Abstract: The removal of hydrogen sulphide is required for reasons of health, odour problems, safety and corrosivity problems. The means of removing hydrogen sulphide mainly depend on its concentration and kind of medium to be purified. The paper deals with a method of hydrogen sulphide removal from the air by its catalytic oxidation to elemental sulphur with the use of Fe-EDTA complex. The possibility of obtaining fibrous filtering materials able to remove small concentrations of H2S from the air were described. The base of these materials is fibrous ion exchanger with Fe(III)- EDTA complex immobilized on their functional groups. The complex of trivalent iron converts hydrogen sulphide to elemental sulphur. Bivalent iron formed in the reaction is oxidized by the atmospheric oxygen, so complex of trivalent iron is continuously regenerated and the overall process can be accounted as pseudocatalytic. In the present paper properties of several fibrous catalysts based on ion exchangers with different chemical nature (weak acid,weak base and strong base) were described. It was shown that the main parameters affecting the process of catalytic oxidation are:concentration of hydrogen sulphide in the air, relative humidity of the purified air, the process time and the content of Fe-EDTA complex in the fibres. The data presented show that the filtering layers with anion exchange package are much more active in the catalytic processes of hydrogen sulphide removal than cation exchanger and inert materials. In the addition to the nature of the fibres relative air humidity is a critical factor determining efficiency of the material in the air purification from H2S. It was proved that the most promising carrier of the Fe-EDTA catalyst for hydrogen sulphide oxidation are Fiban A-6 and Fiban AK-22 fibres.
Abstract: In the present study Schwertmannite (an iron oxide
hydroxide) is selected as an adsorbent for defluoridation of water.
The adsorbent was prepared by wet chemical process and was
characterized by SEM, XRD and BET. The fluoride adsorption
efficiency of the prepared adsorbent was determined with respect to
contact time, initial fluoride concentration, adsorbent dose and pH of
the solution. The batch adsorption data revealed that the fluoride
adsorption efficiency was highly influenced by the studied factors.
Equilibrium was attained within one hour of contact time indicating
fast kinetics and the adsorption data followed pseudo second order
kinetic model. Equilibrium isotherm data fitted to both Langmuir and
Freundlich isotherm models for a concentration range of 5-30 mg/L.
The adsorption system followed Langmuir isotherm model with
maximum adsorption capacity of 11.3 mg/g. The high adsorption
capacity of Schwertmannite points towards the potential of this
adsorbent for fluoride removal from aqueous medium.
Abstract: Injection forging is a Nett-shape manufacturing
process in which one or two punches move axially causing a radial
flow into a die cavity in a form which is prescribed by the exitgeometry,
such as pulley, flanges, gears and splines on a shaft. This
paper presents an experimental and numerical study of the injection
forging of splines in terms of load requirement and material flow.
Three dimensional finite element analyses are used to investigate the
effect of some important parameters in this process. The experiment
has been carried out using solid commercial lead billets with two
different billet diameters and four different dies.
Abstract: Excilamps are new UV sources with great potential
for application in wastewater treatment. In the present work, a XeBr
excilamp emitting radiation at 283 nm has been used for the
photodegradation of 4-chlorophenol within a range of concentrations
from 50 to 500 mg L-1. Total removal of 4-chlorophenol was
achieved for all concentrations assayed. The two main photoproduct
intermediates formed along the photodegradation process,
benzoquinone and hydroquinone, although not being completely
removed, remain at very low residual concentrations. Such
concentrations are insignificant compared to the 4-chlorophenol
initial ones and non-toxic. In order to simulate the process and scaleup,
a kinetic model has been developed and validated from the
experimental data.
Abstract: The flow field and the motion of the free surface in an
oscillating container are simulated numerically to assess the numerical
approach for studying two-phase flows under oscillating conditions.
