Abstract: The present work presents the extraction of copper(II)
from sulphuric acid solutions with Sodium diethyldithiocarbamate
(SDDT), and six different organic diluents: Dichloromethane,
Chloroform, Carbon tetrachloride, Toluene, xylene and Cyclohexane,
were tested. The pair SDDT/Chloroform showed to be the most
selective in removing the copper cations, and hence was considered
throughout the experimental study.
The effects of operating parameters such as the initial concentration
of the extracting agent, the agitation time, the agitation speed and the
acid concentration were considered.
For an initial concentration of Cu (II) of 63 ppm in a 0.5 M sulphuric
acid solution, both with a mass of the extracting agent of 20 mg, an
extraction percentage of about 97.8 % and a distribution coefficient
of 44.42 were obtained, respectively, confirming the performance
of the SDDT-Chloroform pair.
Abstract: Sulphur dioxide is a harmful gaseous product that
needs to be minimized in the atmosphere. This research work
investigates the use of zeolite as a possible additive that can improve
the sulphur dioxide capture in wet flue gas desulphurisation
dissolution process. This work determines the effect of temperature,
solid to liquid ratio, acid concentration and stirring speed on the
leaching of zeolite using a pH stat apparatus. The atomic absorption
spectrometer was used to measure the calcium ions from the solution.
It was found that the dissolution rate of zeolite decreased with
increase in solid to liquid ratio and increases with increase in
temperature, stirring speed and acid concentration. The activation
energy for the dissolution rate of zeolite in hydrochloric acid was
found to be 9.29kJ/mol. and therefore the product layer diffusion was
the rate limiting step.
Abstract: This work deals with modeling and simulation of SO2 removal in a ceramic membrane by means of FEM. A mass transfer model was developed to predict the performance of SO2 absorption in a chemical solvent. The model was based on solving conservation equations for gas component in the membrane. Computational fluid dynamics (CFD) of mass and momentum were used to solve the model equations. The simulations aimed to obtain the distribution of gas concentration in the absorption process. The effect of the operating parameters on the efficiency of the ceramic membrane was evaluated. The modeling findings showed that the gas phase velocity has significant effect on the removal of gas whereas the liquid phase does not affect the SO2 removal significantly. It is also indicated that the main mass transfer resistance is placed in the membrane and gas phase because of high tortuosity of the ceramic membrane.
Abstract: Coarse and fine particulate matter were collected at a
residential area at Vashi, Navi Mumbai and the filter samples were
analysed for trace elements using PIXE technique. The trend of
particulate matter showed higher concentrations during winter than
the summer and monsoon concentration levels. High concentrations
of elements related to soil and sea salt were found in PM10 and
PM2.5. Also high levels of zinc and sulphur found in the particulates
of both the size fractions. EF analysis showed enrichment of Cu, Cr
and Mn only in the fine fraction suggesting their origin from
anthropogenic sources. The EF value was observed to be maximum
for As, Pb and Zn in the fine particulates. However, crustal derived
elements showed very low EF values indicating their origin from
soil. The PCA based multivariate studies identified soil, sea salt,
combustion and Se sources as common sources for coarse and
additionally an industrial source has also been identified for fine
particles.