strains hold promise
to be used in the bioremediation of PCP polluted soils.
Abstract: Chicken feathers were used as biosorbent for Pb
removal from aqueous solution. In this paper, the kinetics and
equilibrium studies at several pH, temperature, and metal
concentration values are reported. For tested conditions, the Pb
sorption capacity of this poultry waste ranged from 0.8 to 8.3 mg/g.
Optimal conditions for Pb removal by chicken feathers have been
identified. Pseudo-first order and pseudo-second order equations
were used to analyze the experimental data. In addition, the sorption
isotherms were fitted to classical Langmuir and Freundlich models.
Finally, thermodynamic parameters for the sorption process have
been determined. In summary, the results showed that chicken
feathers are an alternative and promising sorbent for the treatment of
effluents polluted by Pb ions.
Abstract: The aim of the study was to investigate whether there
is the promotion of product ecodesign measures as a result of
adopting ISO 14001 certification in manufacturing companies in the
Republic of Slovenia. Companies gave the most of their product
development attention to waste and energy reduction during
manufacturing process and reduction of material consumption per
unit of product. Regarding the importance of different ecodesign
criteria reduction of material consumption per unit of product was
reported as the most important criterion. Less attention is paid to endof-
life issues considering recycling or packaging. Most
manufacturing enterprises considered ISO 14001 standard as a very
useful tool or at least a useful tool helping them to accelerate and
establish product ecodesign activities. Two most frequently
considered ecodesign drivers are increased competitive advantage
and legal requirements and two most important barriers are high
development costs and insufficient market demand.
Abstract: Recycling of aluminum alloys often decrease fluidity,
consequently influence the castability of the alloy. In this study, the
fluidity of Al-Zn alloys, such as the standard A713 alloy with and
without scrap addition has been investigated. The scrap added was
comprised of contaminated alloy turning chips. Fluidity
measurements were performed with double spiral fluidity test
consisting of gravity casting of double spirals in green sand moulds
with good reproducibility. The influence of recycled alloy on fluidity
has been compared with that of the virgin alloy and the results
showed that the fluidity decreased with the increase in recycled alloy
at minimum pouring temperatures. Interestingly, an appreciable
improvement in the fluidity was observed at maximum pouring
temperature, especially for coated spirals.
Abstract: This research studied recycled wastes by Recyclable Material Bank project of 17 universities of Thailand for evaluation of reducing greenhouse gasses emission compared with landfilling activity during January 2011 to December 2011. The results showed that the projects collected total amount of recyclable wastes about 1,626.917 metric ton. The office paper has the largest amount among these recycled wastes (55.61 % of total recycled wastes). Groups of recycled waste can be prioritized from high to low according to their amount as paper, plastic, glass, mixed recyclables and metal, respectively. The project reduced greenhouse gasses emission equivalent to about 5,263.481 metric ton of carbon dioxide. The most significant recycled waste that affects the reduction of greenhouse gasses emission is office paper which is 73.45% of total reduced greenhouse gasses emission. According to amount of reduced greenhouse gasses emission, groups of recycled waste can be prioritized from high to low significances as paper, plastic, metal, mixed recyclables and glass, respectively.
Abstract: Plastic waste is a big issue in Thailand, but the amount of recycled plastic in Thailand is still low due to the high investment and operating cost. Hence, the rest of plastic waste are burnt to destroy or sent to the landfills. In order to be financial viable, an effective reverse logistics infrastructure is required to support the product recovery activities. However, there is a conflict between reducing the cost and raising environmental protection level. The purpose of this study is to build a goal programming (GP) so that it can be used to help analyze the proper planning of the Thailand-s plastic recycling system that involves multiple objectives. This study considers three objectives; reducing total cost, increasing the amount of plastic recovery, and raising the desired plastic materials in recycling process. The results from two priority structures show that it is necessary to raise the total cost budget in order to achieve targets on amount of recycled plastic and desired plastic materials.
Abstract: The study and development of an innovative material
for building insulation is really important for a sustainable society in order to improve comfort and reducing energy consumption. The aim of this work is the development of insulating panels for
sustainable buildings based on an innovative material made by
cardboard and Phase Change Materials (PCMs).
