Abstract: Zinc borates can be used as multi-functional
synergistic additives with flame retardant additives in polymers. Zinc
borate is white, non-hygroscopic and powder type product. The most
important properties are low solubility in water and high dehydration
temperature. Zinc borates dehydrate above 290°C and anhydrous zinc
borate has thermal resistance about 400°C. Zinc borates can be
synthesized using several methods such as hydrothermal and solidstate
processes. In this study, the solid-state method was applied at
low temperatures of 600oC and 700oC using the starting materials of
ZnO and H3BO3 with several mole ratios. The reaction time was
determined as 4 hours after some preliminary experiments. After the
synthesis, the crystal structure and the morphology of the products
were examined by X-Ray Diffraction (XRD) and Fourier Transform
Infrared Spectroscopy (FT-IR). As a result the forms of ZnB4O7,
Zn3(BO3)2, ZnB2O4 were synthesized and obtained along with the
unreacted ZnO.
Abstract: A new chelating resin is prepared by coupling
Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer.
The resulting sorbent has been characterized by FT-IR, elemental
analysis and thermogravimetric analysis (TGA) and studied for
preconcentrating of Cu (II) using flame atomic absorption
spectrometry (FAAS) for metal monitoring. The optimum pH value
for sorption of the copper ions was 6.5. The resin was subjected to
evaluation through batch binding of mentioned metal ion.
Quantitative desorption occurs instantaneously with 0.5 M HNO3.
The sorption capacity was found 4.8 mmol.g-1 of resin for Cu (II) in
the aqueous solution. The chelating resin can be reused for 10 cycles
of sorption-desorption without any significant change in sorption
capacity. A recovery of 99% was obtained the metal ions with 0.5 M
HNO3 as eluting agent. The method was applied for metal ions
determination from industrial waste water sample.
Abstract: In this study, we report the synthesis and
characterization of nanohydroxyapatite (nHAp) in gelatin-starch
matrix via biomimetic method. Characterization of the samples was
performed using X-ray diffraction (XRD) and Fourier Transform
infrared spectroscopy (FT-IR). The Size and morphology of the
nHAp samples were determined using scanning and transmission
electron microscopy (SEM and TEM). The results reveal that the
shape and morphology of nHAp is influenced by presence of
biopolymers as template. Carbonyl and amino groups from gelatin
and hydroxyl from starch play crucial roles in HAp formation on the
surface of gelatin-starch.
Abstract: Nano MgO has been synthesized by hydration and
dehydration method by modifies the commercial MgO. The prepared
MgO had been investigated as a heterogeneous base catalyst for
transesterification process for biodiesel production using palm oil.
TGA, FT-IR and XRD results obtained from this study lie each other
and proved in the formation of nano MgO from decomposition of
Mg(OH)2. This study proved that the prepared nano MgO was a
better base transesterification catalyst compared to commercial MgO.
The nano MgO calcined at 600ºC had gives the highest conversion of
51.3% of palm oil to biodiesel.
Abstract: Five lignin samples were fractionated with
Acetone/Water mixtures and the obtained fractions were subjected to
extensive structural characterization, including Fourier Transform
Infrared (FT-IR), Gel permeation Chromatography (GPC) and
Phosphorus-31 NMR spectroscopy (31P-NMR). The results showed
that for all studied lignins the solubility increases with the increment
of the acetone concentration. Wheat straw lignin has the highest
solubility in 90/10 (v/v) Acetone/Water mixture, 400 mg lignin being
dissolved in 1 mL mixture. The weight average molecular weight of
the obtained fractions increased with the increment of acetone
concentration and thus with solubility. 31P-NMR analysis based on
lignin modification by reactive phospholane into phosphitylated
compounds was used to differentiate and quantify the different types
of OH groups (aromatic, aliphatic, and carboxylic) found in the
fractions obtained with 70/30 (v/v) Acetone/Water mixture.
Abstract: The consumption of lactose in acid cheese whey
anaerobic fermentation process under fed-batch conditions was
studied. During fermentation for 100 hours the biogas production
(CO2 and CH4) was analyzed online. Among the standard analyses
FT-IR spectroscopy was used to follow the consumption of lactose by
bacteria. The absorption bands at 990, 894 and 787 cm-1 in the 2nd
derivative spectra were shown to be characteristic for lactose and
were used to follow the lactose conversion. It was shown that acid
cheese whey lactose was converted by bacteria in first 7 hours. In the
spectra of 17, 18 and 95 hour fermentation samples lactose was not
identified and these results correlated with the HPLC data.
