Abstract: Polyaniline is an indispensible component in lightemitting
devices (LEDs), televisions, cellular telephones, automotive,
corrosion-resistant coatings, actuators etc. The electrical conductivity
properties was found be increased by introduction of metal nano
particles. In the present study, an attempt has been made to utilize
platinum nano particles to achieve the improved electrical properties.
Polyaniline and Pt-polyaniline composite are synthesized by
electrochemical routes. X-ray diffractometer confirms the amorphous
nature of polyaniline. The Bragg’s diffraction peaks correspond to
platinum nanoparticles in Pt-polyaniline composite and
thermogravimetric analyzer indicates its decomposition at certain
temperature. The Scanning Electron Micrographs of colloidal
platinum nanoparticles were spherical, uniform shape in the
composite. The current-voltage (I-V) characteristics of the PANI and
composites were also studied which indicate a significant decreasing
resistivity than PANI-Platinum after introduction of pt nanoparticles
in the matrix of polyaniline (PANI).
Abstract: This paper illustrates the effect of nano Magnesium
Hydroxide (MH) loading on the thermal properties of Low Density
Polyethylene (LDPE)/Poly (ethylene-co vinyl acetate) (EVA) nano
composite. Thermal studies were conducted, as it understanding is
vital for preliminary development of new polymeric systems.
Thermal analysis of nanocomposite was conducted using thermo
gravimetric analysis (TGA), and differential scanning calorimetry
(DSC). Major finding of TGA indicated two main stages of
degradation process found at (350 ± 25oC) and (480 ± 25oC)
respectively. Nano metal filler expressed better fire resistance as it
stand over high degree of temperature. Furthermore, DSC analysis
provided a stable glass temperature around 51 (±1oC) and captured
double melting point at 84 (±2oC) and 108 (±2oC). This binary
melting point reflects the modification of nano filler to the polymer
matrix forming melting crystals of folded and extended chain. The
percent crystallinity of the samples grew vividly with increasing filler
content. Overall, increasing the filler loading improved the
degradation temperature and weight loss evidently and a better
process and phase stability was captured in DSC.