Abstract: Sol-gel immobilization of enzymes, which can improve considerably their properties, is now one of the most used techniques. By deposition of the entrapped lipase on a solid support, a new and improved biocatalyst was obtained, which can be used with excellent results in acylation reactions. In this paper, lipase B from Candida antarctica was double immobilized on different adsorbents. These biocatalysts were employed in the kinetic resolution of several aliphatic secondary alcohols in organic medium. High total recovery yields of enzymatic activity, up to 560%, were obtained. For all the studied alcohols the enantiomeric ratios E were over 200. The influence of the reaction medium was studied for the kinetic resolution of 2-pentanol.
Abstract: The experimental and theoretical results of a ZVS
(Zero Voltage Switching) isolated flyback DC-DC converter using
multilayered coreless PCB step down 2:1 transformer are presented.
The performance characteristics of the transformer are shown which
are useful for the parameters extraction. The measured energy
efficiency of the transformer is found to be more than 94% with the
sinusoidal input voltage excitation. The designed flyback converter
has been tested successfully upto the output power level of 10W,
with a switching frequency in the range of 2.7MHz-4.3MHz. The
input voltage of the converter is varied from 25V-40V DC.
Frequency modulation technique is employed by maintaining
constant off time to regulate the output voltage of the converter. The
energy efficiency of the isolated flyback converter circuit under ZVS
condition in the MHz frequency region is found to be approximately
in the range of 72-84%. This paper gives the comparative results in
terms of the energy efficiency of the hard switched and soft switched
flyback converter in the MHz frequency region.
Abstract: The purpose of this article is to study the effects of
plants cover on overland flow and, therefore, its influences on the
amount of eroded and transported soil. In this investigation, all the
experiments were conducted in the LEGHYD laboratory using a
rainfall simulator and a soil tray. The experiments were conducted
using an experimental plot (soil tray) which is 2m long, 0.5 m wide
and 0.15 m deep. The soil used is an agricultural sandy soil (62,08%
coarse sand, 19,14% fine sand, 11,57% silt and 7,21% clay). Plastic
rods (4 mm in diameter) were used to simulate the plants at different
densities: 0 stem/m2 (bared soil), 126 stems/m², 203 stems/m², 461
stems/m² and 2500 stems/m²). The used rainfall intensity is 73mm/h
and the soil tray slope is fixed to 3°. The results have shown that the
overland flow velocities decreased with increasing stems density, and
the density cover has a great effect on sediment concentration.
Darcy–Weisbach and Manning friction coefficients of overland flow
increased when the stems density increased. Froude and Reynolds
numbers decreased with increasing stems density and, consequently,
the flow regime of all treatments was laminar and subcritical. From
these findings, we conclude that increasing the plants cover can
efficiently reduce soil loss and avoid denuding the roots plants.
Abstract: We propose our genuine research of geometric
moments which detects the mineral inadequacy in the frail groundnut
plant. This plant is prone to many deficiencies as a result of the
variance in the soil nutrients. By analyzing the leaves of the plant, we
detect the visual symptoms that are not recognizable to the naked eyes.
We have collected about 160 samples of leaves from the nearby fields.
The images have been taken by keeping every leaf into a black box to
avoid the external interference. For the first time, it has been possible
to provide the farmer with the stages of deficiencies. This paper has
applied the algorithms successfully to many other plants like Lady-s
finger, Green Bean, Lablab Bean, Chilli and Tomato. But we submit
the results of the groundnut predominantly. The accuracy of our
algorithm and method is almost 93%. This will again pioneer a kind of
green revolution in the field of agriculture and will be a boon to that
field.
Abstract: Predict daily global solar radiation (GSR) based on meteorological variables, using Multi-layer perceptron (MLP) neural networks is the main objective of this study. Daily mean air temperature, relative humidity, sunshine hours, evaporation, wind speed, and soil temperature values between 2002 and 2006 for Dezful city in Iran (32° 16' N, 48° 25' E), are used in this study. The measured data between 2002 and 2005 are used to train the neural networks while the data for 214 days from 2006 are used as testing data.
