Abstract: The Kinetics formation of labile Complex
Ag (I) tetra (p-carboxyphenyl) porphyrin, was investigated at 25oC
and I=0.1M (NaNO3). By spectrophotometric titration, the
composition ratio of the complex was established to be 2:1
(Ag : H2TCPP). The equilibrium constant, K, was found to be
log 10-6.53. Binding of the first Ag (I) was found to be rate
determining step with rate constant, k1= 4.67×102 . A plausible
mechanism is discussed. We discus theoretically why Ag(I)2TCPP is
unstable.
Abstract: Wireless sensor networks (WSN) are currently
receiving significant attention due to their unlimited potential. These
networks are used for various applications, such as habitat
monitoring, automation, agriculture, and security. The efficient nodeenergy
utilization is one of important performance factors in wireless
sensor networks because sensor nodes operate with limited battery
power. In this paper, we proposed the MiSense hierarchical cluster
based routing algorithm (MiCRA) to extend the lifetime of sensor
networks and to maintain a balanced energy consumption of nodes.
MiCRA is an extension of the HEED algorithm with two levels of
cluster heads. The performance of the proposed protocol has been
examined and evaluated through a simulation study. The simulation
results clearly show that MiCRA has a better performance in terms of
lifetime than HEED. Indeed, MiCRA our proposed protocol can
effectively extend the network lifetime without other critical
overheads and performance degradation. It has been noted that there
is about 35% of energy saving for MiCRA during the clustering
process and 65% energy savings during the routing process compared
to the HEED algorithm.
Abstract: Synthesis gas manufacturing by steam reforming of hydrocarbons is an important industrial process. High endothermic nature of the process makes it one of the most cost and heat intensive processes. In the present work, composite effect of different inert gases on synthesis gas yield, feed gas conversion and temperature distribution along the reactor length has been studied using a heterogeneous model. Mathematical model was developed as a first stage and validated against the existing process models. With the addition of inert gases, a higher yield of synthesis gas is observed. Simultaneously the rector outlet temperature drops to as low as 810 K. It was found that Xenon gives the highest yield and conversion while Helium gives the lowest temperature. Using Xenon inert gas 20 percent reduction in outlet temperature was observed compared to traditional case.
Abstract: This paper presents two simplified models to
determine nodal voltages in power distribution networks. These
models allow estimating the impact of the installation of reactive
power compensations equipments like fixed or switched capacitor
banks. The procedure used to develop the models is similar to the
procedure used to develop linear power flow models of transmission
lines, which have been widely used in optimization problems of
operation planning and system expansion. The steady state non-linear
load flow equations are approximated by linear equations relating the
voltage amplitude and currents. The approximations of the linear
equations are based on the high relationship between line resistance
and line reactance (ratio R/X), which is valid for power distribution
networks. The performance and accuracy of the models are evaluated
through comparisons with the exact results obtained from the
solution of the load flow using two test networks: a hypothetical
network with 23 nodes and a real network with 217 nodes.
Abstract: In some real applications of Statistical Process Control
it is necessary to design a control chart to not detect small process
shifts, but keeping a good performance to detect moderate and large
shifts in the quality. In this work we develop a new quality control
chart, the synthetic T2 control chart, that can be designed to cope with
this objective. A multi-objective optimization is carried out employing
Genetic Algorithms, finding the Pareto-optimal front of
non-dominated solutions for this optimization problem.
Abstract: Arms detection is one of the fundamental problems in
human motion analysis application. The arms are considered as the
most challenging body part to be detected since its pose and speed
varies in image sequences. Moreover, the arms are usually occluded
with other body parts such as the head and torso. In this paper,
histogram-based skin colour segmentation is proposed to detect the
arms in image sequences. Six different colour spaces namely RGB,
rgb, HSI, TSL, SCT and CIELAB are evaluated to determine the best
colour space for this segmentation procedure. The evaluation is
divided into three categories, which are single colour component,
colour without luminance and colour with luminance. The
performance is measured using True Positive (TP) and True Negative
(TN) on 250 images with manual ground truth. The best colour is
selected based on the highest TN value followed by the highest TP
value.
