Abstract: This report shows the performance of composite
biodegradable film from chitosan, starch and sawdust fiber. The main
objectives of this research are to fabricate and characterize composite
biodegradable film in terms of morphology and physical properties.
The film was prepared by casting method. Sawdust fiber was used as
reinforcing agent and starch as polymer matrix in the casting
solution. The morphology of the film was characterized using atomic
force microscope (AFM). The result showed that the film has
smooth structure. Chemical composition of the film was investigated
using Fourier transform infrared (FTIR) where the result revealed
present of starch in the film. The thermal properties were
characterized using thermal gravimetric analyzer (TGA) and
differential scanning calorimetric (DSC) where the results showed
that the film has small difference in melting and degradation
temperature.
Abstract: Multiphase flow transport in porous medium is very common and significant in science and engineering applications. For example, in CO2 Storage and Enhanced Oil Recovery processes, CO2 has to be delivered to the pore spaces in reservoirs and aquifers. CO2 storage and enhance oil recovery are actually displacement processes, in which oil or water is displaced by CO2. This displacement is controlled by pore size, chemical and physical properties of pore surfaces and fluids, and also pore wettability. In this study, a technique was developed to measure the pressure profile for driving gas/liquid to displace water in pores. Through this pressure profile, the impact of pore size on the multiphase flow transport and displacement can be analyzed. The other rig developed can be used to measure the static and dynamic pore wettability and investigate the effects of pore size, surface tension, viscosity and chemical structure of liquids on pore wettability.
Abstract: This study was conducted in order to determine the physical properties and stability of mayonnaise-like emulsions as affected by modified yam starches. Native yam starch was modified via pre-gelatinization and cross-linking phosphorylation procedures. The emulsions (50% oil dispersed phase) were prepared with 0.3% native potato, native yam, pre-gelatinized yam and cross-linking phosphorylation yam starches. The droplet size of surface weighted mean diameter was found to be significantly (p < 0.05) lower in the sample with cross-linking phosphorylation yam starch as compared to other samples. Moreover, the viscosity of the sample with pregelatinized yam starch was observed to be higher than that of other samples. The phase separation stability was low in the freshly prepared and stored (45 days, 5°C) emulsions containing native yam starch. This study thus generally suggested that modified yam starches were more suitable (i.e. better physical properties and stability) to be used as stabilizers in a similar system i.e. light mayonnaises, rather than a native yam starch.
Abstract: In the present work, we have developed a symmetric electrochemical capacitor based on the nanostructured iron oxide (Fe3O4)-activated carbon (AC) nanocomposite materials. The physical properties of the nanocomposites were characterized by Scanning Electron Microscopy (SEM) and Brunauer-Emmett-Teller (BET) analysis. The electrochemical performances of the composite electrode in 1.0 M Na2SO3 and 1.0 M Na2SO4 aqueous solutions were evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The composite electrode with 4 wt% of iron oxide nanomaterials exhibits the highest capacitance of 86 F/g. The experimental results clearly indicate that the incorporation of iron oxide nanomaterials at low concentration to the composite can improve the capacitive performance, mainly attributed to the contribution of the pseudocapacitance charge storage mechanism and the enhancement on the effective surface area of the electrode. Nevertheless, there is an optimum threshold on the amount of iron oxide that needs to be incorporated into the composite system. When this optimum threshold is exceeded, the capacitive performance of the electrode starts to deteriorate, as a result of the undesired particle aggregation, which is clearly indicated in the SEM analysis. The electrochemical performance of the composite electrode is found to be superior when Na2SO3 is used as the electrolyte, if compared to the Na2SO4 solution. It is believed that Fe3O4 nanoparticles can provide favourable surface adsorption sites for sulphite (SO3 2-) anions which act as catalysts for subsequent redox and intercalation reactions.
