Abstract: Density functional theory (DFT) calculations were
performed to compute nitrogen-14 and boron-11 nuclear quadrupole
resonance (NQR) spectroscopy parameters in the representative
model of armchair boron nitride nanotube (BNNT) for the first time.
The considered model consisting of 1 nm length of H-capped (5, 5)
single-wall BNNT were first allowed to fully relax and then the NQR
calculations were carried out on the geometrically optimized model.
The evaluated nuclear quadrupole coupling constants and asymmetry
parameters for the mentioned nuclei reveal that the model can be
divided into seven layers of nuclei with an equivalent electrostatic
environment where those nuclei at the ends of tubes have a very
strong electrostatic environment compared to the other nuclei along
the length of tubes. The calculations were performed via Gaussian 98
package of program.
Abstract: Acid rain occurs when sulphur dioxide (SO2) and
nitrogen oxides (Nox) gases react in the atmosphere with water,
oxygen, and other chemicals to form various acidic compounds. The
result is a mild solution of sulfuric acid and nitric acid. Soil has a
greater buffering capacity than aquatic systems. However excessive
amount of acids introduced by acid rains may disturb the entire soil
chemistry. Acidity and harmful action of toxic elements damage
vegetation while susceptible microbial species are eliminated. In
present study, the effects of simulated sulphuric acid and nitric acid
rains were investigated on crop Glycine max. The effect of acid rain
on change in soil fertility was detected in which pH of control sample
was 6.5 and pH of 1%H2SO4 and 1%HNO3 were 3.5. Nitrogen nitrate
in soil was high in 1% HNO3 treated soil & Control sample.
Ammonium nitrogen in soil was low in 1% HNO3 & H2SO4 treated
soil. Ammonium nitrogen was medium in control and other samples.
The effect of acid rain on seed germination on 3rd day of germination
control sample growth was 7 cm, 0.1% HNO3 was 8cm, and 0.001%
HNO3 & 0.001% H2SO4 was 6cm each. On 10th day fungal growth
was observed in 1% and 0.1%H2SO4 concentrations, when all plants
were dead. The effect of acid rain on crop productivity was
investigated on 3rd day roots were developed in plants. On12th day
Glycine max showed more growth in 0.1% HNO3, 0.001% HNO3 and
0.001% H2SO4 treated plants growth were same as compare to control
plants. On 20th day development of discoloration of plant pigments
were observed on acid treated plants leaves. On 38th day, 0.1, 0.001%
HNO3 and 0.1, 0.001% H2SO4 treated plants and control plants were
showing flower growth. On 42th day, acid treated Glycine max variety
and control plants were showed seeds on plants. In Glycine max
variety 0.1, 0.001% H2SO4, 0.1, 0.001% HNO3 treated plants were
dead on 46th day and fungal growth was observed. The toxicological
study was carried out on Glycine max plants exposed to 1% HNO3
cells were damaged more than 1% H2SO4. Leaf sections exposed to
0.001% HNO3 & H2SO4 showed less damaged of cells and
pigmentation observed in entire slide when compare with control
plant. The soil analysis was done to find microorganisms in HNO3 &
H2SO4 treated Glycine max and control plants. No microorganism
growth was observed in 1% HNO3 & H2SO4 but control plant showed
microbial growth.
Abstract: Land degradation is of concern in many countries. People more and more must address the problems associated with the degradation of soil properties due to man. Increasingly, organic soil amendments, such as compost are being examined for their potential use in soil restoration and for preventing soil erosion. In the Czech Republic, compost is the most used to improve soil structure and increase the content of soil organic matter. Land reclamation / restoration is one of the ways to evaluate industrially produced compost because Czech farmers are not willing to use compost as organic fertilizer. The most common use of reclamation substrates in the Czech Republic is for the rehabilitation of landfills and contaminated sites.
This paper deals with the influence of reclamation substrates (RS) with different proportions of compost and sand on selected soil properties–chemical characteristics, nitrogen bioavailability, leaching of mineral nitrogen, respiration activity and plant biomass production. Chemical properties vary proportionally with addition of compost and sand to the control variant (topsoil). The highest differences between the variants were recorded in leaching of mineral nitrogen (varies from 1.36mg dm-3 in C to 9.09mg dm-3). Addition of compost to soil improves conditions for plant growth in comparison with soil alone. However, too high addition of compost may have adverse effects on plant growth. In addition, high proportion of compost increases leaching of mineral N. Therefore, mixture of 70% of soil with 10% of compost and 20% of sand may be recommended as optimal composition of RS.
