Abstract: Ground-level tropospheric ozone is one of the air
pollutants of most concern. It is mainly produced by photochemical
processes involving nitrogen oxides and volatile organic compounds
in the lower parts of the atmosphere. Ozone levels become
particularly high in regions close to high ozone precursor emissions
and during summer, when stagnant meteorological conditions with
high insolation and high temperatures are common.
In this work, some results of a study about urban ozone
distribution patterns in the city of Badajoz, which is the largest and
most industrialized city in Extremadura region (southwest Spain) are
shown. Fourteen sampling campaigns, at least one per month, were
carried out to measure ambient air ozone concentrations, during
periods that were selected according to favourable conditions to
ozone production, using an automatic portable analyzer.
Later, to evaluate the ozone distribution at the city, the measured
ozone data were analyzed using geostatistical techniques. Thus, first,
during the exploratory analysis of data, it was revealed that they were
distributed normally, which is a desirable property for the subsequent
stages of the geostatistical study. Secondly, during the structural
analysis of data, theoretical spherical models provided the best fit for
all monthly experimental variograms. The parameters of these
variograms (sill, range and nugget) revealed that the maximum
distance of spatial dependence is between 302-790 m and the
variable, air ozone concentration, is not evenly distributed in reduced
distances. Finally, predictive ozone maps were derived for all points
of the experimental study area, by use of geostatistical algorithms
(kriging). High prediction accuracy was obtained in all cases as
cross-validation showed. Useful information for hazard assessment
was also provided when probability maps, based on kriging
interpolation and kriging standard deviation, were produced.
Abstract: This paper puts forward one kind of air-fuel ratio
control method with PI controller. With the help of
MATLAB/SIMULINK software, the mathematical model of air-fuel
ratio control system for distributorless CNG engine is constructed.
The objective is to maintain cylinder-to-cylinder air-fuel ratio at a
prescribed set point, determined primarily by the state of the Three-
Way-Catalyst (TWC), so that the pollutants in the exhaust are
removed with the highest efficiency. The concurrent control of airfuel
under transient conditions could be implemented by Proportional
and Integral (PI) controller. The simulation result indicates that the
control methods can easily eliminate the air/fuel maldistribution and
maintain the air/fuel ratio at the stochiometry within minimum
engine events.
Abstract: Atmospheric stability plays the most important role in
the transport and dispersion of air pollutants. Different methods are
used for stability determination with varying degrees of complexity.
Most of these methods are based on the relative magnitude of
convective and mechanical turbulence in atmospheric motions.
Richardson number, Monin-Obukhov length, Pasquill-Gifford
stability classification and Pasquill–Turner stability classification, are
the most common parameters and methods. The Pasquill–Turner
Method (PTM), which is employed in this study, makes use of
observations of wind speed, insolation and the time of day to classify
atmospheric stability with distinguishable indices. In this study, a
model is presented to determination of atmospheric stability
conditions using PTM. As a case study, meteorological data of
Mehrabad station in Tehran from 2000 to 2005 is applied to model.
Here, three different categories are considered to deduce the pattern
of stability conditions. First, the total pattern of stability classification
is obtained and results show that atmosphere is 38.77%, 27.26%,
33.97%, at stable, neutral and unstable condition, respectively. It is
also observed that days are mostly unstable (66.50%) while nights are
mostly stable (72.55%). Second, monthly and seasonal patterns are
derived and results indicate that relative frequency of stable
conditions decrease during January to June and increase during June
to December, while results for unstable conditions are exactly in
opposite manner. Autumn is the most stable season with relative
frequency of 50.69% for stable condition, whilst, it is 42.79%,
34.38% and 27.08% for winter, summer and spring, respectively.
Hourly stability pattern is the third category that points out that
unstable condition is dominant from approximately 03-15 GTM and
04-12 GTM for warm and cold seasons, respectively. Finally,
correlation between atmospheric stability and CO concentration is
achieved.