Abstract: Fly ash is a significant waste that is released of
thermal power plants and defined as very fine particles that are drifted upward with up taken by the flue gases due to the burning of
used coal [1]. The fly-ash is capable of removing organic
contaminants in consequence of high carbon content, a large surface area per unit volume and contained heavy metals. Therefore, fly ash
is used as an effective coagulant and adsorbent by pelletization [2, 3].
In this study, the possibility of use of fly ash taken from Turkey like low-cost adsorbent for adsorption of zinc ions found in waste
water was investigated. The fly ash taken from Turkey was pelletized with bentonite and molass to evaluate the adsorption capaticity. For
this purpose; analyses such as sieve analysis, XRD, XRF, FTIR and SEM were performed. As a result, it was seen that pellets prepared
from fly ash, bentonite and molass would be used for zinc adsorption.
Abstract: This research was conducted for the first time at the
southeastern coasts of the Caspian Sea in order to evaluate the
performance of osteichthyes cooperatives through production (catch)
function. Using one of the indirect valuation methods in this research,
contributory factors in catch were identified and were inserted into
the function as independent variables. In order to carry out this
research, the performance of 25 Osteichthyes catching cooperatives
in the utilization year of 2009 which were involved in fishing in
Miankale wildlife refuge region. The contributory factors in catch
were divided into groups of economic, ecological and biological
factors. In the mentioned function, catch rate of the cooperative were
inserted into as the dependant variable and fourteen partial variables
in terms of nine general variables as independent variables. Finally,
after function estimation, seven variables were rendered significant at
99 percent reliably level. The results of the function estimation
indicated that human resource (fisherman quantity) had the greatest
positive effect on catch rate with an influence coefficient of 1.7 while
weather conditions had the greatest negative effect on the catch rate
of cooperatives with an influence coefficient of -2.07. Moreover,
factors like member's share, experience and fisherman training and
fishing effort played the main roles in the catch rate of cooperative
with influence coefficients of 0.81, 0.5 and 0.21, respectively.
Abstract: Choosing the right metadata is a critical, as good
information (metadata) attached to an image will facilitate its
visibility from a pile of other images. The image-s value is enhanced
not only by the quality of attached metadata but also by the technique
of the search. This study proposes a technique that is simple but
efficient to predict a single human image from a website using the
basic image data and the embedded metadata of the image-s content
appearing on web pages. The result is very encouraging with the
prediction accuracy of 95%. This technique may become a great
assist to librarians, researchers and many others for automatically and
efficiently identifying a set of human images out of a greater set of
images.
Abstract: In-core memory requirement is a bottleneck in solving
large three dimensional Navier-Stokes finite element problem
formulations using sparse direct solvers. Out-of-core solution
strategy is a viable alternative to reduce the in-core memory
requirements while solving large scale problems. This study
evaluates the performance of various out-of-core sequential solvers
based on multifrontal or supernodal techniques in the context of
finite element formulations for three dimensional problems on a
Windows platform. Here three different solvers, HSL_MA78,
MUMPS and PARDISO are compared. The performance of these
solvers is evaluated on a 64-bit machine with 16GB RAM for finite
element formulation of flow through a rectangular channel. It is
observed that using out-of-core PARDISO solver, relatively large
problems can be solved. The implementation of Newton and
modified Newton's iteration is also discussed.
Abstract: The research objective of the project and article
“European Ecological Network Natura 2000 – opportunities and
threats” Natura 2000 sites constitute a form of environmental
protection, several legal problems are likely to result. Most
controversially, certain sites will be subject to two regimes of
protection: as national parks and as Natura 2000 sites. This dualism
of the legal regulation makes it difficult to perform certain legal
obligations related to the regimes envisaged under each form of
environmental protection. Which regime and which obligations
resulting from the particular form of environmental protection have
priority and should prevail? What should be done if these obligations
are contradictory? Furthermore, an institutional problem consists in
that no public administration authority has the power to resolve legal
conflicts concerning the application of a particular regime on a given
site. There are also no criteria to decide priority and superiority of
one form of environmental protection over the other. Which
regulations are more important, those that pertain to national parks or
to Natura 2000 sites? In the light of the current regulations, it is
impossible to give a decisive answer to these questions. The internal
hierarchy of forms of environmental protection has not been
determined, and all such forms should be treated equally.