Abstract: The aim of this study was to investigate the
effectiveness of anaerobic digestion for the treatment of wool
scouring wastes. The experiments design comprised three ratios of
waste (W) to seed(S) (W:S) of 25:75, 50:50 and 75:25, corresponding
to 1.9. 1.7 and 1.5g tCOD/g TS, respectively, with or without
chemicals addition. NH4Cl was added to the reactors as a source for
nitrogen to achieve C:N:P of 420:14:3. A cationic flocculent was
added at 0.5 and 0.75% to enhance flocculation of sludge. The results
showed that the reactors that received W:S at a ratio of 25:75
produced the largest volume of biogas. The final soluble COD
(sCOD) was below the limits for discharge to the sewer system.
Abstract: The aim of this study was to screen for
microorganism that able to utilize 3-N-trimethylamino-1-propanol
(homocholine) as a sole source of carbon and nitrogen. The aerobic
degradation of homocholine has been found by a gram-positive
Rhodococcus sp. bacterium isolated from soil. The isolate was
identified as Rhodococcus sp. strain A4 based on the phenotypic
features, physiologic and biochemical characteristics, and
phylogenetic analysis. The cells of the isolated strain grown on both
basal-TMAP and nutrient agar medium displayed elementary
branching mycelia fragmented into irregular rod and coccoid
elements. Comparative 16S rDNA sequencing studies indicated that
the strain A4 falls into the Rhodococcus erythropolis subclade and
forms a monophyletic group with the type-strains of R. opacus, and
R. wratislaviensis. Metabolites analysis by capillary electrophoresis,
fast atom bombardment-mass spectrometry, and gas
chromatography- mass spectrometry, showed trimethylamine (TMA)
as the major metabolite beside β-alanine betaine and
trimethylaminopropionaldehyde. Therefore, the possible degradation
pathway of trimethylamino propanol in the isolated strain is through
consequence oxidation of alcohol group (-OH) to aldehyde (-CHO)
and acid (-COOH), and thereafter the cleavage of β-alanine betaine
C-N bonds yielded trimethylamine and alkyl chain.
Abstract: The paper provides biomasses characteristics by
proximate analysis (volatile matter, fixed carbon and ash) and
ultimate analysis (carbon, hydrogen, nitrogen and oxygen) for the
prediction of the heating value equations. The heating value
estimation of various biomasses can be used as an energy evaluation.
Thirteen types of biomass were studied. Proximate analysis was
investigated by mass loss method and infrared moisture analyzer.
Ultimate analysis was analyzed by CHNO analyzer. The heating
values varied from 15 to 22.4MJ kg-1. Correlations of the calculated
heating value with proximate and ultimate analyses were undertaken
using multiple regression analysis and summarized into three and two
equations, respectively. Correlations based on proximate analysis
illustrated that deviation of calculated heating values from
experimental heating values was higher than the correlations based
on ultimate analysis.
Abstract: Since 2005, an SRF module of CESR type serves as the
accelerating cavity at the Taiwan Light Source in the National
Synchrotron Radiation Research Center. A 500-MHz niobium cavity
is immersed in liquid helium inside this SRF module. To reduce heat
load, the liquid helium vessel is thermally shielded by
liquid-nitrogen-cooled copper layer, and the beam chambers are also
anchored with pipes of the liquid nitrogen flow in middle of the liquid
helium vessel and the vacuum vessel. A strong correlation of the
movement of the cavity-s frequency tuner with the temperature
variation of parts cooled with liquid nitrogen was observed. A
previous study on a spare SRF module with the niobium cavity cooled
by liquid nitrogen instead of liquid helium, satisfactory suppression of
the thermal oscillation was achieved by attaching a temporary buffer
tank for the vented shielding nitrogen flow from the SRF module. In
this study, a home-made buffer tank is designed and integrated to the
spare SRF module with cavity cooled by liquid helium. Design,
construction, integration, and preliminary test results of this buffer
tank are presented.
Abstract: In composting process, N high-organic wastes loss the
great part of its nitrogen as ammonia; therefore, using compost
amendments can promote the quality of compost due to the decrease
in ammonia volatilization. With regard to the effect of pH on
composting, microorganisms- activity and ammonia volatilization,
sulfuric acid and alkaline wastewater of paper mill (as liming agent
with Ca and Mg ions) were used as compost amendments. Study
results indicated that these amendments are suitable for reclamation
of compost quality properties. These held nitrogen in compost caused
to reduce C/N ratio. Both amendments had a significant effect on
total nitrogen, but it should be used sulfuric acid in fewer amounts
(20 ml/kg fresh organic wastes); and the more amounts of acid is not
proposed.