Two numerical methods are compared: one is to model the oscillating
container directly using the moving grid of the ALE method, and the
other is to simulate the effect of container motion using the oscillating
body force acting on the fluid in the stationary container. The
two-phase flow field in the container is simulated using the level set
method in both cases. It is found that the calculated results by the body
force method coinsides with those by the moving grid method and the
sloshing behavior is predicted well by both the methods. Theoretical
back ground and limitation of the body force method are discussed,
and the effects of oscillation amplitude and frequency are shown.
Abstract: The essentiality of maintenance assessment and
maintenance optimization in design stage is analyzed, and the existent
problems of conventional maintenance design method are illuminated.
MDMVM (Maintenance Design Method based Virtual Maintenance)
is illuminated, and the process of MDMVM established, and the
MDMVM architecture is given out. The key techniques of MDMVM
are analyzed, and include maintenance design based KBE (Knowledge
Based Engineering) and virtual maintenance based physically
attribute. According to physical property, physically based modeling,
visual object movement control, the simulation of operation force and
maintenance sequence planning method are emphatically illuminated.
Maintenance design system based virtual maintenance is established in
foundation of maintenance design method.
Abstract: Cooperative organizations in Malaysia are going
through a phase of rapid growth. They are seen by the government as
another crucial vehicle to drive and boost up the country-s
economical development and growth. Hence, the issue of cooperative
governance is of great importance. Unlike literatures on corporate
governance for public listed companies-, literatures on governance
for social enterprises, in particular the cooperative organizations are
still at the early stage in Malaysia and very scant in number. This
paper will look into current practices as well as issues and challenges
related to cooperative governance. The need for a better solution
towards forming best practices of cooperative governance framework
appears imperative in deterring cases of mismanagement and fraud.
Abstract: A numbers of important developments have led to an
increasing attractiveness for very high speed electrical machines
(either motor or generator). Specifically the increasing switching
speed of power electronics, high energy magnets, high strength
retaining materials, better high speed bearings and improvements in
design analysis are the primary drivers in a move to higher speed. The
design challenges come in the mechanical design both in terms of
strength and resonant modes and in the electromagnetic design
particularly in respect of iron losses and ac losses in the various
conducting parts including the rotor. This paper describes detailed
design work which has been done on a 50,000 rpm, 50kW permanent
magnet( PM) synchronous machine. It describes work on
electromagnetic and rotor eddy current losses using a variety of
methods including both 2D finite element analysis
Abstract: Turbulence studies were made in the wake of a rotating
circular cylinder in a uniform free stream. The interest was to
examine the turbulence properties at the suppression of periodicity in
vortex formation process. An experimental study of the turbulent near
wake of a rotating circular cylinder was made at a Reynolds number
of 9000 for velocity ratios, λ between 0 and 2.7. Hot-wire
anemometry and particle image velocimetry results indicate that the
rotation of the cylinder causes significant changes in the vortical
activities. The turbulence quantities are getting smaller as λ increases
due to suppression of coherent vortex structures.
Abstract: The mesoporous MoO3/γ-Al2O3 catalyst was prepared
by incipient wetness impregnation method aiming to investigate the
effect of drying method and molybdenum content on the catalyst
property and performance towards the oxidation of benzothiophene
(BT), dibenzothiophene (DBT) and 4,6-dimethyle dibenzothiophene
(4,6-DMDBT) with H2O2 for deep oxidative desulfurization of diesel
fuel. The catalyst was characterized by XRD, BET, BJH and SEM
method. The catalyst with 10wt.% and 15wt.% Mo content represent
same optimum performance for DBT and 4,6-DMDBT removal, but
a catalyst with 10wt.% Mo has higher efficiency than 15wt.% Mo for
BT conversion. The SEM images show that use of rotary evaporator
in drying step reaches a more homogenous impregnation. The
oxidation reactivity of different sulfur compounds was studied which
followed the order of DBT>4,6-DMDBT>>BT.
