Abstract: Ground-level tropospheric ozone is one of the air
pollutants of most concern. It is mainly produced by photochemical
processes involving nitrogen oxides and volatile organic compounds
in the lower parts of the atmosphere. Ozone levels become
particularly high in regions close to high ozone precursor emissions
and during summer, when stagnant meteorological conditions with
high insolation and high temperatures are common.
In this work, some results of a study about urban ozone
distribution patterns in the city of Badajoz, which is the largest and
most industrialized city in Extremadura region (southwest Spain) are
shown. Fourteen sampling campaigns, at least one per month, were
carried out to measure ambient air ozone concentrations, during
periods that were selected according to favourable conditions to
ozone production, using an automatic portable analyzer.
Later, to evaluate the ozone distribution at the city, the measured
ozone data were analyzed using geostatistical techniques. Thus, first,
during the exploratory analysis of data, it was revealed that they were
distributed normally, which is a desirable property for the subsequent
stages of the geostatistical study. Secondly, during the structural
analysis of data, theoretical spherical models provided the best fit for
all monthly experimental variograms. The parameters of these
variograms (sill, range and nugget) revealed that the maximum
distance of spatial dependence is between 302-790 m and the
variable, air ozone concentration, is not evenly distributed in reduced
distances. Finally, predictive ozone maps were derived for all points
of the experimental study area, by use of geostatistical algorithms
(kriging). High prediction accuracy was obtained in all cases as
cross-validation showed. Useful information for hazard assessment
was also provided when probability maps, based on kriging
interpolation and kriging standard deviation, were produced.
Abstract: As the resources for naturally occurring aggregates
diminished at an ever increasing rate, researchers are keen to utilize
recycled materials in road construction in harmony with sustainable
development. Steel slag, a waste product from the steel making
industry, is one of the recycled materials reported to exhibit great
potential to replace naturally occurring aggregates in asphalt
mixtures. This paper presents the resilient modulus properties of
steel slag asphalt mixtures subjected to short term oven ageing
(STOA). The resilient modulus test was carried out to evaluate the
stiffness of asphalt mixtures at 10ºC, 25ºC and 40ºC. Previous
studies showed that stiffness changes in asphalt mixture played an
important role in inflicting pavement distress particularly cracking
and rutting that are common at low and high temperatures
respectively. Temperature was found to significantly influence the
resilient modulus of asphalt mixes. The resilient modulus of the
asphalt specimens tested decreased by more than 90% when the test
temperature increased from 10°C to 40°C.
Abstract: A group of Stellite alloys are studied in consideration
of temperature effects on their hardness and wear resistance. The
hardness test is conducted on a micro-hardness tester with a hot stage
equipped that allows heating the specimen up to 650°C. The wear
resistance of each alloy is evaluated using a pin-on-disc tribometer
with a heating furnace built-in that provides the temperature capacity
up to 450°C. The experimental results demonstrate that the hardness
and wear resistance of Stellite alloys behave differently at room
temperature and at high temperatures. The wear resistance of Stellite
alloys at room temperature mainly depends on their carbon content and
also influenced by the tungsten content in the alloys. However, at high
temperatures the wear mechanisms of Stellite alloys become more
complex, involving multiple factors. The relationships between
chemical composition, microstructure, hardness and wear resistance of
these alloys are studied, with focus on temperature effect on these
relations.
Abstract: In this paper, creep constitutive equations of base
(Parent) and weld materials of the weldment for cold-drawn 304L
stainless steel have been obtained experimentally. For this purpose,
test samples have been generated from cold drawn bars and weld
material according to the ASTM standard. The creep behavior and
properties have been examined for these materials by conducting uniaxial
creep tests. Constant temperatures and constant load uni-axial
creep tests have been carried out at two high temperatures, 680 and
720 oC, subjected to constant loads, which produce initial stresses
ranging from 240 to 360 MPa. The experimental data have been used
to obtain the creep constitutive parameters using numerical
optimization techniques.
Abstract: Recently, a growing interest has emerged on the
development of new and efficient energy sources, due to the inevitable extinction of the nonrenewable energy reserves. One of
these alternative sources which has a great potential and sustainability to meet up the energy demand is biomass energy. This
significant energy source can be utilized with various energy
conversion technologies, one of which is biomass gasification in
supercritical water.
Water, being the most important solvent in nature, has very important characteristics as a reaction solvent under supercritical
circumstances. At temperatures above its critical point (374.8oC and
22.1 MPa), water becomes more acidic and its diffusivity increases.
Working with water at high temperatures increases the thermal
reaction rate, which in consequence leads to a better dissolving of the
organic matters and a fast reaction with oxygen. Hence, supercritical water offers a control mechanism depending on solubility, excellent
transport properties based on its high diffusion ability and new reaction possibilities for hydrolysis or oxidation.