Abstract: The Bangalore City is facing the acute problem of
pollution in the atmosphere due to the heavy increase in the traffic
and developmental activities in recent years. The present study is an
attempt in the direction to assess trend of the ambient air quality
status of three stations, viz., AMCO Batteries Factory, Mysore Road,
GRAPHITE INDIA FACTORY, KHB Industrial Area, Whitefield
and Ananda Rao Circle, Gandhinagar with respect to some of the
major criteria pollutants such as Total Suspended particular matter
(SPM), Oxides of nitrogen (NOx), and Oxides of sulphur (SO2). The
sites are representative of various kinds of growths viz., commercial,
residential and industrial, prevailing in Bangalore, which are
contributing to air pollution. The concentration of Sulphur Dioxide
(SO2) at all locations showed a falling trend due to use of refined
petrol and diesel in the recent years. The concentration of Oxides of
nitrogen (NOx) showed an increasing trend but was within the
permissible limits. The concentration of the Suspended particular
matter (SPM) showed the mixed trend. The correlation between
model and observed values is found to vary from 0.4 to 0.7 for SO2,
0.45 to 0.65 for NOx and 0.4 to 0.6 for SPM. About 80% of data is
observed to fall within the error band of ±50%. Forecast test for the
best fit models showed the same trend as actual values in most of the
cases. However, the deviation observed in few cases could be
attributed to change in quality of petro products, increase in the
volume of traffic, introduction of LPG as fuel in many types of
automobiles, poor condition of roads, prevailing meteorological
conditions, etc.
Abstract: Wheat gluten hydrolyzates (WGHs) and anchovy fine
powder hydrolyzates (AFPHs) were produced at 300 MPa using
combinations of Flavourzyme 500MG (F), Alcalase 2.4L (A),
Marugoto E (M) and Protamex (P), and then were compared to those
produced at ambient pressure concerning the contents of soluble solid
(SS), soluble nitrogen and electrophoretic profiles. The contents of SS
in the WGHs and AFPHs increased up to 87.2% according to the
increase in enzyme number both at high and ambient pressure. Based
on SS content, the optimum enzyme combinations for one-, two-,
three- and four-enzyme hydrolysis were determined as F, FA, FAM
and FAMP, respectively. Similar trends were found for the contents of
total soluble nitrogen (TSN) and TCA-soluble nitrogen (TCASN). The
contents of SS, TSN and TCASN in the hydrolyzates together with
electrophoretic mobility maps indicates that the high-pressure
treatment of this study accelerated protein hydrolysis compared to
ambient-pressure treatment.
Abstract: Influence of octane and benzene on plant cell
ultrastructure and enzymes of basic metabolism, such as nitrogen
assimilation and energy generation have been studied. Different
plants: perennial ryegrass (Lolium perenne) and alfalfa (Medicago
sativa); crops- maize (Zea mays L.) and bean (Phaseolus vulgaris);
shrubs – privet (Ligustrum sempervirens) and trifoliate orange
(Poncirus trifoliate); trees - poplar (Populus deltoides) and white
mulberry (Morus alba L.) were exposed to hydrocarbons of different
concentrations (1, 10 and 100 mM). Destructive changes in bean and
maize leaves cells ultrastructure under the influence of benzene
vapour were revealed at the level of photosynthetic and energy
generation subcellular organells. Different deviations at the level of
subcellular organelles structure and distribution were observed in
alfalfa and ryegrass root cells under the influence of benzene and
octane, absorbed through roots. The level of destructive changes is
concentration dependent. Benzene at low 1 and 10 mM concentration
caused the increase in glutamate dehydrogenase (GDH) activity in
maize roots and leaves and in poplar and mulberry shoots, though to
higher extent in case of lower, 1mM concentration. The induction
was more intensive in plant roots. The highest tested 100mM
concentration of benzene was inhibitory to the enzyme in all plants.