Abstract: A unique combination of adsorption and
electrochemical regeneration with a proprietary adsorbent material
called Nyex 100 was introduced at the University of Manchester for
waste water treatment applications. Nyex 100 is based on graphite
intercalation compound. It is non porous and electrically conducing
adsorbent material. This material exhibited very small BET surface
area i.e. 2.75 m2g-1, in consequence, small adsorptive capacities for
the adsorption of various organic pollutants were obtained. This work
aims to develop composite adsorbent material essentially capable of
electrochemical regeneration coupled with improved adsorption
characteristics. An organic dye, acid violet 17 was used as standard
organic pollutant. The developed composite material was
successfully electrochemically regenerated using a DC current of 1 A
for 60 minutes. Regeneration efficiency was maintained at around
100% for five adsorption-regeneration cycles.
Abstract: The Beshar River is one aquatic ecosystem, which is
located next to the city of Yasuj in southern Iran. The Beshar river
has been contaminated by industrial factories such as effluent of
sugar factory, agricultural and other activities in this region such as,
Imam Sajjad hospital, drainage from agricultural farms, Yasuj urban
surface runoff and effluent of wastewater treatment plants ,specially
Yasuj waste water treatment plant. In order to evaluate the effects of
these pollutants on the quality of the Beshar river, five monitoring
stations were selected along its course. The first station is located
upstream of Yasuj near the Dehnow village; stations 2 to 4 are
located east, south and west of city; and the 5th station is located
downstream of Yasuj. Several water quality parameters were
sampled. These include pH, dissolved oxygen, biological oxygen
demand (BOD), temperature, conductivity, turbidity, total dissolved
solids and discharge or flow measurements. Water samples from the
five stations were collected and analyzed to determine the following
physicochemical parameters: EC, pH, T.D.S, T.H, No2, DO, BOD5,
COD during 2008 to 2010. The study shows that the BOD5 value of
station 1 is at a minimum (1.7 ppm) and increases downstream from
stations 2 to 4 to a maximum (11.6 ppm), and then decreases at
station 5. The DO values of station 1 is a maximum (8.45 ppm),
decreases downstream to stations 2 - 4 which are at a minimum (3.1
ppm), before increasing at station 5. The amount of BOD and TDS
are highest at the 4th station and the amount of DO is lowest at this
station, marking the 4th station as more highly polluted than the
other stations .This study shows average amount of the water quality
parameters in first year of sampling (2008) have had a better quality
relation to third year in 2010 because of recent drought in this region
and pollutant increasing .As the Beshar river path after 5th station
goes through the mountain area with more slope and flow velocity
,so the physicochemical parameters improve at the 5th station due to
pollutant degradation and dilution. Finally the point and nonpoint
pollutant sources of Beshar river were determined and compared to
the monitoring results.
Abstract: Data envelopment analysis (DEA) has gained great popularity in environmental performance measurement because it can provide a synthetic standardized environmental performance index when pollutants are suitably incorporated into the traditional DEA framework. Since some of the environmental performance indicators cannot be controlled by companies managers, it is necessary to develop the model in a way that it could be applied when discretionary and/or non-discretionary factors were involved. In this paper, we present a semi-radial DEA approach to measuring environmental performance, which consists of non-discretionary factors. The model, then, has been applied on a real case.
Abstract: Nanophotocatalysts such as titanium (TiO2), zinc (ZnO), and iron (Fe2O3) oxides can be used in organic pollutants oxidation, and in many other applications. But among the challenges for technological application (scale-up) of the nanotechnology scientific developments two aspects are still little explored: research on environmental risk of the nanomaterials preparation methods, and the study of nanomaterials properties and/or performance variability. The environmental analysis was performed for six different methods of ZnO nanoparticles synthesis, and showed that it is possible to identify the more environmentally compatible process even at laboratory scale research. The obtained ZnO nanoparticles were tested as photocatalysts, and increased the degradation rate of the Rhodamine B dye up to 30 times.
