Abstract: The textile industry plays a major role in the economy
of India and on the other side of the coin it is the major source for
water pollution. As azo dyes is the largest dye class they are
extensively used in many fields such as textile industry, leather
tanning industry, paper production, food, color photography,
pharmaceuticals and medicine, cosmetic, hair colorings, wood
staining, agricultural, biological and chemical research etc. In
addition to these, they can have acute and/or chronic effects on
organisms depending on their concentration and length of exposure
when they discharged as effluent in the environment. The aim of this
study was to assess the genotoxic and histotoxic potentials of
environmentally relevant concentrations of C. I. Reactive Red 120
(RR 120) on Catla catla, important edible freshwater fingerlings. For
this, healthy Catla catla fingerlings were procured from the
Government Fish Farm and acclimatized in 100 L capacity and
continuously aerated glass aquarium in laboratory for 15 days.
According to APHA some physic-chemical parameters were
measured and maintained such as temperature, pH, dissolve oxygen,
alkalinity, total hardness. Water along with excreta had been changed
every 24 hrs. All fingerlings were fed artificial food palates once a
day @ body weight. After 15 days fingerlings were grouped in 5 (10
in each) and exposed to various concentrations of RR 120 (Control,
10, 20, 30 and 40 mg.l-1) and samples (peripheral blood and gills,
kidney) were collected and analyzed at 96 hrs. All results were
compared with the control. Micronuclei (MN), nuclear buds (NB),
fragmented-apoptotic (FA) and bi-nucleated (BN) cells in blood
smears and in tissues (gills and kidney cells) were observed.
Prominent histopathological alterations were noticed in gills such as
aneurism, hyperplasia, degenerated central axis, lifting of gill
epithelium, curved secondary gill lamellae etc. Similarly kidney
showed some detrimental changes like shrunken glomeruli with
increased periglomerular space, degenerated renal tubules etc. Both
haematological and histopathological changes clearly reveal the toxic
potential of RR 120. This work concludes that water pollution
assessment can be done by these two biomarkers which provide
baseline to the further chromosomal or molecular work.
Abstract: Verification of vented wooden façade system with
bonded joints is presented in this paper. The potential of bonded
joints is studied and described in more detail. The paper presents the results of an experimental and theoretical research about the effects of freeze cycling on the bonded joint. For the purpose of tests spruce
timber profiles were chosen for the load bearing substructure. Planks from wooden plastic composite and Siberian larch are representing facade cladding. Two types of industrial polyurethane adhesives intended for structural bonding were selected. The article is focused on the preparation as well as on the subsequent curing and conditioning of test samples. All test samples were subjected to 15 cycles that represents sudden temperature changes, i.e. immersion in a water bath at (293.15 ± 3) K for 6 hours and subsequent freezing to (253.15 ± 2) K for 18 hours. Furthermore, the retention of bond strength between substructure and cladding wastested and strength in shear was determined under tensile stress.Research data indicate that little, if any, damage to the bond results from freezingcycles. Additionally, the suitability of selected group of adhesives in combination with timber substructure was confirmed.
Abstract: The convective heat and mass transfer in nanofluid
flow through a porous media due to a permeable stretching sheet with
magnetic field, viscous dissipation, chemical reaction and Soret
effects are numerically investigated. Two types of nanofluids, namely
Cu-water and Ag-water were studied. The governing boundary layer
equations are formulated and reduced to a set of ordinary differential
equations using similarity transformations and then solved
numerically using the Keller box method. Numerical results are
obtained for the skin friction coefficient, Nusselt number and
Sherwood number as well as for the velocity, temperature and
concentration profiles for selected values of the governing
parameters. Excellent validation of the present numerical results has
been achieved with the earlier linearly stretching sheet problems in
the literature.
