Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.
Abstract: Bangladesh is a developing country with large
population. Demand of electrical energy is increasing day by day
because of increasing population and industrialization. But due to
limited resources, people here are suffering from power crisis
problem which is considered as a major obstacle to the economic
development. In most of the cases, it is extremely difficult to extend
high tension transmission lines to some of the places that are
separated from the mainland. Renewable energy is considered to be
the right choice for providing clean energy to these remote
settlements. This paper proposes a cost effective design of off-grid
wind-diesel hybrid power system using combined heat and power
(CHP) technology in a grid isolated island, Sandwip, Bangladesh.
Design and simulation of the wind-diesel hybrid power system is
performed considering different factors for the island Sandwip.
Detailed economic analysis and comparison with solar PV system
clearly reveals that wind-diesel hybrid power system can be a cost
effective solution for the isolated island like Sandwip.
Abstract: In this paper, the full state feedback controllers
capable of regulating and tracking the speed trajectory are presented.
A fourth order nonlinear mean value model of a 448 kW turbocharged
diesel engine published earlier is used for the purpose.
For designing controllers, the nonlinear model is linearized and
represented in state-space form. Full state feedback controllers
capable of meeting varying speed demands of drivers are presented.
Main focus here is to investigate sensitivity of the controller to the
perturbations in the parameters of the original nonlinear model.
Suggested controller is shown to be highly insensitive to the
parameter variations. This indicates that the controller is likely
perform with same accuracy even after significant wear and tear of
engine due to its use for years.
Abstract: Performance of a cobalt doped sol-gel derived silica (Co/SiO2) catalyst for Fischer–Tropsch synthesis (FTS) in slurryphase reactor was studied using paraffin wax as initial liquid media. The reactive mixed gas, hydrogen (H2) and carbon monoxide (CO) in a molar ratio of 2:1, was flowed at 50 ml/min. Braunauer-Emmett- Teller (BET) surface area and X-ray diffraction (XRD) techniques were employed to characterize both the specific surface area and crystallinity of the catalyst, respectively. The reduction behavior of Co/SiO2 catalyst was investigated using the Temperature Programmmed Reduction (TPR) method. Operating temperatures were varied from 493 to 533K to find the optimum conditions to maximize liquid fuels production, gasoline and diesel.
Abstract: Since injection engines have a considerable portion, in
consumption of energy and environmental pollution, using an
alternative source of energy with lower pollutant effects in this
regard is necessary.
Biodiesel fuel is a suitable alternative for gasoline in diesel
engines.
In this research the property of biodiesel, the function and the
pollution effects of diesel engine, when using 100% biodiesel, using
100% gasoline and mixing ratio of both fuels for comparing them,
have been investigated.
The researches have shown, using biodiesel fuel in prevalent
diesel engine, will reduce the pollutants such as Co, half burned
carbohydrate and suspended particles and a little increase in
oxidation will achieve while power consumption, particularly fuel
and thermal efficiency of diesel fuel has the same.
Abstract: Due to the stringent legislation for emission of diesel
engines and also increasing demand on fuel consumption, the
importance of detailed 3D simulation of fuel injection, mixing and
combustion have been increased in the recent years. In the present
work, FIRE code has been used to study the detailed modeling of
spray and mixture formation in a Caterpillar heavy-duty diesel
engine. The paper provides an overview of the submodels
implemented, which account for liquid spray atomization, droplet
secondary break-up, droplet collision, impingement, turbulent
dispersion and evaporation. The simulation was performed from
intake valve closing (IVC) to exhaust valve opening (EVO). The
predicted in-cylinder pressure is validated by comparing with
existing experimental data. A good agreement between the predicted
and experimental values ensures the accuracy of the numerical
predictions collected with the present work. Predictions of engine
emissions were also performed and a good quantitative agreement
between measured and predicted NOx and soot emission data were
obtained with the use of the present Zeldowich mechanism and
Hiroyasu model. In addition, the results reported in this paper
illustrate that the numerical simulation can be one of the most
powerful and beneficial tools for the internal combustion engine
design, optimization and performance analysis.
