Abstract: In this paper, we study the optical nonlinearities of
Silver sulfide (Ag2S) nanostructures dispersed in the Dimethyl
sulfoxide (DMSO) under exposure to 532 nm, 15 nanosecond (ns)
pulsed laser irradiation. Ultraviolet–visible absorption spectrometry
(UV-Vis), X-ray diffraction (XRD), and transmission electron
microscopy (TEM) are used to characterize the obtained nanocrystal
samples. The band gap energy of colloid is determined by analyzing
the UV–Vis absorption spectra of the Ag2S NPs using the band
theory of semiconductors. Z-scan technique is used to characterize
the optical nonlinear properties of the Ag2S nanoparticles (NPs).
Large enhancement of two photon absorption effect is observed with
increase in concentration of the Ag2S nanoparticles using open Zscan
measurements in the ns laser regime. The values of the nonlinear
absorption coefficients are determined based on the local nonlinear
responses including two photon absorption. The observed aperture
dependence of the Ag2S NP limiting performance indicates that the
nonlinear scattering plays an important role in the limiting action of
the sample. The concentration dependence of the optical liming is
also investigated. Our results demonstrate that the optical limiting
threshold decreases with increasing the silver sulfide NPs in DMSO.
Abstract: Lately, asynchronous discussion forum is integrated in
higher educational institutions as it may increase learning process,
learners’ understanding, achievement and knowledge construction.
The asynchronous discussion forum is used to complement the
traditional, face-to-face learning session in hybrid learning courses.
However, studies have proven that students’ engagement in online
forums is still unconvincing. Thus, the aim of this study is to
investigate the motivating factors and obstacles that affect the
learners’ engagement in asynchronous discussion forum. This study
is carried out in one of the public higher educational institutions in
Malaysia with 18 postgraduate students as samples. The authors have
developed a 40-items questionnaire based on literature review. The
results indicate several factors that have encouraged or limited
students’ engagement in asynchronous discussion forum: (a) the
practices or behaviors of peers, or instructors, (b) the needs for the
discussions, (c) the learners’ personalities, (d) constraints in
continuing the discussion forum, (e) lack of ideas, (f) the level of
thoughts, (g) the level of knowledge construction, (h) technical
problems, (i) time constraints and (j) misunderstanding. This study
suggests some recommendations to increase the students’
engagement in online forums. Finally, based upon the findings, some
implications are proposed for further research.