Abstract: This paper shortly describes various types of biomass
and a growing number of facilities utilizing the biomass in the Czech
Republic. The considerable part of this paper deals with energy
parameters of the most frequently used types of biomass and results
of their gasification testing. Sixteen most used "Czech" woody plants
and grasses were selected; raw, element and biochemical analyses
were performed and basic calorimetric values, ash composition, and
ash characteristic temperatures were identified. Later, each biofuel
was tested in a fluidized bed gasifier. The essential part of this paper
provides results of the gasification of selected biomass types.
Operating conditions are described in detail with a focus on
individual fuels properties. Gas composition and impurities content
are also identified. In terms of operating conditions and gas quality,
the essential difference occurred mainly between woody plants and
grasses. The woody plants were evaluated as more suitable fuels for
fluidized bed gasifiers. Testing results significantly help with a
decision-making process regarding suitability of energy plants for
growing and with a selection of optimal biomass-treatment
technology.
Abstract: Two finite element (FEM) models are presented in
this paper to address the random nature of the response of glued
timber structures made of wood segments with variable elastic
moduli evaluated from 3600 indentation measurements. This total
database served to create the same number of ensembles as was the
number of segments in the tested beam. Statistics of these ensembles
were then assigned to given segments of beams and the Latin
Hypercube Sampling (LHS) method was called to perform 100
simulations resulting into the ensemble of 100 deflections subjected
to statistical evaluation. Here, a detailed geometrical arrangement of
individual segments in the laminated beam was considered in the
construction of two-dimensional FEM model subjected to in fourpoint
bending to comply with the laboratory tests. Since laboratory
measurements of local elastic moduli may in general suffer from a
significant experimental error, it appears advantageous to exploit the
full scale measurements of timber beams, i.e. deflections, to improve
their prior distributions with the help of the Bayesian statistical
method. This, however, requires an efficient computational model
when simulating the laboratory tests numerically. To this end, a
simplified model based on Mindlin’s beam theory was established.
The improved posterior distributions show that the most significant
change of the Young’s modulus distribution takes place in laminae in
the most strained zones, i.e. in the top and bottom layers within the
beam center region. Posterior distributions of moduli of elasticity
were subsequently utilized in the 2D FEM model and compared with
the original simulations.
Abstract: This paper shows an experimental testing of a small
unit for combustion of solid fuels, such as charcoal and wood logs,
that can provide electricity. One of the concepts is that the unit does
not require qualified personnel for its operation. The unit itself is
composed of two main parts. The design requires a heat producing
stove and electricity producing thermoelectric generator. After the
construction the unit was tested and the results show that the
emission release is within the legislative requirements for emission
production and environmental protection. That qualifies such unit for
indoor application.
Abstract: Hurling a successful Construction and Demolition
Waste (C&DW) recycling operation around the globe is a challenge
today, predominantly because secondary materials markets are yet to
be integrated. Reducing, Reusing and recycling of (C&DW) have
been employed over the years, and various techniques have been
investigated. However, the economic and environmental viability of
its application seems limited. This paper discusses the costs and
benefits in using secondary materials and focus on investigating reuse
and recycling process for five major types of construction materials:
concrete, metal, wood, cardboard/paper and plasterboard. Data
obtained from demolition specialists and contractors are considered
and evaluated. The research paper found that construction material
recovery process fully incorporate a 3R’s principle contributing to
saving energy and natural resources. This scrutiny leads to the
empathy of grand challenges in construction material recovery
process. Recommendations to deepen material recovery process are
also discussed.
