Abstract: In this study, the conversion of n-pentane to aromatics is investigated on HZSM-5 zeolites modified by Ga ion-exchange and silylation using tetraethyl orthosilicate (TEOS) via chemical liquid deposition (CLD). The effect of SiO2/Al2O3 ratios of HZSM-5 was also studied. Parameters in preparing catalysts i.e. TEOS loading and cycles of deposition were varied to obtain the optimal condition for enhancing p-xylene selectivity. The highest p-xylene selectivity 99.7% was achieved when the amount of TEOS was 20 vol.%.The catalysts were characterized by TPD, TPO, XRF, and BET. Results show that the conversion of n-pentane was influenced remarkably by the SiO2/Al2O3 ratios of HZSM-5. The highest p-xylene selectivity 99.7% was achieved when the amount of TEOS was 20 vol.%. And cycles of deposition greatly improves HZSM-5 shape-selectivity.
Abstract: This paper presents a comparative study of statistical methods for the multi-response surface optimization of a cryogenic freezing process. Taguchi design and analysis and steepest ascent methods based on the desirability function were conducted to ascertain the influential factors of a cryogenic freezing process and their optimal levels. The more preferable levels of the set point, exhaust fan speed, retention time and flow direction are set at -90oC, 20 Hz, 18 minutes and Counter Current, respectively. The overall desirability level is 0.7044.
Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.
Abstract: A piston cylinder based high pressure differential
thermal analyzer system is developed to investigate phase
transformations, melting, glass transitions, crystallization behavior of
inorganic materials, glassy systems etc., at ambient to 4 GPa and at
room temperature to 1073 K. The pressure is calibrated by the phase
transition of bismuth and ytterbium and temperature is calibrated
by using thermocouple data chart. The system developed is
calibrated using benzoic acid, ammonium nitrate and it has a
pressure and temperature control of ± 8.9 x 10 -4 GPa , ± 2 K
respectively. The phase transition of Asx Te100-x chalcogenides,
ferrous oxide and strontium boride are studied using the
indigenously developed system.
Abstract: This policy participation action research explores the
roles of Thai government units during its 2010 fiscal year on how to
create value added to recycling business in the central part of
Thailand. The research aims to a) study how the government plays a
role to support the business, and its problems and obstacles on
supporting the business, b) to design a strategic action – short,
medium, and long term plans -- to create value added to the recycling
business, particularly in local full-loop companies/organizations
licensed by Wongpanit Waste Separation Plant as well as those
licensed by the Department of Provincial Administration. Mixed
method research design, i.e., a combination of quantitative and
qualitative methods is utilized in the present study in both data
collection and analysis procedures. Quantitative data was analyzed
by frequency, percent value, mean scores, and standard deviation,
and aimed to note trend and generalizations. Qualitative data was
collected via semi-structured interviews/focus group interviews to
explore in-depth views of the operators. The sampling included 1,079
operators in eight provinces in the central part of Thailand.
Abstract: This paper presents the experimental results on
artificial ageing test of 22 kV XLPE cable for distribution system
application in Thailand. XLPE insulating material of 22 kV cable
was sliced to 60-70 μm in thick and was subjected to ac high voltage
at 23
Ôùª
C, 60
Ôùª
C and 75
Ôùª
C. Testing voltage was constantly applied to
the specimen until breakdown. Breakdown voltage and time to
breakdown were used to evaluate life time of insulating material.
Furthermore, the physical model by J. P. Crine for predicts life time
of XLPE insulating material was adopted as life time model and was
calculated in order to compare the experimental results. Acceptable
life time results were obtained from Crine-s model comparing with
the experimental result. In addition, fourier transform infrared
spectroscopy (FTIR) for chemical analysis and scanning electron
microscope (SEM) for physical analysis were conducted on tested
specimens.