Abstract: Background: Dialign is a DNA/Protein alignment tool
for performing pairwise and multiple pairwise alignments through the
comparison of gap-free segments (fragments) between sequence
pairs. An alignment of two sequences is a chain of fragments, i.e
local gap-free pairwise alignments, with the highest total score.
METHOD: A new approach is defined in this article which relies on
the concept of using three-dimensional fragments – i.e. local threeway
alignments -- in the alignment process instead of twodimensional
ones. These three-dimensional fragments are gap-free
alignments constituting of equal-length segments belonging to three
distinct sequences. RESULTS: The obtained results showed good
improvments over the performance of DIALIGN.
Abstract: High speed networks provide realtime variable bit rate
service with diversified traffic flow characteristics and quality
requirements. The variable bit rate traffic has stringent delay and
packet loss requirements. The burstiness of the correlated traffic
makes dynamic buffer management highly desirable to satisfy the
Quality of Service (QoS) requirements. This paper presents an
algorithm for optimization of adaptive buffer allocation scheme for
traffic based on loss of consecutive packets in data-stream and buffer
occupancy level. Buffer is designed to allow the input traffic to be
partitioned into different priority classes and based on the input
traffic behavior it controls the threshold dynamically. This algorithm
allows input packets to enter into buffer if its occupancy level is less
than the threshold value for priority of that packet. The threshold is
dynamically varied in runtime based on packet loss behavior. The
simulation is run for two priority classes of the input traffic –
realtime and non-realtime classes. The simulation results show that
Adaptive Partial Buffer Sharing (ADPBS) has better performance
than Static Partial Buffer Sharing (SPBS) and First In First Out
(FIFO) queue under the same traffic conditions.
Abstract: In this paper, we propose a Perceptually Optimized Foveation based Embedded ZeroTree Image Coder (POEFIC) that introduces a perceptual weighting to wavelet coefficients prior to control SPIHT encoding algorithm in order to reach a targeted bit rate with a perceptual quality improvement with respect to a given bit rate a fixation point which determines the region of interest ROI. The paper also, introduces a new objective quality metric based on a Psychovisual model that integrates the properties of the HVS that plays an important role in our POEFIC quality assessment. Our POEFIC coder is based on a vision model that incorporates various masking effects of human visual system HVS perception. Thus, our coder weights the wavelet coefficients based on that model and attempts to increase the perceptual quality for a given bit rate and observation distance. The perceptual weights for all wavelet subbands are computed based on 1) foveation masking to remove or reduce considerable high frequencies from peripheral regions 2) luminance and Contrast masking, 3) the contrast sensitivity function CSF to achieve the perceptual decomposition weighting. The new perceptually optimized codec has the same complexity as the original SPIHT techniques. However, the experiments results show that our coder demonstrates very good performance in terms of quality measurement.
Abstract: The increased number of automobiles in recent years
has resulted in great demand for fossil fuel. This has led to the
development of automobile by using alternative fuels which include
gaseous fuels, biofuels and vegetables oils as fuel. Energy from
biomass and more specific bio-diesel is one of the opportunities that
could cover the future demand of fossil fuel shortage. Biomass in the
form of cashew nut shell represents a new energy source and
abundant source of energy in India. The bio-fuel is derived from
cashew nut shell oil and its blend with diesel are promising
alternative fuel for diesel engine. In this work the pyrolysis Cashew
Nut Shell Liquid (CNSL)-Diesel Blends (CDB) was used to run the
Direct Injection (DI) diesel engine. The experiments were conducted
with various blends of CNSL and Diesel namely B20, B40, B60, B80
and B100. The results are compared with neat diesel operation. The
brake thermal efficiency was decreased for blends of CNSL and
Diesel except the lower blends of B20. The brake thermal efficiency
of B20 is nearly closer to that of diesel fuel. Also the emission level
of the all CNSL and Diesel blends was increased compared to neat
diesel. The higher viscosity and lower volatility of CNSL leads to
poor mixture formation and hence lower brake thermal efficiency and
higher emission levels. The higher emission level can be reduced by
adding suitable additives and oxygenates with CNSL and Diesel
blends.