Abstract: The temperature distribution and the heat transfer
rates through a multi-layer door of a furnace were investigated. The
inside of the door was in contact with hot air and the other side of the
door was in contact with room air. Radiation heat transfer from the
walls of the furnace to the door and the door to the surrounding area
was included in the problem. This work is a two dimensional steady
state problem. The Churchill and Chu correlation was used to find
local convection heat transfer coefficients at the surfaces of the
furnace door. The thermophysical properties of air were the functions
of the temperatures. Polynomial curve fitting for the fluid properties
were carried out. Finite difference method was used to discretize for
conduction heat transfer within the furnace door. The Gauss-Seidel
Iteration was employed to compute the temperature distribution in
the door.
The temperature distribution in the horizontal mid plane of the
furnace door in a two dimensional problem agrees with the one
dimensional problem. The local convection heat transfer coefficients
at the inside and outside surfaces of the furnace door are exhibited.
Abstract: Nanomaterials have attracted considerable attention
during the last two decades, due to their unusual electrical, mechanical
and other physical properties as compared with their bulky
counterparts. The mechanical properties of nanostructured materials
show strong size dependency, which has been explained within the
framework of continuum mechanics by including the effects of surface
stress. The size-dependent deformations of two-dimensional
nanosized structures with surface effects are investigated in the paper
by the finite element method. Truss element is used to evaluate the
contribution of surface stress to the total potential energy and the
Gurtin and Murdoch surface stress model is implemented with
ANSYS through its user programmable features. The proposed
approach is used to investigate size-dependent stress concentration
around a nanosized circular hole and the size-dependent effective
moduli of nanoporous materials. Numerical results are compared with
available analytical results to validate the proposed modeling
approach.
Abstract: An interesting method to produce calcium carbonate is based in a gas-liquid reaction between carbon dioxide and aqueous solutions of calcium hydroxide. The design parameters for gas-liquid phase are flow regime, individual mass transfer, gas-liquid specific interfacial area. Most studies on gas-liquid phase were devoted to the experimental determination of some of these parameters, and more specifically, of the mass transfer coefficient, kLa which depends fundamentally on the superficial gas velocity and on the physical properties of absorption phase. The principle investigation was directed to study the effect of the vibration on the mass transfer coefficient kLa in gas-liquid phase during absorption of CO2 in the in aqueous solution of calcium hydroxide. The vibration with a higher frequency increase the mass transfer coefficient kLa, but vibration with lower frequency didn-t improve it, the mass transfer coefficient kLa increase with increase the superficial gas velocity.
Abstract: Soil chemical and physical properties have important
roles in compartment of the environment and agricultural
sustainability and human health. The objectives of this research is
determination of spatial distribution patterns of Cd, Zn, K, pH, TNV,
organic material and electrical conductivity (EC) in agricultural soils
of Natanz region in Esfehan province. In this study geostatistic and
non-geostatistic methods were used for prediction of spatial
distribution of these parameters. 64 composite soils samples were
taken at 0-20 cm depth. The study area is located in south of
NATANZ agricultural lands with area of 21660 hectares. Spatial
distribution of Cd, Zn, K, pH, TNV, organic material and electrical
conductivity (EC) was determined using geostatistic and geographic
information system. Results showed that Cd, pH, TNV and K data
has normal distribution and Zn, OC and EC data had not normal
distribution. Kriging, Inverse Distance Weighting (IDW), Local
Polynomial Interpolation (LPI) and Redial Basis functions (RBF)
methods were used to interpolation. Trend analysis showed that
organic carbon in north-south and east to west did not have trend
while K and TNV had second degree trend. We used some error
measurements include, mean absolute error(MAE), mean squared
error (MSE) and mean biased error(MBE). Ordinary
kriging(exponential model), LPI(Local polynomial interpolation),
RBF(radial basis functions) and IDW methods have been chosen as
the best methods to interpolating of the soil parameters. Prediction
maps by disjunctive kriging was shown that in whole study area was
intensive shortage of organic matter and more than 63.4 percent of
study area had shortage of K amount.