Abstract: “Garbage enzyme", a fermentation product of kitchen waste, water and brown sugar, is claimed in the media as a multipurpose solution for household and agricultural uses. This study assesses the effects of dilutions (5% to 75%) of garbage enzyme in reducing pollutants in domestic wastewater. The pH of the garbage enzyme was found to be 3.5, BOD concentration about 150 mg/L. Test results showed that the garbage enzyme raised the wastewater-s BOD in proportion to its dilution due to its high organic content. For mixtures with more than 10% garbage enzyme, its pH remained acidic after the 5-day digestion period. However, it seems that ammonia nitrogen and phosphorus could be removed by the addition of the garbage enzyme. The most economic solution for removal of ammonia nitrogen and phosphorus was found to be 9%. Further tests are required to understand the removal mechanisms of the ammonia nitrogen and phosphorus.
Abstract: Eutrophication of surface water is one of the most
widespread environmental problems at present. Large number of
pilgrims and tourists visit sacred artificial tank known as “Brahma
Sarover” located at Kurukshetra, India to take holy dip and perform
religious ceremonies. The sources of pollutants include impurities in
feed water, mass bathing, religious offerings and windblown
particulate matter. Studies so far have focused mainly on assessing
water quality for bathing purpose by using physico-chemical and
bacteriological parameters. No effort has been made to assess nutrient
concentration and trophic status of the tank to take more appropriate
measures for improving water quality on long term basis. In the
present study, total nitrogen, total phosphorous and chlorophyll a
measurements have been done to assess the nutrient level and trophic
status of the tank. The results show presence of high concentration of
nutrients and Chlorophyll a indicating mesotrophic and eutrophic
state of the tank. Phosphorous has been observed as limiting nutrient
in the tank water.
Abstract: Ciprofloxacin (CIP) and Carbamazepine (CBZ), nonbiodegradable pharmaceutical residues, were become emerging pollutants in several aquatic environments. The objectives of this research were to study the possibility to recover these pharmaceuticals residues from pharmaceutical wastewater by increasing the selective adsorption on synthesized functionalized porous silicate, comparing with powdered activated carbon (PAC). Hexagonal mesoporous silicate (HMS), functionalized HMSs (3- aminopropyltriethoxy, 3- mercaptopropyltrimethoxy and noctyldimethyl) were synthesized and characterized physico-chemical characteristics. Obtained adsorption kinetics and isotherms showed that 3-mercaptopropyltrimethoxy functional groups grafted on HMS provided highest CIP and CBZ adsorption capacities; however, it was still lower than that of PAC. The kinetic results were compatible with pseudo-second order. The hydrophobicity and hydrogen bonding might play a key role on the adsorption. Furthermore, the capacities were affected by varying pH values due to the strength of hydrogen bonding between targeted compounds and adsorbents. Electrostatic interaction might not affect the adsorption capacities.
Abstract: Environmental contamination is a common problem in ex-industrial and industrial sites. This article gives a brief description of general applied environmental investigation methodologies and possible remediation applications in Latvia. Most of contaminated areas are situated in former and active industrial, military areas and ports. Industrial and logistic activities very often have been with great impact for more than hundred years thus the contamination level with heavy metals, hydrocarbons, pesticides, persistent organic pollutants is high and is threatening health and environment in general. 242 territories now are numbered as contaminated and fixed in the National Register of contaminated territories in Latvia. Research and remediation of contamination in densely populated areas are of important environmental policy domain. Four different investigation case studies of contaminated areas are given describing the history of use, environmental quality assessment as well as planned environmental management actions. All four case study locations are situated in Riga - the capital of the Republic of Latvia. The aim of this paper is to analyze the situation and problems with management of contaminated areas in Latvia, give description of field research methods and recommendations for remediation industry based on scientific data and innovations.
Abstract: The increased use of biodiesel implies variations on both greenhouse gases and air pollutant emissions. Some studies point out that the use of biodiesel blends on diesel can help in controlling air pollution and promote a reduction of CO2 emissions. Reductions on PM, SO2, VOC and CO emissions are also expected, however NOx emissions may increase, which may potentiate O3 formation. This work aims to assess the impact of the biodiesel use on air quality, through a numerical modeling study, taking the Northern region of Portugal as a case study. The emission scenarios are focused on 2008 (baseline year) and 2020 (target year of Renewable Energy Directive-RED) and on three biodiesel blends (B0, B10 and B20). In a general way the use of biodiesel by 2020 will reduce the CO2 and air pollutants emissions in the Northern Portugal, improving air quality. However it will be in a very small extension.