Abstract: Network layer multicast, i.e. IP multicast, even after
many years of research, development and standardization, is not
deployed in large scale due to both technical (e.g. upgrading of
routers) and political (e.g. policy making and negotiation) issues.
Researchers looked for alternatives and proposed application/overlay
multicast where multicast functions are handled by end hosts, not
network layer routers. Member hosts wishing to receive multicast
data form a multicast delivery tree. The intermediate hosts in the tree
act as routers also, i.e. they forward data to the lower hosts in the
tree. Unlike IP multicast, where a router cannot leave the tree until all
members below it leave, in overlay multicast any member can leave
the tree at any time thus disjoining the tree and disrupting the data
dissemination. All the disrupted hosts have to rejoin the tree. This
characteristic of the overlay multicast causes multicast tree unstable,
data loss and rejoin overhead. In this paper, we propose that each node
sets its leaving time from the tree and sends join request to a number
of nodes in the tree. The nodes in the tree will reject the request if
their leaving time is earlier than the requesting node otherwise they
will accept the request. The node can join at one of the accepting
nodes. This makes the tree more stable as the nodes will join the tree
according to their leaving time, earliest leaving time node being at the
leaf of the tree. Some intermediate nodes may not follow their leaving
time and leave earlier than their leaving time thus disrupting the tree.
For this, we propose a proactive recovery mechanism so that disrupted
nodes can rejoin the tree at predetermined nodes immediately. We
have shown by simulation that there is less overhead when joining
the multicast tree and the recovery time of the disrupted nodes is
much less than the previous works. Keywords
Abstract: A model predictive controller based on recursive learning is proposed. In this SISO adaptive controller, a model is automatically updated using simple recursive equations. The identified models are then stored in the memory to be re-used in the future. The decision for model update is taken based on a new control performance index. The new controller allows the use of simple linear model predictive controllers in the control of nonlinear time varying processes.
Abstract: By introducing the concept of Oracle we propose an approach for improving the performance of genetic algorithms for large-scale asymmetric Traveling Salesman Problems. The results have shown that the proposed approach allows overcoming some traditional problems for creating efficient genetic algorithms.
Abstract: In this paper, a tooth shape optimization method for
cogging torque reduction in Permanent Magnet (PM) motors is
developed by using the Reduced Basis Technique (RBT) coupled by
Finite Element Analysis (FEA) and Design of Experiments (DOE)
methods. The primary objective of the method is to reduce the
enormous number of design variables required to define the tooth
shape. RBT is a weighted combination of several basis shapes. The
aim of the method is to find the best combination using the weights
for each tooth shape as the design variables. A multi-level design
process is developed to find suitable basis shapes or trial shapes at
each level that can be used in the reduced basis technique. Each level
is treated as a separated optimization problem until the required
objective – minimum cogging torque – is achieved. The process is
started with geometrically simple basis shapes that are defined by
their shape co-ordinates. The experimental design of Taguchi method
is used to build the approximation model and to perform
optimization. This method is demonstrated on the tooth shape
optimization of a 8-poles/12-slots PM motor.
Abstract: Increasing growth of information volume in the
internet causes an increasing need to develop new (semi)automatic
methods for retrieval of documents and ranking them according to
their relevance to the user query. In this paper, after a brief review
on ranking models, a new ontology based approach for ranking
HTML documents is proposed and evaluated in various
circumstances. Our approach is a combination of conceptual,
statistical and linguistic methods. This combination reserves the
precision of ranking without loosing the speed. Our approach
exploits natural language processing techniques to extract phrases
from documents and the query and doing stemming on words. Then
an ontology based conceptual method will be used to annotate
documents and expand the query. To expand a query the spread
activation algorithm is improved so that the expansion can be done
flexible and in various aspects. The annotated documents and the
expanded query will be processed to compute the relevance degree
exploiting statistical methods. The outstanding features of our
approach are (1) combining conceptual, statistical and linguistic
features of documents, (2) expanding the query with its related
concepts before comparing to documents, (3) extracting and using
both words and phrases to compute relevance degree, (4) improving
the spread activation algorithm to do the expansion based on
weighted combination of different conceptual relationships and (5)
allowing variable document vector dimensions. A ranking system
called ORank is developed to implement and test the proposed
model. The test results will be included at the end of the paper.