Abstract: The development of allometric models is crucial to
accurate forest biomass/carbon stock assessment. The aim of this
study was to develop a set of biomass prediction models that will
enable the determination of total tree aboveground biomass for
savannah woodland area in Niger State, Nigeria. Based on the data
collected through biometric measurements of 1816 trees and
destructive sampling of 36 trees, five species specific and one site
specific models were developed. The sample size was distributed
equally between the five most dominant species in the study site
(Vitellaria paradoxa, Irvingia gabonensis, Parkia biglobosa,
Anogeissus leiocarpus, Pterocarpus erinaceous). Firstly, the
equations were developed for five individual species. Secondly these
five species were mixed and were used to develop an allometric
equation of mixed species. Overall, there was a strong positive
relationship between total tree biomass and the stem diameter. The
coefficient of determination (R2 values) ranging from 0.93 to 0.99 P
< 0.001 were realised for the models; with considerable low standard
error of the estimates (SEE) which confirms that the total tree above
ground biomass has a significant relationship with the dbh. F-test
values for the biomass prediction models were also significant at p
Abstract: Surface modification and functionalization has been
an important tool for scientists in order to open new frontiers in
nanoscience and nanotechnology. Desired surface characteristics for
the intended applications can be achieved with surface
functionalization.
In this work, the effect of water soluble ligands on the adsorption
capabilities of silver nanoparticles onto AC which was synthesized
from German beech wood was investigated. Sodium borohydride
(NaBH4) and polyvinyl alcohol (PVA) were used as the ligands.
Silver nanoparticles with different surface coatings have average
sizes range from 10 to 13 nm. They were synthesized in aqueous
media by reducing Ag (I) ion in the presence of ligands. These
particles displayed adsorption tendencies towards AC when they
were mixed together and shaken in distilled water.
Silver nanoparticles (NaBH4-AgNPs) reduced and stabilized by
NaBH4 adsorbed onto AC with a homogenous dispersion of
aggregates with sizes in the range of 100-400 nm. Beside, silver
nanoparticles, which were prepared in the presence of both NaBH4
and PVA (NaBH4/PVA-Ag NPs), demonstrated that NaBH4/PVA-Ag
NPs adsorbed and dispersed homogenously but, they aggregated with
larger sizes on the AC surface (range from 300 to 600 nm). In
addition, desorption resistance of Ag nanoparticles were investigated
in distilled water. According to the results AgNPs were not desorbed
on the AC surface in distilled water.
Abstract: Polycyclic aromatic hydrocarbons (PAHs) are formed
during the pyrolysis of scrap tyres to produce tyre pyrolytic oil
(TPO). Due to carcinogenic, mutagenic, and toxic properties PAHs
are priority pollutants. Hence it is essential to remove PAHs from
TPO before utilising TPO as a petroleum fuel alternative (to run the
engine). Agricultural wastes have promising future to be utilized as
biosorbent due to their cost effectiveness, abundant availability, high
biosorption capacity and renewability. Various low cost adsorbents
were prepared from natural sources. Uptake of PAHs present in tyre
pyrolytic oil was investigated using various low-cost adsorbents of
natural origin including sawdust (shisham), coconut fiber, neem bark,
chitin, activated charcoal. Adsorption experiments of different PAHs
viz. naphthalene, acenaphthalene, biphenyl and anthracene have been
carried out at ambient temperature (25°C) and at pH 7. It was
observed that for any given PAH, the adsorption capacity increases
with the lignin content. Freundlich constant Kf and 1/n have been
evaluated and it was found that the adsorption isotherms of PAHs
were in agreement with a Freundlich model, while the uptake
capacity of PAHs followed the order: activated charcoal> saw dust
(shisham) > coconut fiber > chitin. The partition coefficients in
acetone-water, and the adsorption constants at equilibrium, could be
linearly correlated with octanol–water partition coefficients. It is
observed that natural adsorbents are good alternative for PAHs
removal. Sawdust of Dalbergia sissoo, a by-product of sawmills was
found to be a promising adsorbent for the removal of PAHs present in
TPO. It is observed that adsorbents studied were comparable to those
of some conventional adsorbents.
Abstract: In this study, an experiment was executed related to
the strength of wooden materials which have been commonly used
both in the past and present against pressure and whether fire
retardant materials used against fire have any effects or not. Totally
81 samples which included 3 different wood species, 3 different
sizes, 2 different fire retardants and 2 unprocessed samples were
prepared. Compressive pressure tests were applied to the prepared
samples, their variance analyses were executed in accordance with
the obtained results and it was aimed to determine the most
convenient wooden materials and fire-retardant coating material. It
was also determined that the species of wood and the species of
coating caused the decrease and/or increase in the resistance against
pressure.