Abstract: The objective of this research is to study of microbial lipid production by locally photosynthetic microalgae and oleaginous yeast via integrated cultivation technique using CO2 emissions from yeast fermentation. A maximum specific growth rate of Chlorella sp. KKU-S2 of 0.284 (1/d) was obtained under an integrated cultivation and a maximum lipid yield of 1.339g/L was found after cultivation for 5 days, while 0.969g/L of lipid yield was obtained after day 6 of cultivation time by using CO2 from air. A high value of volumetric lipid production rate (QP, 0.223 g/L/d), specific product yield (YP/X, 0.194), volumetric cell mass production rate (QX, 1.153 g/L/d) were found by using ambient air CO2 coupled with CO2 emissions from yeast fermentation. Overall lipid yield of 8.33 g/L was obtained (1.339 g/L of Chlorella sp. KKU-S2 and 7.06g/L of T. maleeae Y30) while low lipid yield of 0.969g/L was found using non-integrated cultivation technique. To our knowledge this is the unique report about the lipid production from locally microalgae Chlorella sp. KKU-S2 and yeast T. maleeae Y30 in an integrated technique to improve the biomass and lipid yield by using CO2 emissions from yeast fermentation.
Abstract: For numerical prediction of the NOX in the exhaust of
a compression ignition engine a model was developed by considering
the parameter equivalence ratio. This model was validated by
comparing the predicted results of NOX with experimental ones. The
ultimate aim of the work was to access the applicability, robustness
and performance of the improved NOX model against other NOX
models.
Abstract: Over 90% of the world trade is carried by the
international shipping industry. As most of the countries are
developing, seaborne trade continues to expand to bring benefits for
consumers across the world. Studies show that world trade will
increase 70-80% through shipping in the next 15-20 years. Present
global fleet of 70000 commercial ships consumes approximately 200
million tonnes of diesel fuel a year and it is expected that it will be
around 350 million tonnes a year by 2020. It will increase the
demand for fuel and also increase the concentration of CO2 in the
atmosphere. So, it-s essential to control this massive fuel
consumption and CO2 emission. The idea is to utilize a diesel-wind
hybrid system for ship propulsion. Use of wind energy by installing
modern wing-sails in ships can drastically reduce the consumption of
diesel fuel. A huge amount of wind energy is available in oceans.
Whenever wind is available the wing-sails would be deployed and
the diesel engine would be throttled down and still the same forward
speed would be maintained. Wind direction in a particular shipping
route is not same throughout; it changes depending upon the global
wind pattern which depends on the latitude. So, the wing-sail
orientation should be such that it optimizes the use of wind energy.
We have made a computer programme in which by feeding the data
regarding wind velocity, wind direction, ship-motion direction; we
can find out the best wing-sail position and fuel saving for
commercial ships. We have calculated net fuel saving in certain
international shipping routes, for instance, from Mumbai in India to
Durban in South Africa. Our estimates show that about 8.3% diesel
fuel can be saved by utilizing the wind. We are also developing an
experimental model of the ship employing airfoils (small scale wingsail)
and going to test it in National Wind Tunnel Facility in IIT
Kanpur in order to develop a control mechanism for a system of
airfoils.
Abstract: Biodiesel as an alternative fuel for diesel engines has been developed for some three decades now. While it is gaining wide acceptance in Europe, USA and some parts of Asia, the same cannot be said of Africa. With more than 35 countries in the continent depending on imported crude oil, it is necessary to look for alternative fuels which can be produced from resources available locally within any country. Hence this study presents performance of single cylinder diesel engine using blends of shea butter biodiesel. Shea butter was transformed into biodiesel by transesterification process. Tests are conducted to compare the biodiesel with baseline diesel fuel in terms of engine performance and exhaust emission characteristics. The results obtained showed that the addition of biodiesel to diesel fuel decreases the brake thermal efficiency (BTE) and increases the brake specific fuel consumption (BSFC). These results are expected due to the lower energy content of biodiesel fuel. On the other hand while the NOx emissions increased with increase in biodiesel content in the fuel blends, the emissions of carbon monoxide (CO), un-burnt hydrocarbon (UHC) and smoke opacity decreased. The engine performance which indicates that the biodiesel has properties and characteristics similar to diesel fuel and the reductions in exhaust emissions make shea butter biodiesel a viable additive or substitute to diesel fuel.