Kinetics Study of Ammonia Removal from Synthetic Waste Water
The aim of this study was to investigate ammonium
exchange capacity of natural and activated clinoptilolite from
Kwazulu-Natal Province, South Africa. X – ray fluorescence (XRF)
analysis showed that the clinoptilolite contained exchangeable ions
of sodium, potassium, calcium and magnesium. This analysis also
confirmed that the zeolite sample had a high silicon composition
compared to aluminium. Batch equilibrium studies were performed
in an orbital shaker and the data fitted the Langmuir isotherm very
well. The ammonium exchange capacity was found to increase with
pH and temperature. Clinoptilolite functionalization with
hydrochloric acid increased its ammonia uptake ability.
[1] R. Leva-ramos, J. E. Monsivais-Rocha, A. Aragon-Pina, M. S. Berber-
Mendoza, R. M. Guerrero-Coronado, P. Alonso-Davila, J. Mendoza-
Barron, "Removal of ammonium from aqueous solution by ion exchange
on natural and modified Chabazite," J. Environ. Man., vol. 91, pp.
2662-2668, 2010.
[2] A. Hedstrom, "Ion exchange of ammonium in zeolites: a literature
review. J. Environ., Eng. vol. 127, pp. 673-681, 2001.
[3] R. Leva-ramos, G. Aguilar-Armenta, L. V. Gonzalez-Gutierrez, R. M.
Guerrero-Coronado, J. Mendoza-Bason, "Ammonium exchange on
clinoptilolite from mineral deposits located in Mexico," J. Chem.
Technol. Biotechnol., vol. 79, pp. 651-657, 2004.
[4] V. K Jha, S. Hayashi, "Modificaton on natural clinoptilolite zeolite for
its NH4+ retention capacity," J. Hazard. Mater., vol. 141, pp. 483-488,
2009.
[5] P. Vassileva, D Voikova, "Investigation on natural and pretreated
Bulgarian clinoptilolite for ammonium ions removal from aqueous
solutions," J. Hazard. Mater., vol. 170, pp. 948-953, 2009.
[6] Y. F. Wang, F. Lin, W. Q. Pang, "Ammonium exchange in aqueous
solution using Chine natural clinoptilolite and modified zeolite," J.
Hazard. Mater., vol. 142. pp. 160 - 164, 2007.
[7] B. B. Mamba, D. W. Nyembe and A. F. Mulaba-Bafubiandi, "The effect
of conditioning with NaCl, KCl and HCl on the performance of natural
clinoptilolite's removal efficiency of Cu2+ and Co2+ Synthetic
solutions," Water SA, vol. 36, no. 4, pp. 437-444, 2009.
[8] M. Zhang, H. Zhang, Dan Xu, L. Han, D Niu, B.Tian, J Zhan, L. Zhan
and W. Wu, "Removal of Ammonium from aqueous solutions using
zeolite synthesized from fly ash by a fusion method," Desalination
(2011) doi: 10.1016/j. desal. 2010.12.021.
[9] A. M. Yusofa, L. K. Keata, Z. Ibrahimb, Z. A. Majiza, N. A. Nizamb,
"Kinetic and equilibrium studies of the removal of ammonium ions from
aqueous solution by rice husk ash-synthesized zeolite Y and powered
and granulated forms of mordenite," J. Hazard.Mat., 2010, vol. 174, pp.
380-385, 2010.
[10] H. Huang, X Xiao, Bo Yan, L. Yang, "Ammonium removal from
aqueous solution by using natural Chinese (Chende) zeolite as
adsorbent". J. Hazard. Mat. Vol. 175, pp. 247-252, 2010.
[11] B. N. K. Njoroge and S. G. Mwamachi, "Ammonia removal from an
aqueous solution by the use of a natural zeolite," J. Envir. Eng. Sci., vol.
3, pp. 147-154, 2004.
[12] O. Korkuna, R. Leboda, J. Skubiszewska, T. Vrublevs-ka, V.M. Gun-ko
and J Ryczkowski, "Structural and physicochemical properties of natural
zeolites: clinoptilolite and mordenite," Microporous and Mesoporous
Materials, vol. 87, pp. 243-254, 2006.
[13] V. O. Vasylechko, G. V. Gryshchouk, L. O. Lebedynets, R. Leboda and
J. Skubiszewska-zieba, "Investigation of usefulness of Transcarpathian
zeolites in trace analysis of waters. Application of mordenite for the pre
concentration of trace amounts of copper and cadmium," Chem. Anal.
(Warsaw), vol. 44, no. 6, pp. 1013-1024, 1999.
[14] M. A. Hernandez, "Nitrogen-sorption characteristics of the micro porous
structure of clinoptilolite-type zeolites," J. Porous Mater., vol. 7, no. 4,
pp. 443-454, 2000..