Abstract: Post cracking behavior and load –bearing capacity of
the steel fiber reinforced high-strength concrete (SFRHSC) are
dependent on the number of fibers are crossing the weakest crack
(bridged the crack) and their orientation to the crack surface. Filling
the mould by SFRHSC, fibers are moving and rotating with the
concrete matrix flow till the motion stops in each internal point of the
concrete body. Filling the same mould from the different ends
SFRHSC samples with the different internal structures (and different
strength) can be obtained. Numerical flow simulations (using Newton
and Bingham flow models) were realized, as well as single fiber
planar motion and rotation numerical and experimental investigation
(in viscous flow) was performed. X-ray pictures for prismatic
samples were obtained and internal fiber positions and orientations
were analyzed. Similarly fiber positions and orientations in cracked
cross-section were recognized and were compared with numerically
simulated. Structural SFRHSC fracture model was created based on
single fiber pull-out laws, which were determined experimentally.
Model predictions were validated by 15x15x60cm prisms 4 point
bending tests.
Abstract: Electrochemical-oxidation of Reactive Black-5 (RB- 5) was conducted for degradation using DSA type Ti/RuO2-SnO2- Sb2O5 electrode. In the study, for electro-oxidation, electrode was indigenously fabricated in laboratory using titanium as substrate. This substrate was coated using different metal oxides RuO2, Sb2O5 and SnO2 by thermal decomposition method. Laboratory scale batch reactor was used for degradation and decolorization studies at pH 2, 7 and 11. Current density (50mA/cm2) and distance between electrodes (8mm) were kept constant for all experiments. Under identical conditions, removal of color, COD and TOC at initial pH 2 was 99.40%, 55% and 37% respectively for initial concentration of 100 mg/L RB-5. Surface morphology and composition of the fabricated electrode coatings were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) respectively. Coating microstructure was analyzed by X-ray diffraction (XRD). Results of this study further revealed that almost 90% of oxidation occurred within 5-10 minutes.
Abstract: This paper proposes a way to track persons by making use of multiple non-overlapping cameras. Tracking persons on multiple non-overlapping cameras enables data communication among cameras through the network connection between a camera and a computer, while at the same time transferring human feature data captured by a camera to another camera that is connected via the network. To track persons with a camera and send the tracking data to another camera, the proposed system uses a hierarchical human model that comprises a head, a torso, and legs. The feature data of the person being modeled are transferred to the server, after which the server sends the feature data of the human model to the cameras connected over the network. This enables a camera that captures a person's movement entering its vision to keep tracking the recognized person with the use of the feature data transferred from the server.
Abstract: Design of Converter transformer insulation is a major
challenge. The insulation of these transformers is stressed by both
AC and DC voltages. Particle contamination is one of the major
problems in insulation structures, as they generate partial discharges
leading it to major failure of insulation. Similarly corona discharges
occur in transformer insulation. This partial discharge due to particle
movement / corona formation in insulation structure under different
voltage wave shapes, are different. In the present study, UHF
technique is adopted to understand the discharge activity and could
be realized that the characteristics of UHF signal generated under
low and high fields are different. In the case of corona generated
signal, the frequency content of the UHF sensor output lies in the
range 0.3-1.2 GHz and is not much varied except for its increase in
magnitude of discharge with the increase in applied voltage. It is
realized that the current signal injected due to partial
discharges/corona is about 4ns duration measured for first one half
cycle. Wavelet technique is adopted in the present study. It allows
one to identify the frequency content present in the signal at different
instant of time. The STD-MRA analysis helps one to identify the
frequency band in which the energy content of the UHF signal is
maximum.
Abstract: Carbon dioxide capture process has been simulated
and studied under different process conditions. It has been shown
that several process parameters such as lean amine temperature,
number of adsorber stages, number of stripper stages and stripper
pressure affect different process conditions and outputs such as
carbon dioxide removal and reboiler duty. It may be concluded that
the simulation of carbon dioxide capture process can help to estimate
the best process conditions.
Abstract: The performance of modified Fenton (MF) treatment
to promote PAH oxidation in artificially contaminated soil was
investigated in packed soil column with a hydrogen peroxide (H2O2)
delivery system simulating in situ injection. Soil samples were spiked
with phenanthrene (low molecular weight PAH) and fluoranthene
(high molecular weight PAH) to an initial concentration of 500
mg/kg dried soil each. The effectiveness of process parameters
H2O2/soil, iron/soil, chelating agent/soil weight ratios and reaction
time were studied using a 24 three level factorial design experiments.