Abstract: This paper presents an alternate approach that uses
artificial neural network to simulate the flood level dynamics in a
river basin. The algorithm was developed in a decision support
system environment in order to enable users to process the data. The
decision support system is found to be useful due to its interactive
nature, flexibility in approach and evolving graphical feature and can
be adopted for any similar situation to predict the flood level. The
main data processing includes the gauging station selection, input
generation, lead-time selection/generation, and length of prediction.
This program enables users to process the flood level data, to
train/test the model using various inputs and to visualize results. The
program code consists of a set of files, which can as well be modified
to match other purposes. This program may also serve as a tool for
real-time flood monitoring and process control. The running results
indicate that the decision support system applied to the flood level
seems to have reached encouraging results for the river basin under
examination. The comparison of the model predictions with the
observed data was satisfactory, where the model is able to forecast
the flood level up to 5 hours in advance with reasonable prediction
accuracy. Finally, this program may also serve as a tool for real-time
flood monitoring and process control.
Abstract: The acid rain causes change in pH level of soil it is
directly influence on root and leaf growth. Yield of the crop was
reduced if acidity of soil is more. Acid rain seeps into the earth and
poisons plants and trees by dissolving toxic substances in the soil,
such as aluminum, which get absorbed by the roots. In present
investigation, effect of acid rain on crop Vigna radiata was studied.
The effect of acid rain on change in soil fertility was detected in
which pH of control sample was 6.5 and pH of 1% H2SO4 and 1%
HNO3 were 3.5. Nitrogen nitrate in soil was high in 1% HNO3 treated
soil & Control sample. Ammonium nitrogen in soil was low in 1%
HNO3 & H2SO4 treated soil. Ammonium nitrogen was medium in
control and other samples. The effect of acid rain on seed
germination on 3rd day of germination control sample growth was
6.1cm with plumule 0.001% HNO3 & 0.001% H2SO4 was 5.5cm
with plumule and 8cm with plumule. On 10th day fungal growth was
observed in 1% and 0.1% H2SO4 concentrations when all plants were
dead. The effect of acid rain on crop productivity was investigated on
3rd day roots were developed in plants. On 12th day Vigna radiata
showed more growth in 0.1% HNO3 and 0.1% H2SO4 treated plants
as compare to control plants. On 20th day development of
discoloration of plant pigments were observed on acid treated plants
leaves. On 34th day Vigna radiata showed flower in 0.1% HNO3,
0.01% HNO3 and 0.01% H2SO4treated plants and no flowers were
observed on control plants. On 42th day 0.1% HNO3, 0.01% HNO
and 0.01% H2SO4 treated Vigna radiata variety and control plants
were showed seeds on plants. In Vigna radiate variety 0.1%, 0.01%
HNO3, 0.01% H2SO4treated plants were dead on 46th day and fungal
growth was observed. The toxicological study was carried out on
Vigna radiata plants exposed to 1% HNO3 cells were damaged more
than 1% H2SO4. Leaf sections exposed to 0.001% HNO3 & H2SO4
showed less damaged of cells and pigmentation observed in entire
slide when compare with control plant.
Abstract: Global temperature had increased by about 0.5oC over
the past century, increasing temperature leads to a loss or a decrease
of soil organic matter (SOM). Whereas soil organic matter in many
tropical soils is less stable than that of temperate soils, and it will be
easily affected by climate change. Therefore, conservation of soil
organic matter is urgent issue nowadays. This paper presents the
effect of different doses (5%, 15%) of Ca-type zeolite in conjunction
with organic manure, applied to soil samples from Philippines,
Paraguay and Japan, on the decomposition resistance of soil organic
matter under high temperature. Results showed that a remain or
slightly increase the C/N ratio of soil. There are an increase in
percent of humic acid (PQ) that extracted with Na4P2O7. A decrease
of percent of free humus (fH) after incubation was determined. A
larger the relative color intensity (RF) value and a lower the color
coefficient (6logK) value following increasing zeolite rates leading
to a higher degrees of humification. The increase in the aromatic
condensation of humic acid (HA) after incubation, as indicates by the
decrease of H/C and O/C ratios of HA. This finding indicates that the
use of zeolite could be beneficial with respect to SOM conservation
under global warming condition.
