Abstract: In the present research, the titanium-catalyzed
ethylene dimerization and more specifically, the concomitant byproducts
and polymer formation have been studied in the presence of 2,5-dimethoxytetrahydrofuran as an electron donor compound in the
combination with triethylaluminium (TEA) as activator. Then, we
added ethylene chlorobromide as a new efficient promoter to the
relevant catalyst system. Finally, the behavior of novel homogeneous
[Titanium tetrabutoxide (Ti(OC4H9)4)/2,5-dimethoxytetrahydrofuran/
TEA/ethylene chlorobromide] was investigated in the various
operating conditions for the optimum production of 1-butene. In the
optimum conditions, a very high ethylene conversion (almost 90.77
%), a relative high selectivity to 1-butene (79.00 %), yield of reaction equal to 71.70 % and a significant productivity (turnover frequency
equal to 1370 h-1) were achieved.
Abstract: This paper presents the design, development and characterization of contractile water jet thruster (CWJT) for mini underwater robot. Instead of electric motor, this CWJT utilizes the Ionic Polymer Metal Composite (IPMC) as the actuator to generate the water jet. The main focus of this paper is to analyze the conceptual design of the proposed CWJT which would determine the thrust force value, jet flow behavior and actuator’s stress. Those thrust force and jet flow studies were carried out using Matlab/Simscape simulation software. The actuator stress had been analyzed using COSMOS simulation software. The results showed that there was no significant change for jet velocity at variable cross sectional nozzle area. However, a significant change was detected for jet velocity at different nozzle cross sectional area ratio which was up to 37%. The generated thrust force has proportional relation to the nozzle cross sectional area.
Abstract: Online discussions are an important component of
both blended and online courses. This paper examines the varieties of
online discussions and the perils, pitfalls and possibilities of this
rather new technological tool for enhanced learning. The discussion
begins with possible perils and pitfalls inherent in this educational
tool and moves to a consideration of the advantages of the varieties
of online discussions feasible for use in teacher education programs.
Abstract: At the end of the 20th century it was actual the
development of transport corridors and the improvement of their
technical parameters. With this purpose, many countries and Georgia
among them manufacture to construct new highways, railways and
also reconstruction-modernization of the existing transport
infrastructure. It is necessary to explore the artificial structures
(bridges and tunnels) on the existing tracks as they are very old.
Conference report includes the peculiarities of reconstruction of
tunnels, because we think that this theme is important for the
modernization of the existing road infrastructure. We must remark
that the methods of determining mining pressure of tunnel
reconstructions are worked out according to the jobs of new tunnels
but it is necessary to foresee additional mining pressure which will be
formed during their reconstruction. In this report there are given the
methods of figuring the additional mining pressure while
reconstruction of tunnels, there was worked out the computer
program, it is determined that during reconstruction of tunnels the
additional mining pressure is 1/3rd of main mining pressure.
Abstract: The quality improvements of the environmental
elements could increase the recreational opportunities in a certain
area (destination). The technique of the need for recreation focuses
on choosing certain destinations for recreational purposes. The basic
exchange taken into consideration is the one between the satisfaction
gained after staying in that area and the value expressed in money
and time allocated. The number of tourists in the respective area, the
duration of staying and the money spent including transportation
provide information on how individuals rank the place or certain
aspects of the area (such as the quality of the environmental
elements).
For the statistical analysis of the environmental benefits offered by
an area through the need of recreation technique, the following stages
are suggested:
- characterization of the reference area based on the
statistical variables considered;
- estimation of the environmental benefit through
comparing the reference area with other similar areas
(having the same environmental characteristics), from
the perspective of the statistical variables considered.
The model compared in recreation technique faced with a series of
difficulties which refers to the reference area and correct
transformation of time in money.
Abstract: This paper proposes rough set models with three
different level knowledge granules in incomplete information system
under tolerance relation by similarity between objects according to
their attribute values. Through introducing dominance relation on the
discourse to decompose similarity classes into three subclasses: little
better subclass, little worse subclass and vague subclass, it dismantles
lower and upper approximations into three components. By using
these components, retrieving information to find naturally hierarchical
expansions to queries and constructing answers to elaborative queries
can be effective. It illustrates the approach in applying rough set
models in the design of information retrieval system to access different
granular expanded documents. The proposed method enhances rough
set model application in the flexibility of expansions and elaborative
queries in information retrieval.
