Abstract: High-density polyethylene reinforced with carbon nanofibers (HDPE/CNF) have been prepared via melt processing using dialkylimidazolium tetrafluoroborate (ionic liquid) as a dispersion agent. The prepared samples were characterized by thermogravimetric (TGA) and differential scanning calorimetric (DSC) analyses. The samples blended with imidazolium ionic liquid exhibit higher thermal stability. DSC analysis showed clear miscibility of ionic liquid in the HDPE matrix and showed single endothermic peak. The melt rheological analysis of HDPE/CNF composites was performed using an oscillatory rheometer. The influence of CNF and ionic liquid concentration (ranging from 0, 0.5, and 1 wt%) on the viscoelastic parameters was investigated at 200 °C with an angular frequency range of 0.1 to 100 rad/s. The rheological analysis shows the shear-thinning behavior for the composites. An improvement in the viscoelastic properties was observed as the nanofiber concentration increases. The progress in the modulus values was attributed to the structural rigidity imparted by the high aspect ratio CNF. The modulus values and complex viscosity of the composites increased significantly at low frequencies. Composites blended with ionic liquid exhibit slightly lower values of complex viscosity and modulus over the corresponding HDPE/CNF compositions. Therefore, reduction in melt viscosity is an additional benefit for polymer composite processing as a result of wetting effect by polymer-ionic liquid combinations.
Abstract: Non-Newtonian fluid properties can change the flow
behaviour significantly, its prediction is more difficult when thermal
effects come into play. Hence, the focal point of this work is the
wake flow behind a heated circular cylinder in the laminar vortex
shedding regime for thermo-viscous shear thinning fluids. In the case
of isothermal flows of Newtonian fluids the vortex shedding regime
is characterised by a distinct Reynolds number and an associated
Strouhal number. In the case of thermo-viscous shear thinning
fluids the flow regime can significantly change in dependence of
the temperature of the viscous wall of the cylinder. The Reynolds
number alters locally and, consequentially, the Strouhal number
globally. In the present CFD study the temperature dependence of
the Reynolds and Strouhal number is investigated for the flow of a
Carreau fluid around a heated cylinder. The temperature dependence
of the fluid viscosity has been modelled by applying the standard
Williams-Landel-Ferry (WLF) equation. In the present simulation
campaign thermal boundary conditions have been varied over a
wide range in order to derive a relation between dimensionless heat
transfer, Reynolds and Strouhal number. Together with the shear
thinning due to the high shear rates close to the cylinder wall
this leads to a significant decrease of viscosity of three orders of
magnitude in the nearfield of the cylinder and a reduction of two
orders of magnitude in the wake field. Yet the shear thinning effect
is able to change the flow topology: a complex K´arm´an vortex street
occurs, also revealing distinct characteristic frequencies associated
with the dominant and sub-dominant vortices. Heating up the cylinder
wall leads to a delayed flow separation and narrower wake flow,
giving lesser space for the sequence of counter-rotating vortices. This
spatial limitation does not only reduce the amplitude of the oscillating
wake flow it also shifts the dominant frequency to higher frequencies,
furthermore it damps higher harmonics. Eventually the locally heated
wake flow smears out. Eventually, the CFD simulation results of the
systematically varied thermal flow parameter study have been used
to describe a relation for the main characteristic order parameters.
Abstract: Ice slurries are considered as a promising phase-changing secondary fluids for air-conditioning, packaging or cooling industrial processes. An experimental study has been here carried out to measure the rheological characteristics of ice slurries. Ice slurries consist in a solid phase (flake ice crystals) and a liquid phase. The later is composed of a mixture of liquid water and an additive being here either (1) Propylene-Glycol (PG) or (2) Ethylene-Glycol (EG) used to lower the freezing point of water. Concentrations of 5%, 14% and 24% of both additives are investigated with ice mass fractions ranging from 5% to 85%. The rheological measurements are carried out using a Discovery HR-2 vane-concentric cylinder with four full-length blades. The experimental results show that the behavior of ice slurries is generally non-Newtonian with shear-thinning or shear-thickening behaviors depending on the experimental conditions. In order to determine the consistency and the flow index, the Herschel-Bulkley model is used to describe the behavior of ice slurries. The present results are finally validated against an experimental database found in the literature and the predictions of an Artificial Neural Network model.
Abstract: This study aims to investigate the mixing behaviors of
deionized (DI) water and carboxymethyl cellulose (CMC) solutions in
C-shaped serpentine micromixers over a wide range of flow
conditions. The flow of CMC solutions exhibits shear-thinning
behaviors. Numerical simulations are performed to investigate the
effects of the mean flow speed, fluid properties and geometry
parameters on flow and mixing in the micromixers with the serpentine
channel of the same overall channel length. From the results, we can
find the following trends. When convection dominates fluid mixing,
the curvature-induced vortices enhance fluid mixing effectively. The
mixing efficiency of a micromixer consisting of semicircular C-shaped
repeating units with a smaller centerline radius is better than that of a
micromixer consisting of major segment repeating units with a larger
centerline radius. The viscosity of DI water is less than the overall
average apparent viscosity of CMC solutions, and so the effect of
curvature-induced vortices on fluid mixing in DI water is larger than
that in CMC solutions for the cases with the same mean flow speed.
Abstract: Solid lipid nanoparticles (SLNs) have gained great attention for the topical treatment of skin associated fungal infection as they facilitate the skin penetration of loaded drugs. Our work deals with the preparation of nystatin loaded solid lipid nanoparticles (NystSLNs) using the hot homogenization and ultrasonication method. The prepared NystSLNs were characterized in terms of entrapment efficiency, particle size, zeta potential, transmission electron microscopy, differential scanning calorimetry, rheological behavior and in vitro drug release. A stability study for 6 months was performed. A microbiological study was conducted in male rats infected with Candida albicans, by counting the colonies and examining the histopathological changes induced on the skin of infected rats. The results showed that SLNs dispersions are spherical in shape with particle size ranging from 83.26±11.33 to 955.04±1.09 nm. The entrapment efficiencies are ranging from 19.73±1.21 to 72.46±0.66% with zeta potential ranging from -18.9 to -38.8 mV and shear-thinning rheological Behavior. The stability studies done for 6 months showed that nystatin (Nyst) is a good candidate for topical SLN formulations. A least number of colony forming unit/ ml (cfu/ml) was recorded for the selected NystSLN compared to the drug solution and the commercial Nystatin® cream present in the market. It can be fulfilled from this work that SLNs provide a good skin targeting effect and may represent promising carrier for topical delivery of Nyst offering the sustained release and maintaining the localized effect, resulting in an effective treatment of cutaneous fungal infection.
Abstract: The influence of transverse surface roughness on EHL characteristics has been investigated numerically using an extensive set of full EHL line contact simulations for shear-thinning lubricants under pure sliding condition. The shear-thinning behavior of lubricant is modeled using Carreau viscosity equation along with Doolittle-Tait equation for lubricant compressibility. The surface roughness is assumed to be sinusoidal and it is present on the stationary surface. It is found that surface roughness causes sharp pressure peaks along with reduction in central and minimum film thickness. With increasing amplitude of surface roughness, the minimum film thickness decreases much more rapidly as compared to the central film thickness.