Abstract: Effect of biopesticide from wood vinegar and
extracted substances from 3 medicinal plants such as: non taai yak
(Stemona tuberosa Lour), boraphet (Tinospora crispa Mier) and
derris (Derris elliptica Roxb) were tested on the age five years of
pomelo. The selected pomelo was carried out for insects’ pest control
and its quality. The experimental site was located at farmer’s orchard
in Phichit Province, Thailand. This study was undertaken during the
drought season (December to March). The extracted from plants and
wood vinegar were evaluated in 6 treatments: 1) water as control; 2)
wood vinegar; 3) S. tuberosa Lour; 4) T. crispa Mier; 5) D. elliptica
Roxb; 6) mixed (wood vinegar + S. tuberosa Lour + T. crispa Mier +
D. elliptica Roxb). The experiment was RCB with 6 treatments and 3
replications per treatment. The results showed that T. crispa Mier was
the highest effectiveness for reduction population of thrips
(Scirtothrips dorsalis Hood) and citrus leaf miner (Phyllocnistis
citrella Stainton) at 14.10 and 15.37 respectively, followed by
treatment of mixed, D. elliptica Roxb, S. tuberosa Lour and wood
vinegar with significance different. Additionally, T. crispa Mier
promoted the high quality of harvested pomelo in term of thickness
of skin at 12.45 mm and S. tuberosa Lour gave the high quality of the
pomelo in term of firmness (276.5 kg/cm2) and brix (11.0%).
Abstract: Artificial intelligence applications are commonly used
in industry in many fields in parallel with the developments in the
computer technology. In this study, a fire room was prepared for the
resistance of wooden construction elements and with the mechanism
here, the experiments of polished materials were carried out. By
utilizing from the experimental data, an artificial neural network
(ANN) was modelled in order to evaluate the final cross sections of
the wooden samples remaining from the fire. In modelling,
experimental data obtained from the fire room were used. In the
developed system, the first weight of samples (ws-gr), preliminary
cross-section (pcs-mm2), fire time (ft-minute), and fire temperature
(t-oC) as input parameters and final cross-section (fcs-mm2) as output
parameter were taken. When the results obtained from ANN and
experimental data are compared after making statistical analyses, the
data of two groups are determined to be coherent and seen to have no
meaning difference between them. As a result, it is seen that ANN
can be safely used in determining cross sections of wooden materials
after fire and it prevents many disadvantages.
Abstract: This study was developed to compare the behavior
and the ability of polymer foam composites towards sound absorption
test of Shorea leprosula wood (SL) of acid hydrolysis treatment with
particle size
Abstract: The main aim of this research was to investigate a
prototype bamboo shading device. There were two objectives to this
study: first, to investigate the effects of non-chemical treatments on
bamboo shading devices damaged by powder-post beetles and fungi,
and second to develop a prototype bamboo shading device. This
study of the effects of non-chemical treatments on bamboo shading
devices damage by powder-post beetles in the laboratory showed
that, among seven treatments tested, wood vinegar treatment can
protect powder-post beetles better than the original method by up to
92.91%. It was also found that wood vinegar treatment shows the
best performance in fungi protection and works better than the
original method by up to 40%. A second experiment was carried out
by constructing four bamboo shading devices and installing them on
a building for 28 days. All aspects of shading device were
investigated in terms of their beauty, durability, and ease of
construction and assembly. The final prototype was developed from
the lessons learned from the test results. In conclusion, this study
showed the effectiveness of some natural preservatives against insect
and fungi damage, and it also illustrated the characteristics of a
prototype bamboo shading device that can be constructed by rural
workers within one week.