Abstract: The understanding of knee movement during swing
importance for golf swing improving and preventing injury. Thirty
male professional and amateur golfers were assigned to swing time
by time for 3 times. Data from a vedio-based motion capture were
used to compute knee joint movement variables. The results showed
that professional and amateur golfers were significantly in left knee
flexion angle at the impact point and mid follow through phase.
Nevertheless, left knee external rotation in both groups was also
significant. The right knee were no significant different in all
variable. However, pattern of knee joint movement are also likely
between professional and amateur golfers.
Abstract: An experimental study is presented on the effect of
Conservation Agriculture (CA) compared to Conventional
Agriculture (ConvA) upon Maize Yield based on split-plot model.
Two factors have been considered: A Factor-Fertilization with two
variants: A1- N40P40 kg/ha and A2- N90P70 kg/ha; B Factor- Crop
protection with 4 variants : B1- 4 treatments, B2-3 treatments, B3- 2
treatments and B4- 1 treatment. In comparison with conventional
agriculture, CA determined lower maize yields. Fertilization is the
key factor determining a yield gain of 973.58 kg/ha in ConvA and
1,123.33 kg/ha in CA. A reduced number of treatments determined a
yield decline. The A-B interaction had a positive effect on maize
yield when a larger amount of fertilizer and 4 or 3 treatments were
applied in ConvA and a benefic in CA for highest fertilization level
and 2 treatments. The B2A2 ConvA variant was the most efficient
leading to 302.67 kg/ha gain while B3A2 CA variant brought 181.33
kg production gain.
Abstract: The flow field within the combustor of scramjet
engine is very complex and poses a considerable challenge in the
design and development of a supersonic combustor with an optimized
geometry. In this paper comprehensive numerical studies on flow
field characteristics of different cavity based scramjet combustors
with transverse injection of hydrogen have been carried out for both
non-reacting and reacting flows. The numerical studies have been
carried out using a validated 2D unsteady, density based 1st-order
implicit k-omega turbulence model with multi-component finite rate
reacting species. The results show a wide variety of flow features
resulting from the interactions between the injector flows, shock
waves, boundary layers, and cavity flows. We conjectured that an
optimized cavity is a good choice to stabilize the flame in the
hypersonic flow, and it generates a recirculation zone in the scramjet
combustor. We comprehended that the cavity based scramjet
combustors having a bearing on the source of disturbance for the
transverse jet oscillation, fuel/air mixing enhancement, and flameholding
improvement. We concluded that cavity shape with
backward facing step and 45o forward ramp is a good choice to get
higher temperatures at the exit compared to other four models of
scramjet combustors considered in this study.
Abstract: Alpinia galanga is rhizome, generally known as
Greater galangal and is selected for isolation of newer constituents
accountable for various therapeutic activities. Present study is
intended to isolate glycoside from Alpinia galanga rhizomes. Alpinia
galanga methanolic extract was column chromatograph and eluted
with ethyl acetate-methanol (99:1) to isolate compound β-Sitosterol
Diarabinoside. Herein, the isolation and structural elucidation of new
compound is described. Chemical investigation of methanolic extract
of rhizomes of Alpinia galanga furnished a new compound β-
Sitosterol Diarabinoside. The IR, NMR and MASS investigations of
isolated compound confirmed its structure as β-Sitosterol
Diarabinoside, which is isolated for the first time from a medicinal
plant or any synthetic source.
Abstract: Shirvan is located in plain in Northern Khorasan province north east of Iran and has semiarid to temperate climate. To investigate the annual changes in some qualitative parameters such as electrical conductivity, total dissolved solids and chloride concentrations which have increased during ten continuous years. Fourteen groundwater sources including deep as well as semi-deep wells were sampled and were analyzed using standard methods. The trends of obtained data were analyzed during these years and the effects of different factors on the changes in electrical conductivity, concentration of chloride and total dissolved solids were clarified. The results showed that the amounts of some qualitative parameters have been increased during 10 years time which has led to decrease in water quality. The results also showed that increased in urban populations as well as extensive industrialization in the studied area are the most important reasons to influence underground water quality. Furthermore decrease in water quantity is also evident due to more water utilization and occurrence of recent droughts in the region during recent years.
Abstract: In this paper, we propose an approach for the classification of fingerprint databases. It is based on the fact that a fingerprint image is composed of regular texture regions that can be successfully represented by co-occurrence matrices. So, we first extract the features based on certain characteristics of the cooccurrence matrix and then we use these features to train a neural network for classifying fingerprints into four common classes. The obtained results compared with the existing approaches demonstrate the superior performance of our proposed approach.