Abstract: Levan, an exopolysaccharide, was produced by
Microbacterium laevaniformans and its yield was characterized as a
function of concentrations of date syrup, sucrose and the fermentation
time. The optimum condition for levan production from sucrose was
at concentration of 20% sucrose for 48 h and for date syrup was 25%
for 48 h. The results show that an increase in fermentation time
caused a decrease in the levan production at all concentrations of date
syrup tested. Under these conditions after 48 h in sucrose medium,
levan production reached 48.9 g/L and for date syrup reached 10.48
g/L . The effect of pH on the yield of the purified levan was examined
and the optimum pH for levan production was determined to be 6.0.
Levan was composed mainly of fructose residues when analyzed by
TLC and FT-IR spectroscopy. Date syrup is a cheap substrate widely
available in Iran and has potential for levan production. The thermal
stability of levan was assessed by Thermo Gravimetric Analysis
(TGA) that revealed the onset of decomposition near to 49°C for the
levan produced from sucrose and 51°C for the levan from date syrup.
DSC results showed a single Tg at 98°C for levan produced from
sucrose and 206 °C for levan from date syrup.
Abstract: Magnesium wastes and scraps, one of the metal wastes, are produced by many industrial activities, all over the world. Their growing size is becoming a future problem for the world. In this study, the use of magnesium wastes as a raw material in the production of the magnesium borate hydrates are aimed. The method used in the experiments is hydrothermal synthesis. The conditions are set to, waste magnesium to B2O3, 1:3 as a molar ratio. Four different reaction times are studied which are 30, 60, 120 and 240 minutes. For the identification analyses X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and Raman spectroscopy techniques are used. As a result at all the reaction times magnesium borate hydrates are synthesized and the most crystalline forms are obtained at a reaction time of 120 minutes. The overall yields of the production are found between the values of 65-80 %.
Abstract: One of the important factors of cracks on the asphalt
pavements is bitumen aging that associated with the loss of volatile
components and oxidation of asphalt binder. This paper is about
effect of Styrene-Butadiene-Styrene (SBS) polymer on asphalt aging
In order to decrease asphalt aging effects. For this purpose samples of
base bitumen and SBS modified bitumen aged according to the
rolling thin film oven test (RTFOT) and pressure aging vessel (PAV),
respectively. Properties of each sample were evaluated using Fourier
Transform Infrared (FTIR) spectroscopy, n-heptane precipitation,
viscosity test, softening point test and penetration test. FT-IR
Analysis, showed lower oxidation of SBS modified bitumen than
base bitumen, after aging.
Abstract: The leaching behavior and structure of Li2O-CeO2- Fe2O3-P2O5 glasses incorporated with simulated high level nuclear wastes (HLW) were studied. The leach rates of gross and each constituent element were determined from the total weight loss of the specimen and the leachate analyses by inductively coupled argon plasma spectroscopy (ICP). The gross leach rate of the 4.5Li2O- 9.7CeO2-34.7Fe2O3-51.5P2O5 glass waste form containing 45 mass% simulated HLW is of the order of 10
Abstract: To reduce the carbon dioxide emission into the
atmosphere, adsorption is believed to be one of the most attractive
methods for post-combustion treatment of flue gas. In this work,
activated carbon (AC) was modified by polyethylenimine (PEI) via
impregnation in order to enhance CO2 adsorption capacity. The
adsorbents were produced at 0.04, 0.16, 0.22, 0.25, and 0.28 wt%
PEI/AC. The adsorption was carried out at a temperature range from
30 °C to 75 °C and five different gas pressures up to 1 atm. TG-DTA,
FT-IR, UV-visible spectrometer, and BET were used to characterize
the adsorbents. Effects of PEI loading on the AC for the CO2
adsorption were investigated. Effectiveness of the adsorbents on the
CO2 adsorption including CO2 adsorption capacity and adsorption
temperature was also investigated. Adsorption capacities of CO2 were
enhanced with the increase in the amount of PEI from 0.04 to 0.22
wt% PEI before the capacities decreased onwards from0.25 wt% PEI
at 30 °C. The 0.22 wt% PEI/AC showed higher adsorption capacity
than the AC for adsorption at 50 °C to 75 °C.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.