Octane caused induction of GDH in all grassy plants at all tested
concentrations; however the rate of induction decreased parallel to
increase of the hydrocarbon concentration. Octane at concentration 1
mM caused induction of GDH in privet, trifoliate and white mulberry
shoots. The highest, 100mM octane was characterized by inhibitory
effect to GDH activity in all plants. Octane had inductive effect on
malate dehydrogenase in almost all plants and tested concentrations,
indicating the intensification of Trycarboxylic Acid Cycle.
The data could be suggested for elaboration of criteria for plant
selection for phytoremediation of oil hydrocarbons contaminated
soils.
Abstract: This paper presents an integrated knowledge-based
approach to multi-scale modeling of aquatic systems, with a view to
enhancing predictive power and aiding environmental management
and policy-making. The basic phases of this approach have been
exemplified in the case of a bay in Saronicos Gulf (Attiki, Greece).
The results showed a significant problem with rising phytoplankton
blooms linked to excessive microbial growth, arisen mostly due to
increased nitrogen inflows; therefore, the nitrification/denitrification
processes of the benthic and water column sub-systems have
provided the quality variables to be monitored for assessing
environmental status. It is thereby demonstrated that the proposed
approach facilitates modeling choices and implementation option
decisions, while it provides substantial support for knowledge and
experience capitalization in long-term water management.
Abstract: In order to evaluate the relationship between the sulphur (S), glucose (G), nitrogen (N) and plant residues (st), sulphur immobilization and microbial transformation were monitored in five soil samples from 0-30 cm of Bastam farmers fields of Shahrood area following 11 treatments with different levels of Sulphur (S), glucose (G), N and plant residues (wheat straw) in a randomized block design with three replications and incubated over 20, 45 and 60 days, the immobilization of SO4 -2-S presented as a percentage of that added, was inversely related to its addition rate. Additions of glucose and plant residues increased with the C-to-S ratio of the added amendments, irrespective of their origins (glucose and plant residues). In the presence of C sources (glucose or plant residues). N significantly increased the immobilization of SO4 -2-S, whilst the effect of N was insignificant in the absence of a C amendment. In first few days the amounts of added SO4 -2-S immobilized were linearly correlated with the amounts of added S recovered in the soil microbial biomass. With further incubation the proportions of immobilized SO4 -2-S remaining as biomass-S decreased. Decrease in biomass-S was thought to be due to the conversion of biomass-S into soil organic-S. Glucose addition increased the immobilization (microbial utilization and incorporation into the soil organic matter) of native soil SO4 -2-S. However, N addition enhance the mineralization of soil organic-S, increasing the concentration of SO4 - 2-S in soil.
Abstract: The kinetics of palm oil catalytic cracking over
aluminum containing mesoporous silica Al-MCM-41 (5% Al) was
investigated in a batch autoclave reactor at the temperatures range of
573 – 673 K. The catalyst was prepared by using sol-gel technique
and has been characterized by nitrogen adsorption and x-ray
diffraction methods. Surface area of 1276 m2/g with average pore
diameter of 2.54 nm and pore volume of 0.811 cm3/g was obtained.
The experimental catalytic cracking runs were conducted using 50 g
of oil and 1 g of catalyst. The reaction pressure was recorded at
different time intervals and the data were analyzed using Levenberg-
Marquardt (LM) algorithm using polymath software. The results
show that the reaction order was found to be -1.5 and activation
energy of 3200 J/gmol.
Abstract: In China, with the rapid urbanization and
industrialization, and highly accelerated economic development have
resulted in degradation of water resource. The water quality
deterioration usual result from eutrophication in most cases, so how to
dispose this type pollution water higher efficiently is an urgent task.
Hower, different with traditional technology, constructed wetlands are
effective treatment systems that can be very useful because they are
simple technology and low operational cost. A pilot-scale treatment
including constructed wetlands was constructed at XingYun Lake,
Yuxi, China, and operated as primary treatment measure before
eutrophic-lake water draining to riverine landscape. Water quality
indices were determined during the experiment, the results indicated
that treatment removal efficiencies were high for Nitrate nitrogen,
Chlorophyll–a and Algae, the final removal efficiency reached to
95.20%, 93.33% and 99.87% respectively, but the removal efficiency
of Total phosphorous and Total nitrogen only reach to 68.83% and
50.00% respectively.
