Abstract: In this study, the effect of coal mining activities on lead and cadmium concentrations and distribution in soil was investigated in Hyrcanian forest, North Iran. 16 plots (20×20 m2) were established by systematic-randomly (60×60 m2) in an area of 4 ha (200×200 m2-mine entrance placed at center). An area adjacent to the mine was not affected by the mining activity; considered as the controlled area. In order to investigate soil lead and cadmium concentration, one sample was taken from the 0-10 cm in each plot. To study the spatial pattern of soil properties and lead and cadmium concentrations in the mining area, an area of 80×80m2 (the mine as the center) was considered and 80 soil samples were systematic-randomly taken (10 m intervals). Geostatistical analysis was performed via Kriging method and GS+ software (version 5.1). In order to estimate the impact of coal mining activities on soil quality, pollution index was measured. Lead and cadmium concentrations were significantly higher in mine area (Pb: 10.97±0.30, Cd: 184.47±6.26 mg.kg-1) in comparison to control area (Pb: 9.42±0.17, Cd: 131.71±15.77 mg.kg-1). The mean values of the PI index indicate that Pb (1.16) and Cd (1.77) presented slightly polluted. Results of the NIPI index showed that Pb (1.44) and Cd (2.52) presented slight pollution and moderate pollution respectively. Results of variography and kriging method showed that it is possible to prepare interpolation maps of lead and cadmium around the mining areas in Hyrcanian forest. According to results of pollution and risk assessments, forest soil was contaminated by heavy metals (lead and cadmium); therefore, using reclamation and remediation techniques in these areas is necessary.
Abstract: Within geostatistics research, effective estimation of
the variogram points has been examined, particularly in developing
robust alternatives. The parametric fit of these variogram points which
eventually defines the kriging weights, however, has not received
the same attention from a robust perspective. This paper proposes
the use of the non-linear Wilcoxon norm over weighted non-linear
least squares as a robust variogram fitting alternative. First, we
introduce the concept of variogram estimation and fitting. Then, as
an alternative to non-linear weighted least squares, we discuss the
non-linear Wilcoxon estimator. Next, the robustness properties of the
non-linear Wilcoxon are demonstrated using a contaminated spatial
data set. Finally, under simulated conditions, increasing levels of
contaminated spatial processes have their variograms points estimated
and fit. In the fitting of these variogram points, both non-linear
Weighted Least Squares and non-linear Wilcoxon fits are examined
for efficiency. At all levels of contamination (including 0%), using
a robust estimation and robust fitting procedure, the non-weighted
Wilcoxon outperforms weighted Least Squares.
Abstract: For this study, a town based soil database created in
Gümüsçay District of Biga Town, Çanakkale, Turkey. Crop and
livestock production are major activities in the district. Nutrient
management is mainly based on commercial fertilizer application
ignoring the livestock manure. Within the boundaries of district, 122
soil sampling points determined over the satellite image. Soil samples
collected from the determined points with the help of handheld
Global Positioning System. Labeled samples were sent to a
commercial laboratory to determine 11 soil parameters including
salinity, pH, lime, organic matter, nitrogen, phosphorus, potassium,
iron, manganese, copper and zinc. Based on the test results soil maps
for mentioned parameters were developed using remote sensing, GIS,
and geostatistical analysis. In this study we developed a GIS database
that will be used for soil nutrient management. Methods were
explained and soil maps and their interpretations were summarized in
the study.
Abstract: The concentrations of As, Hg, Co, Cr and Cd were
tested for each soil sample, and their spatial patterns were analyzed
by the semivariogram approach of geostatistics and geographical
information system technology. Multivariate statistic approaches
(principal component analysis and cluster analysis) were used to
identify heavy metal sources and their spatial pattern. Principal
component analysis coupled with correlation between heavy metals
showed that primary inputs of As, Hg and Cd were due to
anthropogenic while, Co, and Cr were associated with pedogenic
factors. Ordinary kriging was carried out to map the spatial patters of
heavy metals. The high pollution sources evaluated was related with
usage of urban and industrial wastewater. The results of this study
helpful for risk assessment of environmental pollution for decision
making for industrial adjustment and remedy soil pollution.
Abstract: Soil chemical and physical properties have important
roles in compartment of the environment and agricultural
sustainability and human health. The objectives of this research is
determination of spatial distribution patterns of Cd, Zn, K, pH, TNV,
organic material and electrical conductivity (EC) in agricultural soils
of Natanz region in Esfehan province. In this study geostatistic and
non-geostatistic methods were used for prediction of spatial
distribution of these parameters. 64 composite soils samples were
taken at 0-20 cm depth. The study area is located in south of
NATANZ agricultural lands with area of 21660 hectares. Spatial
distribution of Cd, Zn, K, pH, TNV, organic material and electrical
conductivity (EC) was determined using geostatistic and geographic
information system. Results showed that Cd, pH, TNV and K data
has normal distribution and Zn, OC and EC data had not normal
distribution. Kriging, Inverse Distance Weighting (IDW), Local
Polynomial Interpolation (LPI) and Redial Basis functions (RBF)
methods were used to interpolation. Trend analysis showed that
organic carbon in north-south and east to west did not have trend
while K and TNV had second degree trend. We used some error
measurements include, mean absolute error(MAE), mean squared
error (MSE) and mean biased error(MBE). Ordinary
kriging(exponential model), LPI(Local polynomial interpolation),
RBF(radial basis functions) and IDW methods have been chosen as
the best methods to interpolating of the soil parameters. Prediction
maps by disjunctive kriging was shown that in whole study area was
intensive shortage of organic matter and more than 63.4 percent of
study area had shortage of K amount.