Abstract: Graphene material has found tremendous applications
in water desalination, DNA sequencing and energy storage. Multiple
nanopores are etched to create opening for water desalination and
energy storage applications. The nanopores created are of the order
of 3-5 nm allowing multiple ions to transport through the pore. In
this paper, we present for the first time, molecular dynamics study of
single ion transport, where only one ion passes through the graphene
nanopore. The diameter of the graphene nanopore is of the same
order as the hydration layers formed around each ion. Analogous to
single electron transport resulting from ionic transport is observed
for the first time. The current-voltage characteristics of such a device
are similar to single electron transport in quantum dots. The current
is blocked until a critical voltage, as the ions are trapped inside a
hydration shell. The trapped ions have a high energy barrier compared
to the applied input electrical voltage, preventing the ion to break free
from the hydration shell. This region is called “Coulomb blockade
region”. In this region, we observe zero transport of ions inside the
nanopore. However, when the electrical voltage is beyond the critical
voltage, the ion has sufficient energy to break free from the energy
barrier created by the hydration shell to enter into the pore. Thus, the
input voltage can control the transport of the ion inside the nanopore.
The device therefore acts as a binary storage unit, storing 0 when
no ion passes through the pore and storing 1 when a single ion
passes through the pore. We therefore postulate that the device can
be used for fluidic computing applications in chemistry and biology,
mimicking a computer. Furthermore, the trapped ion stores a finite
charge in the Coulomb blockade region; hence the device also acts
a super capacitor.
Abstract: Thermochemical energy storage (TCES), as a long-term and lossless energy storage principle, provides a contribution for the reduction of greenhouse emissions of mobile applications, such as passenger vehicles with an internal combustion engine. A prototype of a TCES system, based on reversible sorption reactions of LiBr composite and methanol has been designed at Vienna University of Technology. In this paper, the selection of reactive and inert carrier materials as well as the design of heat exchangers (reactor vessel and evapo-condenser) was reviewed and the cycle stability under real operating conditions was investigated. The performance of the developed system strongly depends on the environmental temperatures, to which the reactor vessel and evapo-condenser are exposed during the phases of thermal conversion. For an integration of the system into mobile applications, the functionality of the designed prototype was proved in numerous conducted cycles whereby no adverse reactions were observed.
Abstract: This paper presents an optimization method based
on genetic algorithm for the energy management inside buildings
developed in the frame of the project Smart Living Lab (SLL)
in Fribourg (Switzerland). This algorithm optimizes the interaction
between renewable energy production, storage systems and energy
consumers. In comparison with standard algorithms, the innovative
aspect of this project is the extension of the smart regulation
over three simultaneous criteria: the energy self-consumption, the
decrease of greenhouse gas emissions and operating costs. The
genetic algorithm approach was chosen due to the large quantity
of optimization variables and the non-linearity of the optimization
function. The optimization process includes also real time data of the
building as well as weather forecast and users habits. This information
is used by a physical model of the building energy resources to predict
the future energy production and needs, to select the best energetic
strategy, to combine production or storage of energy in order to
guarantee the demand of electrical and thermal energy. The principle
of operation of the algorithm as well as typical output example of
the algorithm is presented.
Abstract: The use of CO2 in oil recovery and in CO2 capture and storage is gaining traction in recent years. These applications involve heat transfer between CO2 and the base fluid, and hence, there arises a need to improve the thermal conductivity of CO2 to increase the process efficiency and reduce cost. One way to improve the thermal conductivity is through nanoparticle addition in the base fluid. The nanofluid model in this study consisted of copper (Cu) nanoparticles in varying concentrations with CO2 as a base fluid. No experimental data are available on thermal conductivity of CO2 based nanofluid. Molecular dynamics (MD) simulations are an increasingly adopted tool to perform preliminary assessments of nanoparticle (NP) fluid interactions. In this study, the effect of the formation of a nanolayer (or molecular layering) at the gas-solid interface on thermal conductivity is investigated using equilibrium MD simulations by varying NP diameter and keeping the volume fraction (1.413%) of nanofluid constant to check the diameter effect of NP on the nanolayer and thermal conductivity. A dense semi-solid fluid layer was seen to be formed at the NP-gas interface, and the thickness increases with increase in particle diameter, which also moves with the NP Brownian motion. Density distribution has been done to see the effect of nanolayer, and its thickness around the NP. These findings are extremely beneficial, especially to industries employed in oil recovery as increased thermal conductivity of CO2 will lead to enhanced oil recovery and thermal energy storage.
Abstract: In this study, a form-stable composite Paraffin/Nanoclay (PA-NC) has been prepared by absorbing PA into porous particles of NC to be used for low-temperature latent heat thermal energy storage. The leakage test shows that the maximum mass fraction of PA that can be incorporated in NC without leakage is 60 wt.%. Differential scanning calorimetry (DSC) has been used to measure the thermal properties of the PA and PA-NC both before and after incorporation in plasterboard (PL). The mechanical performance of the samples has been evaluated in flexural mode. The thermal energy storage performance has been studied using a small test chamber (100 mm × 100 mm × 100 mm) made from 10 mm thick PL and measuring the temperatures using thermocouples. The flammability of the PL+PL-NC has been discussed using a cone calorimeter. The results indicate that the form composite PA has good potential for use as thermal energy storage materials in building applications.