The research has consisted in laboratory tests whose purpose has been the obtaining of the required properties for insulation panels: lightweight, porous structures and mechanical resistance. PCMs have been used for many years in the building industry as
smart insulation technology because of their properties of storage and release high quantity of latent heat at useful specific temperatures [1]- [2].
The integration of PCMs into cellulose matrix during the waste paper recycling process has been developed in order to obtain a
composite material.
Experiments on the productive process for the realization of insulating panels were done in order to make the new material
suitable for building application. The addition of rising agents
demonstrated the possibility to obtain a lighter structure with better
insulation properties.
Several tests were conducted to verify the new panel properties. The results obtained have shown the possibility to realize an
innovative and sustainable material suitable to replace insulating panels currently used.
Abstract: Thermo-chemical treatment (TCT) such as pyrolysis
is getting recognized as a valid route for (i) materials and valuable
products and petrochemicals recovery; (ii) waste recycling; and (iii)
elemental characterization. Pyrolysis is also receiving renewed
attention for its operational, economical and environmental
advantages. In this study, samples of polyethylene terephthalate
(PET) and polystyrene (PS) were pyrolysed in a microthermobalance
reactor (using a thermogravimetric-TGA setup). Both
polymers were prepared and conditioned prior to experimentation.
The main objective was to determine the kinetic parameters of the
depolymerization reactions that occur within the thermal degradation
process. Overall kinetic rate constants (ko) and activation energies
(Eo) were determined using the general kinetics theory (GKT)
method previously used by a number of authors. Fitted correlations
were found and validated using the GKT, errors were within ± 5%.
This study represents a fundamental step to pave the way towards the
development of scaling relationship for the investigation of larger
scale reactors relevant to industry.
Abstract: Water recycling represents an important challenge for many countries, in particular in countries where this natural resource is rare. On the other hand, in many operations, water is used as a cooling medium, as a high proportion of water consumed in industry is used for cooling purposes. Generally this water is rejected directly to the nature. This reject will cause serious environment damages as well as an important waste of this precious element.. On way to solve these problems is to reuse and recycle this warm water, through the use of natural cooling medium, such as air in a heat exchanger unit, known as a cooling tower. A poor performance, design or reliability of cooling towers will result in lower flow rate of cooling water an increase in the evaporation of water, an hence losses of water and energy. This paper which presents an experimental investigate of thermal and hydraulic performances of a mechanical cooling tower, enables to show that the water evaporation rate, Mev, increases with an increase in the air and water flow rates, as well as inlet water temperature and for fixed air flow rates, the pressure drop (ΔPw/Z) increases with increasing , L, due to the hydrodynamic behavior of the air/water flow.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.
Abstract: Proper management of residues originated from
industrial activities is considered as one of the serious challenges
faced by industrial societies due to their potential hazards to the
environment. Common disposal methods for industrial solid wastes
(ISWs) encompass various combinations of solely management
options, i.e. recycling, incineration, composting, and sanitary
landfilling. Indeed, the procedure used to evaluate and nominate the
best practical methods should be based on environmental, technical,
economical, and social assessments. In this paper an environmentaltechnical
assessment model is developed using analytical network
process (ANP) to facilitate the decision making practice for ISWs
generated at Gilan province, Iran. Using the results of performed
surveys on industrial units located at Gilan, the various groups of
solid wastes in the research area were characterized, and four
different ISW management scenarios were studied. The evaluation
process was conducted using the above-mentioned model in the
Super Decisions software (version 2.0.8) environment. The results
indicates that the best ISW management scenario for Gilan province
is consist of recycling the metal industries residues, composting the
putrescible portion of ISWs, combustion of paper, wood, fabric and
polymeric wastes as well as energy extraction in the incineration
plant, and finally landfilling the rest of the waste stream in addition
with rejected materials from recycling and compost production plants
and ashes from the incineration unit.
Abstract: Aluminum alloy sheets have several advantages such
as the lightweight, high-specific strength and recycling efficiency.
Therefore, aluminum alloy sheets in sheet forming have been used in various areas as automotive components and so forth. During the
process of sheet forming, wrinkling which is caused by compression stress might occur and the formability of sheets was affected by
occurrence of wrinkling. A few studies of uniaxial compressive test by
using square tubes, pipes and sheets were carried out to clarify the each wrinkling behavior. However, on uniaxial compressive test,
deformation behavior of the sheets hasn-t be cleared. Then, it is necessary to clarify the relationship between the buckling behavior
and the forming conditions. In this study, the effect of dimension of the sheet in the buckling behavior on compression test of aluminum alloy sheet was cleared by experiment and FEA. As the results, the buckling
deformation was classified by three modes in terms of the distribution of equivalent plastic strain.