In this study the gasification of a real biomass, namely olive mill
wastewater (OMW), in supercritical water is investigated with the
use of Pt/Al2O3 and Ni/Al2O3 catalysts. OMW is a by-product
obtained during olive oil production, which has a complex nature
characterized by a high content of organic compounds and
polyphenols. These properties impose OMW a significant pollution
potential, but at the same time, the high content of organics makes
OMW a desirable biomass candidate for energy production.
All of the catalytic gasification experiments were made with five
different reaction temperatures (400, 450, 500, 550 and 600°C),
under a constant pressure of 25 MPa. For the experiments conducted
with Ni/Al2O3 catalyst, the effect of five reaction times (30, 60, 90,
120 and 150 s) was investigated. However, procuring that similar
gasification efficiencies could be obtained at shorter times, the experiments were made by using different reaction times (10, 15, 20,
25 and 30 s) for the case of Pt/Al2O3 catalyst. Through these experiments, the effects of temperature, time and catalyst type on the
gasification yields and treatment efficiencies were investigated.
Abstract: Carbon fibers are fabricated from different materials,
such as special polyacrylonitrile (PAN) fibers, rayon fibers and pitch.
Among these three groups of materials, PAN fibers are the most
widely used precursor for the manufacture of carbon fibers. The
process of fabrication carbon fibers from special PAN fibers includes
two steps; oxidative stabilization at low temperature and
carbonization at high temperatures in an inert atmosphere. Due to the
high price of raw materials (special PAN fibers), carbon fibers are
still expensive.
In the present work the main goal is making carbon fibers from
low price commercial PAN fibers with modified chemical
compositions. The results show that in case of conducting completes
stabilization process, it is possible to produce carbon fibers with
desirable tensile strength from this type of PAN fibers. To this
matter, thermal characteristics of commercial PAN fibers were
investigated and based upon the obtained results, with some changes
in conventional procedure of stabilization in terms of temperature
and time variables; the desirable conditions of complete stabilization
is achieved.
Abstract: In this study, the effect of nanofluids on the pool film
boiling was experimentally investigated at saturated condition under
atmospheric pressure. For this purpose, four different water-based
nanofluids (Al2O3, SiO2, TiO2 and CuO) with 0.1% particle volume
fraction were prepared. To investigate the boiling heat transfer, a
cylindrical rod with high temperature was used. The rod heated up to
high temperatures was immersed into nanofluids. The center
temperature of rod during the cooling process was recorded by using
a K-type thermocouple. The quenching curves showed that the pool
boiling heat transfer was strongly dependent on the nanoparticle
materials. During the repetitive quenching tests, the cooling time
decreased and thus, the film boiling vanished. Consequently, the
primary reason of this was the change of the surface characteristics
due to the nanoparticles deposition on the rod-s surface.
Abstract: In this work, we incorporated a quartic bond potential
into a coarse-grained bead-spring model to study lubricant adsorption
on a solid surface as well as depletion instability. The surface tension
density and the number density profiles were examined to verify the
solid-liquid and liquid-vapor interfaces during heat treatment. It was
found that both the liquid-vapor interfacial thickness and the
solid-vapor separation increase with the temperatureT* when T*is
below the phase transition temperature Tc
*. At high temperatures
(T*>Tc
*), the solid-vapor separation decreases gradually as the
temperature increases. In addition, we evaluated the lubricant weight
and bond loss profiles at different temperatures. It was observed that
the lubricant desorption is favored over decomposition and is the main
cause of the lubricant failure at the head disk interface in our
simulations.
Abstract: Air conditioning is mainly use as human comfort
cooling medium. It use more in high temperatures are country such as
Malaysia. Proper estimation of cooling load will archive ideal
temperature. Without proper estimation can lead to over estimation or
under estimation. The ideal temperature should be comfort enough.
This study is to develop a program to calculate an ideal cooling load
demand, which is match with heat gain. Through this study, it is easy
to calculate cooling load estimation. Objective of this study are to
develop user-friendly and easy excess cooling load program. This is
to insure the cooling load can be estimate by any of the individual
rather than them using rule-of-thumb. Developed software is carryout
by using Matlab-GUI. These developments are only valid for
common building in Malaysia only. An office building was select as
case study to verify the applicable and accuracy of develop software.
In conclusion, the main objective has successfully where developed
software is user friendly and easily to estimate cooling load demand.