Abstract: Alkali treated oil palm empty fruit bunch (EFB) fibres
(TEFBF) and untreated EFBF fibers (UEFBF) were incorporated in
polypropylene (PP) with and without malic anhydride grafted PP
(MAPP) and magnesium hydroxide as flame retardant (FR) to
produce TEFBF-PP and UEFBF-PP composites by the melt casting
method. The composites were characterized by mechanical and
burning tests along with a scanning electron microscope and Fourier
transform infrared spectroscopy. The significant improvement in
flexural modulus (133%) and flame retardant property (60%) of
TEFBF-PP composite with MAPP and FR is observed. The improved
mechanical property is discussed by the development of encapsulated
textures.
Abstract: Magnesium wastes and scraps, one of the metal wastes, are produced by many industrial activities, all over the world. Their growing size is becoming a future problem for the world. In this study, the use of magnesium wastes as a raw material in the production of the magnesium borate hydrates are aimed. The method used in the experiments is hydrothermal synthesis. The conditions are set to, waste magnesium to B2O3, 1:3 as a molar ratio. Four different reaction times are studied which are 30, 60, 120 and 240 minutes. For the identification analyses X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and Raman spectroscopy techniques are used. As a result at all the reaction times magnesium borate hydrates are synthesized and the most crystalline forms are obtained at a reaction time of 120 minutes. The overall yields of the production are found between the values of 65-80 %.
Abstract: A liquid curved jet has many applications in different
industrial and engineering processes, such as the prilling process
for generating small spherical pellets (fertilizer or magnesium). The
liquids used are usually molten and contain small quantities of
polymers and therefore can be modelled as non-Newtonian liquids. In
this paper, we model the viscoelastic liquid jet by using the Oldroyd-
B model. An asymptotic analysis has been used to simplify the
governing equations. Furthermore, the trajectory and a linear temporal
stability in the presence of gravity and rotation have been determined.
Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: The aim of this study was to investigate ammonium
exchange capacity of natural and activated clinoptilolite from
Kwazulu-Natal Province, South Africa. X – ray fluorescence (XRF)
analysis showed that the clinoptilolite contained exchangeable ions
of sodium, potassium, calcium and magnesium. This analysis also
confirmed that the zeolite sample had a high silicon composition
compared to aluminium. Batch equilibrium studies were performed
in an orbital shaker and the data fitted the Langmuir isotherm very
well. The ammonium exchange capacity was found to increase with
pH and temperature. Clinoptilolite functionalization with
hydrochloric acid increased its ammonia uptake ability.
Abstract: In this study, The physico-chemical and nutritional
properties of `Musmula` Medlar (Mespilus germanica L.) fruit and
seed grown in Northeast Anatolia was investigated. In the fruit,
length, width, thickness, weight, total soluble solids, colour (1),
colour (2) [L, a, b values], protein, crude ash, crude fiber, crude oil,
texture and pH were determinated as 4.34 cm, 4.22 cm, 3.67 cm,
38.36 g, 23.97 %, S60O60Y41,, [53.85, 17.15, 33.75], 1.06 %, 0.79 %,
4.24 %, 0.005 %, 1.21 kg/cm2 and 4.26 respectively. Also, pulp ratio,
seed ratio and pulp/seed ratio were found to be 92.88 %, 7.11 % and
14.07 %, respectively. In addition, the mineral composition of medlar
fruit in Northeast Anatolia was studied. In the fruit, 23 minerals were
analyzed and 19 minerals were present at detectable levels. The
medlar fruit was richest in potassium (6962 ppm), calcium (1186.378
ppm), magnesium (1070.08 ppm) and phosphor (763.425 ppm).
Abstract: A large quantity of world-s oil reserves exists in
carbonate reservoirs. Carbonate reservoirs are very sensitive to
chemical enhanced oil recovery process because of containing large
amount of calcite, dolomite and calcium sulfate minerals. These
minerals cause major obstacles during alkali-surfactant-polymer
(ASP) flooding. Alkali reacts with these minerals and form undesired
precipitations which plug effective porous openings, reduce
permeability and cause scale occurrence at the wellbore. In this
paper, a new chemical combination consists of acrylic acid and alkali
was used to minimize precipitation problem during ASP flooding. A
series of fluid-fluid compatibility tests were performed using acrylic
acid and different concentrations of alkaline. Two types of alkalis
namely; sodium carbonate and sodium metaborate were screened. As
a result, the combination of acrylic acid and sodium carbonate was
not effective in preventing calcium and magnesium precipitations.
However, acrylic acid and sodium metaborate showed promising
results for keeping all solutions without any precipitations. The ratio
of acrylic acid to sodium metaborate of 0.7:1.0 was found to be
optimum for achieving a compatible solution for 30 days at 80oC.
Abstract: This paper presents the results of a study aimed at
establishing the temperature distribution during the welding of
magnesium alloy sheets by Pulsed Current Gas Tungsten Arc
Welding (PCGTAW) and Constant Current Gas Tungsten Arc
Welding (CCGTAW) processes. Pulsing of the GTAW welding
current influences the dimensions and solidification rate of the fused
zone, it also reduces the weld pool volume hence a narrower bead. In
this investigation, the base material considered was 2mm thin AZ 31
B magnesium alloy, which is finding use in aircraft, automobile and
high-speed train components. A finite element analysis was carried
out using ANSYS, and the results of the FEA were compared with
the experimental results. It is evident from this study that the finite
element analysis using ANSYS can be effectively used to model
PCGTAW process for finding temperature distribution.