Abstract: The present paper develops and validates a numerical procedure for the calculation of turbulent combustive flow in converging and diverging ducts and throuh simulation of the heat transfer processes, the amount of production and spread of Nox pollutant has been measured. A marching integration solution procedure employing the TDMA is used to solve the discretized equations. The turbulence model is the Prandtl Mixing Length method. Modeling the combustion process is done by the use of Arrhenius and Eddy Dissipation method. Thermal mechanism has been utilized for modeling the process of forming the nitrogen oxides. Finite difference method and Genmix numerical code are used for numerical solution of equations. Our results indicate the important influence of the limiting diverging angle of diffuser on the coefficient of recovering of pressure. Moreover, due to the intense dependence of Nox pollutant to the maximum temperature in the domain with this feature, the Nox pollutant amount is also in maximum level.
Abstract: A study was undertaken to investigate the effect of
liquid nitrogen aeration on mortalities of adult Cryptolestes
furrugineus, rusty grain beetles, in a prototype cardboard grain bin
equipped with an aeration system. The grain bin was filled with Hard
Red Spring wheat and liquid nitrogen was introduced from the bottom
of the bin. The survival of both cold acclimated and unacclimated C.
furrugineus was tested. The study reveals that cold acclimated insects
had higher survival than unacclimated insects under similar cooling
conditions. In most cases, mortalities of as high as 100% were
achieved at the bottom 100 cm of the grain bin for unacclimated
insects for most of the trials. Insect survival increased as the distance
from the bottom of the grain bin increased. There was no adverse
effect of liquid nitrogen aeration on wheat germination.
Abstract: Films of pure tin oxide SnO2 and in presence of
antimony atoms (SnO2-Sb) deposited onto glass substrates have
shown a sufficiently high energy gap to be transparent in the visible
region, a high electrical mobility and a carrier concentration which
displays a good electrical conductivity [1]. In this work, the effects of
polycrystalline silicon substrate on the optical properties of pure and
Sb doped tin oxide is investigated.
We used the APCVD (atmospheric pressure chemical vapour
deposition) technique, which is a low-cost and simple technique,
under nitrogen ambient, for growing this material. A series of SnO2
and SnO2-Sb have been deposited onto polycrystalline silicon
substrates with different contents of antimony atoms at the same
conditions of deposition (substrate temperature, flow oxygen,
duration and nitrogen atmosphere of the reactor). The effect of the
substrate in terms of morphology and nonlinear optical properties,
mainly the reflectance, was studied. The reflectance intensity of the
device, compared to the reflectance of tin oxide films deposited
directly on glass substrate, is clearly reduced on the overall
wavelength range. It is obvious that the roughness of the poly-c
silicon plays an important role by improving the reflectance and
hence the optical parameters.
A clear shift in the minimum of the reflectance upon doping level
is observed. This minimum corresponds to strong free carrier
absorption, resulting in different plasma frequency. This effect is
followed by an increase in the reflectance depending of the antimony
doping. Applying the extended Drude theory to the combining
optical and electrical obtained results these effects are discussed.
Abstract: Homogeneous Charge Compression (HCCI) Ignition technology has been around for a long time, but has recently received renewed attention and enthusiasm. This paper deals with experimental investigations of HCCI engine using hydrous methanol as a primary fuel and Dimethyl Ether (DME) as an ignition improver. A regular diesel engine has been modified to work as HCCI engine for this investigation. The hydrous methanol is inducted and DME is injected into a single cylinder engine. Hence, hydrous methanol is used with 15% water content in HCCI engine and its performance and emission behavior is documented. The auto-ignition of Methanol is enabled by DME. The quantity of DME varies with respect to the load. In this study, the experiments are conducted independently and the effect of the hydrous methanol on the engine operating limit, heat release rate and exhaust emissions at different load conditions are investigated. The investigation also proves that the Hydrous Methanol with DME operation reduces the oxides of Nitrogen and smoke to an extreme low level which is not possible by the direct injection CI engine. Therefore, it is beneficial to use hydrous methanol-DME HCCI mode while using hydrous methanol in internal Combustion Engines.
Abstract: This study developed a high efficient and combined
biological and chemical filter treatment process. This process used
PAC (Powder Activated Carbon), Alum and attached growth
treatment process. The system removals of total nitrogen and total
phosphorus ratio of two were as high as 70% and 73%, moreover, the
effluent water was suitable to urban and agricultural water. Also the
advantages of this process are not only occupies small place but is
simple, economic and easy operating. Besides, our developed process
can keep stable process efficiency even in relative low load level.
Therefore, this study judges that use of the high efficient and
combined biological and chemical filter treatment process, it is
expected that the effluent water in this system can be reused as urban
and agricultural water.