Abstract: Hazard rate estimation is one of the important topics
in forecasting earthquake occurrence. Forecasting earthquake
occurrence is a part of the statistical seismology where the main
subject is the point process. Generally, earthquake hazard rate is
estimated based on the point process likelihood equation called the
Hazard Rate Likelihood of Point Process (HRLPP). In this research,
we have developed estimation method, that is hazard rate single
decrement HRSD. This method was adapted from estimation method
in actuarial studies. Here, one individual associated with an
earthquake with inter event time is exponentially distributed. The
information of epicenter and time of earthquake occurrence are used
to estimate hazard rate. At the end, a case study of earthquake hazard
rate will be given. Furthermore, we compare the hazard rate between
HRLPP and HRSD method.
Abstract: This paper deals with the project selection problem. Project selection problem is one of the problems arose firstly in the field of operations research following some production concepts from primary product mix problem. Afterward, introduction of managerial considerations into the project selection problem have emerged qualitative factors and criteria to be regarded as well as quantitative ones. To overcome both kinds of criteria, an analytic network process is developed in this paper enhanced with fuzzy sets theory to tackle the vagueness of experts- comments to evaluate the alternatives. Additionally, a modified version of Least-Square method through a non-linear programming model is augmented to the developed group decision making structure in order to elicit the final weights from comparison matrices. Finally, a case study is considered by which developed structure in this paper is validated. Moreover, a sensitivity analysis is performed to validate the response of the model with respect to the condition alteration.
Abstract: This contribution aims to outline some topics around the process of introduction of compulsory electronic exchange of documents (so called e-Boxes) in public administration. The research was conducted in order to gauge the difference between the expectation of those using internal email and their experience in reality. Both qualitative and quantitative research is employed to lead also to an estimation of the willingness and readiness of government bodies, business units and citizens to adopt new technologies. At the same time the most potent barriers to successful e-communication through the e-Boxes are identified.
Abstract: Propranolol is worldwide hypertension drug that is active in S-isomer. Patients must use this drug throughout their lives, and this action employsa significant level of expenditure. A simpler synthesis and lower cost can reduce the price for the patient. A sis pathway of S-propranolol starting from protection of (R,S)-propranolol with di-t-butyldicarbonate and then the product is oxidized with pyridiniumchlorochromate. The selective reduction of ketone occurrs with sodiumborohydride in the presence of metal chloride provided S-propranolol.
Abstract: The network of delivering commodities has been an important design problem in our daily lives and many transportation applications. The delivery performance is evaluated based on the system reliability of delivering commodities from a source node to a sink node in the network. The system reliability is thus maximized to find the optimal routing. However, the design problem is not simple because (1) each path segment has randomly distributed attributes; (2) there are multiple commodities that consume various path capacities; (3) the optimal routing must successfully complete the delivery process within the allowable time constraints. In this paper, we want to focus on the design optimization of the Multi-State Flow Network (MSFN) for multiple commodities. We propose an efficient approach to evaluate the system reliability in the MSFN with respect to randomly distributed path attributes and find the optimal routing subject to the allowable time constraints. The delivery rates, also known as delivery currents, of the path segments are evaluated and the minimal-current arcs are eliminated to reduce the complexity of the MSFN. Accordingly, the correct optimal routing is found and the worst-case reliability is evaluated. It has been shown that the reliability of the optimal routing is at least higher than worst-case measure. Two benchmark examples are utilized to demonstrate the proposed method. The comparisons between the original and the reduced networks show that the proposed method is very efficient.
Abstract: The knee bracing steel frame (KBF) is a new kind of energy dissipating frame, which combines excellent ductility and lateral stiffness. In this framing system, a special form of diagonal brace connected to a knee element instead of beam-column joint, is investigated. Recently, a similar system was proposed and named as chevron knee bracing system (CKB) which in comparison with the former system has a better energy absorption characteristic and at the same time retains the elastic nature of the structures. Knee bracing can provide a stiffer bracing system but reduces the ductility of the steel frame. Chevron knee bracing can be employed to provide the desired ductility level for a design. In this article, relation between seismic performance and structural parameters of the two above mentioned systems are investigated and compared. Frames with similar dimensions but various heights in both systems are designed according to Iranian code of practice for seismic resistant design of building, and then based on a non-linear push over static analysis; the seismic parameters such as behavior factor and performance levels are compared.
Abstract: This paper presents the adaptation of the knowledge management model and intellectual capital measurement NOVA to the needs of work or research project must be developed when conducting a program of graduate-level master. Brackets are added in each of the blocks which is represented in the original model NOVA and which allows to represent those involved in each of these.