Abstract: More than half of the urban population in Romania lives today in residential buildings made out of large prefabricated reinforced concrete panels. Since their initial design was made in the 1960’s, these housing units are now being technically and morally outdated, consuming large amounts of energy for heating, cooling, ventilation and lighting, while failing to meet the needs of the contemporary life-style. Due to their widespread use, the design of a system that improves their energy efficiency would have a real impact, not only on the energy consumption of the residential sector, but also on the quality of life that it offers. Furthermore, with the transition of today’s existing power grid to a “smart grid”, buildings could become an active element for future electricity networks by contributing in micro-generation and energy storage. One of the most addressed issues today is to find locally adapted strategies that can be applied considering the 20-20-20 EU policy criteria and to offer sustainable and innovative solutions for the cost-optimal energy performance of buildings adapted on the existing local market. This paper presents a possible adaptive design scenario towards sustainable retrofitting of these housing units. The apartments are transformed in order to meet the current living requirements and additional extensions are placed on top of the building, replacing the unused roof space, acting not only as housing units, but as active solar energy collection systems. An adaptive building envelope is ensured in order to achieve overall air-tightness and an elevator system is introduced to facilitate access to the upper levels.
Abstract: The paper presents and energy management strategy for a Fuel Cell, Ultracapacitor, Battery hybrid energy storage. The fuel cell hybrid power system is devised basically for emergency power requirements and transient load applications. The power density of an Ultracapacitor is extremely high and for a battery, it is subtle. For a fuel cell, the value of power density is medium. The energy density of these three stockpiling gadgets is contrarily about the power density, i.e. for the batteries it is most noteworthy and for the Ultracapacitor, it is least. Again the fuel cell has medium energy density. The proposed Energy Management System (EMS) is trying to rationalize these parameters viz. the energy density and power density. The working of the fuel cell, Ultracapacitor and batteries are controlled in a coordinated environment in a way to optimize the energy usage and at the same time to get benefits of power and energy density from their inherent characteristics. MATLAB/ Simulink® based test bench is created by using different DC-DC converters for all energy storage devices and an inverter is modeled to supply the time varying load. The results provided by the EMS are highly satisfactory that proves its adaptability.
Abstract: Holistic methods covering the development process as
a whole – e.g. systems engineering – have established themselves in
product design. However, technical product optimization,
representing improvements in efficiency and/or minimization of loss,
usually applies to single components of a system. A holistic approach
is being defined based on a hierarchical point of view of systems
engineering. This is subsequently presented using the example of an
electromechanical flywheel energy storage system for automotive
applications.
Abstract: The use of hydroelectric pump-storage system at large
scale, MW-size systems, is already widespread around the world.
Designed for large scale applications, pump-storage station can be
scaled-down for small, remote residential applications. Given the cost
and complexity associated with installing a substation further than
100 miles from the main transmission lines, a remote, independent
and self-sufficient system is by far the most feasible solution. This
article is aiming at the design of wind and solar power generating
system, by means of pumped-storage to replace the wind and /or solar
power systems with a battery bank energy storage. Wind and solar
pumped-storage power generating system can reduce the cost of
power generation system, according to the user's electricity load and
resource condition and also can ensure system reliability of power
supply. Wind and solar pumped-storage power generation system is
well suited for remote residential applications with intermittent wind
and/or solar energy. This type of power systems, installed in these
locations, could be a very good alternative, with economic benefits
and positive social effects. The advantage of pumped storage power
system, where wind power regulation is calculated, shows that a
significant smoothing of the produced power is obtained, resulting in
a power-on-demand system’s capability, concomitant to extra
economic benefits.
Abstract: In recent years Li-Ion batteries getting more attention among the Electrical Vehicles (EV) and Hybrid Electrical Vehicles (HEV) energy storage. Li-Ion has shown extended power density and light weight compared to other batteries readily available in the market. One of the major drawbacks in Li-Ion batteries is their sensitivity to the temperature. If the working temperature is beyond the limit, that could affect seriously on the durability and performance of Li-Ion battery. Thus Battery Thermal Management (BTM) is the most essential in adapting Li-Ion battery to the EVs and HEVs.
Abstract: Gliding during night without electric power is an efficient method to enhance endurance performance of solar aircrafts. The properties of maximum gliding endurance path are studied in this paper. The problem is formulated as an optimization problem about maximum endurance can be sustained by certain potential energy storage with dynamic equations and aerodynamic parameter constrains. The optimal gliding path is generated based on gauss pseudo-spectral method. In order to analyse relationship between altitude, velocity of solar UAVs and its endurance performance, the lift coefficient in interval of [0.4, 1.2] and flight envelopes between 0~30km are investigated. Results show that broad range of lift coefficient can improve solar aircrafts- long endurance performance, and it is possible for a solar aircraft to achieve the aim of long endurance during whole night just by potential energy storage.
Abstract: PCMs have always been viewed as a suitable
candidate for off peak thermal storage, particularly for refrigeration
systems, due to the high latent energy densities of these materials.
However, due to the need to have them encapsulated within a
container this density is reduced. Furthermore, PCMs have a low
thermal conductivity which reduces the useful amount of energy
which can be stored. To consider these factors, the true energy
storage density of a PCM system was proposed and optimised for
PCMs encapsulated in slabs. Using a validated numerical model of
the system, a parametric study was undertaken to investigate the
impact of the slab thickness, gap between slabs and the mass flow
rate. The study showed that, when optimised, a PCM system can
deliver a true energy storage density between 53% and 83% of the
latent energy density of the PCM.