Abstract: The pollution of sediments sampled from the North
Port by polycyclic aromatic hydrocarbons (PAHs) was investigated.
Concentrations of PAHs estimated in the port sediments ranged from
199 to 2851.2 μg/kg dw. The highest concentration was found which
is closed to the Berth line, this locations affected by intensive
shipping activities and Land based runoff and they were dominated
by the high molecular weight PAHs (4–6- rings). Source
identification showed that PAHs originated mostly from the
pyrogenic source either from the combustion of fossil fuels, grass,
wood and coal (majority of the samples). Ecological Risk Assessment
on the port sediments presented that slightly adverse ecological
effects to biological community are expected to occur at the vicinity
of the stations 1 and 4. Thus PAHs are not considered as pollutants of
concern in the North Port.
Abstract: As a part of the development of a numerical method of
close capture exhausts systems for machining devices, a test rig
recreating a situation similar to a grinding operation, but in a
perfectly controlled environment, is used. The properties of the
obtained spray of solid particles are initially characterized using
particle tracking velocimetry (PTV), in order to obtain input and
validation parameters for numerical simulations. The dispersion of a
tracer gas (SF6) emitted simultaneously with the particle jet is then
studied experimentally, as the dispersion of such a gas is
representative of that of finer particles, whose aerodynamic response
time is negligible. Finally, complete modeling of the test rig is
achieved to allow comparison with experimental results and thus to
progress towards validation of the models used to describe a twophase
flow generated by machining operation.
Abstract: This paper presents the experimental results of
leakage current waveforms which appears on porcelain insulator
surface due to existence of artificial pollutants. The tests have been
done using the chemical compounds of NaCl, Na2SiO3, H2SO4, CaO,
Na2SO4, KCl, Al2SO4, MgSO4, FeCl3, and TiO2. The insulator
surface was coated with those compounds and dried. Then, it was
tested in the chamber where the high voltage was applied. Using
correspondence analysis, the result indicated that the fundamental
harmonic of leakage current was very close to the applied voltage
and third harmonic leakage current was close to the yielded leakage
current amplitude. The first harmonic power was correlated to first
harmonic amplitude of leakage current, and third harmonic power
was close to third harmonic one. The chemical compounds of H2SO4
and Na2SiO3 affected to the power factor of around 70%. Both are the
most conductive, due to the power factor drastically increase among
the chemical compounds.
Abstract: Understanding of how and where NOx formation
occurs in industrial burner is very important for efficient and clean
operation of utility burners. Also the importance of this problem is
mainly due to its relation to the pollutants produced by more burners
used widely of gas turbine in thermal power plants and glass and steel
industry.
In this article, a numerical model of an industrial burner operating
in MILD combustion is validated with experimental data.. Then
influence of air flow rate and air temperature on combustor
temperature profiles and NOX product are investigated. In order to
modification this study reports on the effects of fuel and air dilution
(with inert gases H2O, CO2, N2), and also influence of lean-premixed
of fuel, on the temperature profiles and NOX emission.
Conservation equations of mass, momentum and energy, and
transport equations of species concentrations, turbulence, combustion
and radiation modeling in addition to NO modeling equations were
solved together to present temperature and NO distribution inside the
burner.