Abstract: This study investigated the removal efficiency of electrokinetic remediation of copper-contaminated soil at different combinations of enhancement reagents used as anolyte and catholyte. Sodium hydroxide (at 0.1, 0.5, and 1.0 M concentrations) and distilled water were used as anolyte, while lactic acid (at 0.01, 0.1, and 0.5 M concentrations), ammonium citrate (also at 0.01, 0.1, and 0.5 M concentrations) and distilled water were used as catholyte. A continuous voltage application (1.0 VDC/cm) was employed for 240 hours for each experiment. The copper content of the catholyte was determined at the end of the 240-hour period. Optimization was carried out with a Response Surface Methodology - Optimal Design, including F test, and multiple comparison method, to determine which pair of anolyte-catholyte was the most significant for the removal efficiency. "1.0 M NaOH" was found to be the most significant anolyte while it was established that lactic acid was the most significant type of catholyte to be used for the most successful electrokinetic experiments. Concentrations of lactic acid should be at the range of 0.1 M to 0.5 M to achieve maximum percent removal values.
Abstract: The overall objective of this paper is to retrieve soil
surfaces parameters namely, roughness and soil moisture related to
the dielectric constant by inverting the radar backscattered signal
from natural soil surfaces.
Because the classical description of roughness using statistical
parameters like the correlation length doesn't lead to satisfactory
results to predict radar backscattering, we used a multi-scale
roughness description using the wavelet transform and the Mallat
algorithm. In this description, the surface is considered as a
superposition of a finite number of one-dimensional Gaussian
processes each having a spatial scale. A second step in this study
consisted in adapting a direct model simulating radar backscattering
namely the small perturbation model to this multi-scale surface
description. We investigated the impact of this description on radar
backscattering through a sensitivity analysis of backscattering
coefficient to the multi-scale roughness parameters.
To perform the inversion of the small perturbation multi-scale
scattering model (MLS SPM) we used a multi-layer neural network
architecture trained by backpropagation learning rule. The inversion
leads to satisfactory results with a relative uncertainty of 8%.
Abstract: Different techniques for estimating seasonal water
use from soil profile water depletion frequently do not account for
flux below the root zone. Shallow water table contribution to supply
crop water use may be important in arid and semi-arid regions.
Development of predictive root uptake models, under influence of
shallow water table makes it possible for planners to incorporate
interaction between water table and root zone into design of irrigation
projects. A model for obtaining soil moisture depletion from root
zone and water movement below it is discussed with the objective to
determine impact of shallow water table on seasonal moisture
depletion patterns under water table depth variation, up to the bottom
of root zone. The role of different boundary conditions has also been
considered. Three crops: Wheat (Triticum aestivum), Corn (Zea
mays) and Potato (Solanum tuberosum), common in arid & semi-arid
regions, are chosen for the study. Using experimentally obtained soil
moisture depletion values for potential soil moisture conditions,
moisture depletion patterns using a non linear root uptake model have
been obtained for different water table depths. Comparative analysis
of the moisture depletion patterns under these conditions show a wide
difference in percent depletion from different layers of root zone
particularly top and bottom layers with middle layers showing
insignificant variation in moisture depletion values. Moisture
depletion in top layer, when the water table rises to root zone
increases by 19.7%, 22.9% & 28.2%, whereas decrease in bottom
layer is 68.8%, 61.6% & 64.9% in case of wheat, corn & potato
respectively. The paper also discusses the causes and consequences
of increase in moisture depletion from top layers and exceptionally
high reduction in bottom layer, and the possible remedies for the
same. The numerical model developed for the study can be used to
help formulating irrigation strategies for areas where shallow
groundwater of questionable quality is an option for crop production.