Abstract: Focusing on the environmental issues, including the reduction of scrap and consumer residuals, along with the benefiting from the economic value during the life cycle of goods/products leads the companies to have an important competitive approach. The aim of this paper is to present a new mixed nonlinear facility locationallocation model in recycling collection networks by considering multi-echelon, multi-suppliers, multi-collection centers and multifacilities in the recycling network. To make an appropriate decision in reality, demands, returns, capacities, costs and distances, are regarded uncertain in our model. For this purpose, a fuzzy mathematical programming-based possibilistic approach is introduced as a solution methodology from the recent literature to solve the proposed mixed-nonlinear programming model (MNLP). The computational experiments are provided to illustrate the applicability of the designed model in a supply chain environment and to help the decision makers to facilitate their analysis.
Abstract: In recent years, environment regulation forcing
manufactures to consider recovery activity of end-of- life products
and/or return products for refurbishing, recycling,
remanufacturing/repair and disposal in supply chain management. In
this paper, a mathematical model is formulated for single product
production-inventory system considering remanufacturing/reuse of
return products and rate of return products follows a demand like
function, dependent on purchasing price and acceptance quality level.
It is useful in decision making to determine whether to go for
remanufacturing or disposal of returned products along with newly
produced products to satisfy a stationary demand. In addition, a
modified genetic algorithm approach is proposed, inspired by particle
swarm optimization method. Numerical analysis of the case study is
carried out to validate the model.
Abstract: In the paper the method of product analysis from
recycling point of view has been described. The analysis bases on set
of measures that assess a product from the point of view of final
stages of its lifecycle. It was assumed that such analysis will be
performed at the design phase – in order to conduct such analysis the
computer system that aids the designer during the design process has
been developed. The structure of the computer tool, based on agent
technology, and example results has been also included in the paper.
Abstract: Thermochemcial characteristics of powder fabricated
using oxidation treatment of spent PWR fuel and SIMFUEL were
evaluated for recycling of spent fuel such as DUPIC process.
Especially, the influence of spent fuel burn-ups on the powder
fabrication characteristics was experimentally evaluated, ranging from
27,300 to 65,000 MWd/tU. Densities of powder manufactured from an
oxidation, OREOX and the milling processes at the same process
conditions were compared as a function of the fuel burn-ups
respectively. Also, based on chemical analysis results, homogeneity of
fissile elements in oxidized powder was confirmed.
Abstract: The recycling process of Tungsten alloy (Swarf) by
oxidation reduction technique have been investigated. The reduced
powder was pressed under a pressure 20Kg/cm2 and sintered at
1150°C in dry hydrogen atmosphere. The particle size of the recycled
alloy powder was 1-3 μm and the shape was regular at a reduction
temperature 800°C. The chemical composition of the recycled alloy
is the same as the primary Swarf.
Abstract: A study of various turbulent inflow generation methods
was performed to compare their relative effectiveness for LES
computations of turbulent boundary layers. This study confirmed
the quality of the turbulent information produced by the family of
recycling and rescaling methods which take information from within
the computational domain. Furthermore, more general inflow methods
also proved applicable to such simulations, with a precursor-like
inflow and a random inflow augmented with forcing planes showing
promising results.
Abstract: Road industry has challenged the prospect of ecoconstruction. Pavements may fit within the framework of sustainable development. Hence, research implements assessments of conventional pavements impacts on environment in use of life cycle approach. To meet global, and often national, targets on pollution control, newly introduced pavement designs are under study. This is the case of Cyprus demonstration, which occurred within EcoLanes project work. This alternative pavement differs on concrete layer reinforced with tire recycling product. Processing of post-consumer tires produces steel fibers improving strength capacity against cracking. Thus maintenance works are relevantly limited in comparison to flexible pavement. This enables to be more ecofriendly, referenced to current study outputs. More specific, proposed concrete pavement life cycle processes emits 15 % less air pollutants and consumes 28 % less embodied energy than those of the asphalt pavement. In addition there is also a reduction on costs by 0.06 %.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.