The results shows that dilution, cause to a reduction in value of
temperature and NOX emission, and suppresses any flame
propagation inside the furnace and made the flame inside the furnace
invisible. Dilution with H2O rather than N2 and CO2 decreases further
the value of the NOX. Also with raise of lean-premix level, local
temperature of burner and the value of NOX product are decreases
because of premixing prevents local “hot spots" within the combustor
volume that can lead to significant NOx formation. Also leanpremixing
of fuel with air cause to amount of air in reaction zone is
reach more than amount that supplied as is actually needed to burn
the fuel and this act lead to limiting NOx formation
Abstract: There is a complex situation on the transport environment in the cities of the world. For the analysis and prevention of environmental problems an accurate calculation hazardous substances concentrations at each point of the investigated area is required. In the turbulent atmosphere of the city the wellknown methods of mathematical statistics for these tasks cannot be applied with a satisfactory level of accuracy. Therefore, to solve this class of problems apparatus of mathematical physics is more appropriate. In such models, because of the difficulty as a rule the influence of uneven land surface on streams of air masses in the turbulent atmosphere of the city are not taken into account. In this paper the influence of the surface roughness, which can be quite large, is mathematically shown. The analysis of this problem under certain conditions identified the possibility of areas appearing in the atmosphere with pressure tending to infinity, i.e. so-called "wall effect".
Abstract: The Bangalore City is facing the acute problem of
pollution in the atmosphere due to the heavy increase in the traffic
and developmental activities in recent years. The present study is an
attempt in the direction to assess trend of the ambient air quality
status of three stations, viz., AMCO Batteries Factory, Mysore Road,
GRAPHITE INDIA FACTORY, KHB Industrial Area, Whitefield
and Ananda Rao Circle, Gandhinagar with respect to some of the
major criteria pollutants such as Total Suspended particular matter
(SPM), Oxides of nitrogen (NOx), and Oxides of sulphur (SO2). The
sites are representative of various kinds of growths viz., commercial,
residential and industrial, prevailing in Bangalore, which are
contributing to air pollution. The concentration of Sulphur Dioxide
(SO2) at all locations showed a falling trend due to use of refined
petrol and diesel in the recent years. The concentration of Oxides of
nitrogen (NOx) showed an increasing trend but was within the
permissible limits. The concentration of the Suspended particular
matter (SPM) showed the mixed trend. The correlation between
model and observed values is found to vary from 0.4 to 0.7 for SO2,
0.45 to 0.65 for NOx and 0.4 to 0.6 for SPM. About 80% of data is
observed to fall within the error band of ±50%. Forecast test for the
best fit models showed the same trend as actual values in most of the
cases. However, the deviation observed in few cases could be
attributed to change in quality of petro products, increase in the
volume of traffic, introduction of LPG as fuel in many types of
automobiles, poor condition of roads, prevailing meteorological
conditions, etc.
Abstract: This paper presents the study of parameters affecting
the environment protection in the printing industry. The paper has
also compared LCA studies performed within the printing industry in
order to identify common practices, limitations, areas for
improvement, and opportunities for standardization. This comparison
is focused on the data sources and methodologies used in the printing
pollutants register. The presented concepts, methodology and results
represent the contribution to the sustainable development
management. Furthermore, the paper analyzes the result of the
quantitative identification of hazardous substances emitted in printing
industry of Novi Sad.
Abstract: Soil washing process with a surfactant solution is a potential technology for the rapid removal of hydrophobic organic compound (HOC) from soil. However, large amount of washed water would be produced during operation and this should be treated effectively by proper methods. The soil washed water for complex contaminated site with HOC and heavy metals might contain high amount of pollutants such as HOC and heavy metals as well as used surfactant. The heavy metals in the soil washed water have toxic effects on microbial activities thus these should be removed from the washed water before proceeding to a biological waste-water treatment system. Moreover, the used surfactant solutions are necessary to be recovered for reducing the soil washing operation cost. In order to simultaneously remove the heavy metals and HOC from soil-washed water, activated carbon (AC) was used in the present study. In an anionic-nonionic surfactant mixed solution, the Cd(II) and phenanthrene (PHE) were effectively removed by adsorption on activated carbon. The removal efficiency for Cd(II) was increased from 0.027 mmol-Cd/g-AC to 0.142 mmol-Cd/g-AC as the mole ratio of SDS increased in the presence of PHE. The adsorptive capacity of PHE was also increased according to the SDS mole ratio due to the decrement of molar solubilization ratios (MSR) for PHE in an anionic-nonionic surfactant mixture. The simultaneous adsorption of HOC and cationic heavy metals using activated carbon could be a useful method for surfactant recovery and the reduction of heavy metal toxicity in a surfactant-enhanced soil washing process.