Abstract: The use OF adhesive anchors for wooden constructions is an efficient technology to connect and design timber members in new timber structures and to rehabilitate the damaged structural members of historical buildings. Due to the lack of standard regulation in this specific area of structural design, designers’ choices are still supported by test analysis that enables knowledge, and the prediction, of the structural behaviour of glued in rod joints. The paper outlines an experimental research activity aimed at identifying the tensile resistance capacity of several new adhesive joint prototypes made of epoxy resin, steel bar and timber, Oak and Douglas Fir species. The development of new adhesive connectors has been carried out by using epoxy to glue stainless steel bars into pre-drilled holes, characterised by smooth and rough internal surfaces, in timber samples. The realization of a threaded contact surface using a specific drill bit has led to an improved bond between wood and epoxy. The applied changes have also reduced the cost of the joints’ production. The paper presents the results of this parametric analysis and a Finite Element analysis that enables identification and study of the internal stress distribution in the proposed adhesive anchors.
Abstract: The industrial process adds to engineering wood
products features absent in solid wood, with homogeneous structure
and reduced defects, improved physical and mechanical properties,
bio-deterioration, resistance and better dimensional stability,
improving quality and increasing the reliability of structures wood.
These features combined with using fast-growing trees, make them
environmentally ecological products, ensuring a strong consumer
market. The wood I-joists are manufactured by the industrial profiles
bonding flange and web, an important aspect of the production of
wooden I-beams is the adhesive joint that bonds the web to the
flange. Adhesives can effectively transfer and distribute stresses,
thereby increasing the strength and stiffness of the composite. The
objective of this study is to evaluate different resins in a shear strain
specimens with the aim of analyzing the most efficient resin and
possibility of using national products, reducing the manufacturing
cost. First was conducted a literature review, where established the
geometry and materials generally used, then established and analyzed
8 national resins and produced six specimens for each.
Abstract: An analysis is carried out to investigate the effect of
magnetic field and heat source on the steady boundary layer flow and
heat transfer of a Casson nanofluid over a vertical cylinder stretching
exponentially along its radial direction. Using a similarity
transformation, the governing mathematical equations, with the
boundary conditions are reduced to a system of coupled, non –linear
ordinary differential equations. The resulting system is solved
numerically by the fourth order Runge – Kutta scheme with shooting
technique. The influence of various physical parameters such as
Reynolds number, Prandtl number, magnetic field, Brownian motion
parameter, thermophoresis parameter, Lewis number and the natural
convection parameter are presented graphically and discussed for non
– dimensional velocity, temperature and nanoparticle volume
fraction. Numerical data for the skin – friction coefficient, local
Nusselt number and the local Sherwood number have been tabulated
for various parametric conditions. It is found that the local Nusselt
number is a decreasing function of Brownian motion parameter Nb
and the thermophoresis parameter Nt.
Abstract: Eucalyptus species are well reputed for their
traditional use in Asia as well as in other parts of the world; therefore,
the present study was designed to investigate the antimicrobial and
antioxidant activities associated with essential oils from different
Eucalyptus species. Essential oils from the leaves of six Eucalyptus
species, including: Eucalyptus woodwardi, Eucalyptus stricklandii,
Eucalyptus salubris, Eucalyptus sargentii, Eucalyptus torquata and
Eucalyptus wandoo were separated by hydrodistillation and dried
over anhydrous sodium sulphate. DPPH, ferric reducing antioxidant
power, and hydroxyl radical scavenging activity assays were carried
out to evaluate the antioxidant potential of the oils. The results
indicate that examined oils exhibit substantial antioxidant activities
relative to ascorbic acid. Previously, these oils were evaluated for
their antimicrobial activities, against wide range of bacterial and
fungal strains, and they were shown to possess significant
antimicrobial activities. In this study, further investigation into the
growth kinetics of oil-treated microbial cultures was conducted. The
results clearly demonstrate that the microbial growth was markedly
inhibited when treated with sub-MIC concentrations of the oils.
Taken together, the results obtained indicate a high potential of the
examined essential oils as bioactive oils, for nutraceutical and
medical applications, possessing significant antioxidant and anti
microbial activities.
Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.