Abstract: Fourier transform infrared (FT-IR) spectroscopic imaging
is an emerging technique that provides both chemically and
spatially resolved information. The rich chemical content of data
may be utilized for computer-aided determinations of structure and
pathologic state (cancer diagnosis) in histological tissue sections for
prostate cancer. FT-IR spectroscopic imaging of prostate tissue has
shown that tissue type (histological) classification can be performed to
a high degree of accuracy [1] and cancer diagnosis can be performed
with an accuracy of about 80% [2] on a microscopic (≈ 6μm)
length scale. In performing these analyses, it has been observed
that there is large variability (more than 60%) between spectra from
different points on tissue that is expected to consist of the same
essential chemical constituents. Spectra at the edges of tissues are
characteristically and consistently different from chemically similar
tissue in the middle of the same sample. Here, we explain these
differences using a rigorous electromagnetic model for light-sample
interaction. Spectra from FT-IR spectroscopic imaging of chemically
heterogeneous samples are different from bulk spectra of individual
chemical constituents of the sample. This is because spectra not
only depend on chemistry, but also on the shape of the sample.
Using coupled wave analysis, we characterize and quantify the nature
of spectral distortions at the edges of tissues. Furthermore, we
present a method of performing histological classification of tissue
samples. Since the mid-infrared spectrum is typically assumed to
be a quantitative measure of chemical composition, classification
results can vary widely due to spectral distortions. However, we
demonstrate that the selection of localized metrics based on chemical
information can make our data robust to the spectral distortions
caused by scattering at the tissue boundary.
Abstract: A new chelating resin is prepared by coupling Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer. The resulting sorbent has been characterized by FT-IR, elemental analysis and thermogravimetric analysis (TGA) and studied for preconcentrating of Fe (II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the iron ions was 6.5. The resin was subjected to evaluation through batch binding of mentioned metal ion. Quantitative desorption occurs instantaneously with 0.5 M HNO3. The sorption capacity was found 4.1 mmol.g-1 of resin for Fe (II) in the aqueous solution. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 97% was obtained the metal ions with 0.5 M HNO3 as eluting agent. The method was applied for metal ions determination from industrial waste water sample.
Abstract: In this investigation, types of commercial and special
polyacrylonitrile (PAN) fibers contain sodium 2-methyl-2-
acrylamidopropane sulfonate (SAMPS) and itaconic acid (IA)
comonomers were studied by fourier transform infrared (FT-IR)
spectroscopy. The study of FT-IR spectra of PAN fibers samples
with different comonomers shows that during stabilization of PAN
fibers, the peaks related to C≡N bonds and CH2 are reduced sharply.
These reductions are related to cyclization of nitrile groups and
stabilization procedure. This reduction in PAN fibers contain IA
comonomer is very intense in comparison with PAN fibers contain
SAMPS comonomer. This fact indicates the cycling and stabilization
for sample contain IA comonomer have been conducted more
completely. Therefore the carbon fibers produced from this material
have higher tensile strength due to suitable stabilization.
Abstract: A concrete structure is designed and constructed for its
purpose of use, and is expected to maintain its function for the target
durable years from when it was planned. Nevertheless, as time elapses
the structure gradually deteriorates and then eventually degrades to the
point where the structure cannot exert the function for which it was
planned. The performance of concrete that is able to maintain the level
of the performance required over the designed period of use as it has
less deterioration caused by the elapse of time under the designed
condition is referred to as Durability. There are a number of causes of
durability degradation, but especially chloride damage, carbonation,
freeze-thaw, etc are the main causes. In this study, carbonation, one of
the main causes of deterioration of the durability of a concrete
structure, was investigated via a microstructure analysis technique.
The method for the measurement of carbonation was studied using the
existing indicator method, and the method of measuring the progress
of carbonation in a quantitative manner was simultaneously studied
using a FT-IR (Fourier-Transform Infrared) Spectrometer along with
the microstructure analysis technique.