Statistically significant quadratic models were developed using
Response Surface Methodology (RSM) for degrading PAHs from the
soil samples. Optimum operating condition was achieved at mild
range of H2O2/soil, iron/soil and chelating agent/soil weight ratios,
indicating cost efficient method for treating highly contaminated
lands.
Abstract: The objective of this study is to evaluate the threshold
stress of the clay with sand subgrade soil. Threshold stress can be
defined as the stress level above which cyclic loading leads to
excessive deformation and eventual failure. The thickness
determination of highways formations using the threshold stress
approach is a more realistic assessment of the soil behaviour because
it is subjected to repeated loadings from moving vehicles. Threshold
stress can be evaluated by plastic strain criterion, which is based on
the accumulated plastic strain behaviour during cyclic loadings [1].
Several conditions of the all-round pressure the subgrade soil namely,
zero confinement, low all-round pressure and high all-round pressure
are investigated. The threshold stresses of various soil conditions are
determined. Threshold stress of the soil are 60%, 31% and 38.6% for
unconfined partially saturated sample, low effective stress saturated
sample, high effective stress saturated sample respectively.
Abstract: The requirement to improve software productivity has
promoted the research on software metric technology. There are
metrics for identifying the quality of reusable components but the
function that makes use of these metrics to find reusability of
software components is still not clear. These metrics if identified in
the design phase or even in the coding phase can help us to reduce the
rework by improving quality of reuse of the component and hence
improve the productivity due to probabilistic increase in the reuse
level. CK metric suit is most widely used metrics for the objectoriented
(OO) software; we critically analyzed the CK metrics, tried
to remove the inconsistencies and devised the framework of metrics
to obtain the structural analysis of OO-based software components.
Neural network can learn new relationships with new input data and
can be used to refine fuzzy rules to create fuzzy adaptive system.
Hence, Neuro-fuzzy inference engine can be used to evaluate the
reusability of OO-based component using its structural attributes as
inputs. In this paper, an algorithm has been proposed in which the
inputs can be given to Neuro-fuzzy system in form of tuned WMC,
DIT, NOC, CBO , LCOM values of the OO software component and
output can be obtained in terms of reusability. The developed
reusability model has produced high precision results as expected by
the human experts.
Abstract: The present study examines the adsorption of phenol, 3-nitrophenol and dyes (methylene blue, alizarine yellow), from aqueous solutions onto a commercial activated carbon. Two different operations, semi-batch and continuous with reflux, were applied. The commercial activated carbon exhibits high adsorption abilities for phenol, 3-nitrophenol and dyes (methylene blue and alizarin yellow) from their aqueous solutions. The adsorption of all adsorbates after 1 h is higher by the continuous operation with reflux than by the semibatch operation. The adsorption of phenol is higher than that of 3-nitrophenol for both operations. Similarly, the adsorption of alizarin yellow is higher than that of methylene blue for both operations. The regenerated commercial activated carbon regains its adsorption ability due to the removal of the adsorbate from its pores during the regeneration.
Abstract: A horizontal anaerobic digester was developed and
tested in pilot scale for Korean food waste with high water contents
(>80%). The hydrogen sulfide in the biogas was removed by a
biological desulfurization equipment integrated in the horizontal
digester. A mixer of the horizontal digester was designed to easily
remove the sediment in the bottom and scum layers on surface in the
digester. Experimental result for 120 days of operation of the pilot
plant showed a high removal efficiency of 81.2% for organic
substance and high stability during the whole operation period were
acquired. Also food waste was treated at high organic loading rates
over 4 kg•VS/m3∙day and a methane gas production rate of 0.62
m3/kg•VSremoved was accomplished.
The biological desulfurization equipment inside the horizontal
digester was proven to be an economic and effective method to reduce
the biogas desulfurization cost by removing hydrogen sulfide more
than 90% without external desulfurization equipments.