[1] R. Leva-ramos, J. E. Monsivais-Rocha, A. Aragon-Pina, M. S. Berber-
Mendoza, R. M. Guerrero-Coronado, P. Alonso-Davila, J. Mendoza-
Barron, "Removal of ammonium from aqueous solution by ion exchange
on natural and modified Chabazite," J. Environ. Man., vol. 91, pp.
2662-2668, 2010.
[2] A. Hedstrom, "Ion exchange of ammonium in zeolites: a literature
review. J. Environ., Eng. vol. 127, pp. 673-681, 2001.
[3] R. Leva-ramos, G. Aguilar-Armenta, L. V. Gonzalez-Gutierrez, R. M.
Guerrero-Coronado, J. Mendoza-Bason, "Ammonium exchange on
clinoptilolite from mineral deposits located in Mexico," J. Chem.
Technol. Biotechnol., vol. 79, pp. 651-657, 2004.
[4] V. K Jha, S. Hayashi, "Modificaton on natural clinoptilolite zeolite for
its NH4+ retention capacity," J. Hazard. Mater., vol. 141, pp. 483-488,
2009.
[5] P. Vassileva, D Voikova, "Investigation on natural and pretreated
Bulgarian clinoptilolite for ammonium ions removal from aqueous
solutions," J. Hazard. Mater., vol. 170, pp. 948-953, 2009.
[6] Y. F. Wang, F. Lin, W. Q. Pang, "Ammonium exchange in aqueous
solution using Chine natural clinoptilolite and modified zeolite," J.
Hazard. Mater., vol. 142. pp. 160 - 164, 2007.
[7] B. B. Mamba, D. W. Nyembe and A. F. Mulaba-Bafubiandi, "The effect
of conditioning with NaCl, KCl and HCl on the performance of natural
clinoptilolite's removal efficiency of Cu2+ and Co2+ Synthetic
solutions," Water SA, vol. 36, no. 4, pp. 437-444, 2009.
[8] M. Zhang, H. Zhang, Dan Xu, L. Han, D Niu, B.Tian, J Zhan, L. Zhan
and W. Wu, "Removal of Ammonium from aqueous solutions using
zeolite synthesized from fly ash by a fusion method," Desalination
(2011) doi: 10.1016/j. desal. 2010.12.021.
[9] A. M. Yusofa, L. K. Keata, Z. Ibrahimb, Z. A. Majiza, N. A. Nizamb,
"Kinetic and equilibrium studies of the removal of ammonium ions from
aqueous solution by rice husk ash-synthesized zeolite Y and powered
and granulated forms of mordenite," J. Hazard.Mat., 2010, vol. 174, pp.
380-385, 2010.
[10] H. Huang, X Xiao, Bo Yan, L. Yang, "Ammonium removal from
aqueous solution by using natural Chinese (Chende) zeolite as
adsorbent". J. Hazard. Mat. Vol. 175, pp. 247-252, 2010.
[11] B. N. K. Njoroge and S. G. Mwamachi, "Ammonia removal from an
aqueous solution by the use of a natural zeolite," J. Envir. Eng. Sci., vol.
3, pp. 147-154, 2004.
[12] O. Korkuna, R. Leboda, J. Skubiszewska, T. Vrublevs-ka, V.M. Gun-ko
and J Ryczkowski, "Structural and physicochemical properties of natural
zeolites: clinoptilolite and mordenite," Microporous and Mesoporous
Materials, vol. 87, pp. 243-254, 2006.
[13] V. O. Vasylechko, G. V. Gryshchouk, L. O. Lebedynets, R. Leboda and
J. Skubiszewska-zieba, "Investigation of usefulness of Transcarpathian
zeolites in trace analysis of waters. Application of mordenite for the pre
concentration of trace amounts of copper and cadmium," Chem. Anal.
(Warsaw), vol. 44, no. 6, pp. 1013-1024, 1999.
[14] M. A. Hernandez, "Nitrogen-sorption characteristics of the micro porous
structure of clinoptilolite-type zeolites," J. Porous Mater., vol. 7, no. 4,
pp. 443-454, 2000..
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:50218", author = "Edison Muzenda and John Kabuba and Freeman Ntuli and Mansoor Mollagee", title = "Kinetics Study of Ammonia Removal from Synthetic Waste Water", abstract = "The aim of this study was to investigate ammonium
exchange capacity of natural and activated clinoptilolite from
Kwazulu-Natal Province, South Africa. X – ray fluorescence (XRF)
analysis showed that the clinoptilolite contained exchangeable ions
of sodium, potassium, calcium and magnesium. This analysis also
confirmed that the zeolite sample had a high silicon composition
compared to aluminium. Batch equilibrium studies were performed
in an orbital shaker and the data fitted the Langmuir isotherm very
well. The ammonium exchange capacity was found to increase with
pH and temperature. Clinoptilolite functionalization with
hydrochloric acid increased its ammonia uptake ability.", keywords = "Activated clinoptilolite, Ammonium exchange,Equilibrium, Functionalization, Langmuir isotherm", volume = "5", number = "7", pages = "528-4", }