Abstract: Most agricultural crops cultivated in Brazil are highly
nutrient demanding. Brazilian soils are generally acidic with low base
saturation and available nutrients. Demand for fertilizer application
has increased because the national agricultural sector expansion. To
improve productivity without environmental impact, there is the need
for the utilization of novel procedures and techniques to optimize
fertilizer application. This includes the digital soil mapping and GIS
application applied to mapping in different scales. This paper is
based on research, realized during 2005 to 2010 by Brazilian
Corporation for Agricultural Research (EMBRAPA) and its partners.
The purpose was to map soil fertility in national and regional scales.
A soil profile data set in national scale (1:5,000,000) was constructed
from the soil archives of Embrapa Soils, Rio de Janeiro and in the
regional scale (1:250,000) from COMIGO Cooperative soil data set,
Rio Verde, Brazil. The mapping was doing using ArcGIS 9.1 tools
from ESRI.
Abstract: The comparative analysis of different taxonomic
groups of microorganisms isolated from dark chernozem soils under
different agricultures (alfalfa, melilot, sainfoin, soybean, rapeseed) at
Almaty region of Kazakhstan was conducted. It was shown that the
greatest number of micromycetes was typical to the soil planted with
alfalfa and canola. Species diversity of micromycetes markedly
decreases as it approaches the surface of the root, so that the species
composition in the rhizosphere is much more uniform than in the
virgin soil. Promising strains of microscopic fungi and yeast with
plant growth-promoting activity to agricultures were selected. Among
the selected fungi there are representatives of Penicillium bilaiae,
Trichoderma koningii, Fusarium equiseti, Aspergillus ustus. The
highest rates of growth and development of seedlings of plants
observed under the influence of yeasts Aureobasidium pullulans,
Rhodotorula mucilaginosa, Metschnikovia pulcherrima. Using
molecular - genetic techniques confirmation of the identification
results of selected micromycetes was conducted.
Abstract: The studies concerned an effect of six variants of ion
exchange substrate (nutrient carriers with a different potential impact
on pH of soil solution) on vegetation of orchard grass during two
different periods (42 and 84 days). In the pot experiment plants were
grown on sand (model of degraded soil) and six mixtures of sand and
2% (v/v) additions of particular variants of ion exchange substrate
(with pH ranged from 5.5 to 8.0). The study results showed that the
addition of the substrate at pH=6.5 caused the highest increase in
plant yield after shorter vegetation period whereas the addition of the
substrate at pH=5.5 increased dry stem and root biomass of orchard
grass after longer vegetation period. Thus, the ion exchange substrate
at pH=6.5 can be recommended for restoration of exhausted soils
when shorter vegetation period is planned; the ion exchange substrate
at pH=5.5 can be used for the same purpose when longer periods of
vegetative growth are considered.
Abstract: This paper presents a comparison between two Pulse
Width Modulation (PWM) algorithms applied to a three-level Neutral
Point Clamped (NPC) Voltage Source Inverter (VSI). The first
algorithm applied is the triangular-sinusoidal strategy; the second is
the Space Vector Pulse Width Modulation (SVPWM) strategy. In the
first part, we present a topology of three-level NCP VSI. After that,
we develop the two PWM strategies to control this converter. At the
end the experimental results are presented.
Abstract: Desert regions around the Nile valley in Upper Egypt
contain great extent of swelling soil. Many different comment
procedures of treatment of the swelling soils for construction such as
pre-swelling, load balance OR soil replacement. One of the measure
factors which affect the level of the aggressiveness of the swelling
soil is the direction of the infiltration water directions within the
swelling soils. In this paper a physical model was installed to
measure the effect of water on the swelling soil with replacement
using fatty acid distillation residuals (FADR) mixed with sand as
thick sand-FADR mixture to prevent the water pathway arrive to the
swelling soil. Testing program have been conducted on different
artificial samples with different sand to FADR contents ratios (4%,
6%, and 9%) to get the optimum value fulfilling the impermeable
replacement. The tests show that a FADR content of 9% is sufficient
to produce impermeable replacement.
Abstract: Organic farmers across Saskatchewan face soil
phosphorus (P) shortages. Due to the restriction on inputs in organic
systems, farmers rely on crop rotation and naturally-occurring
arbuscular mycorrhizal fungi (AMF) for plant P supply. Crop rotation
is important for disease, pest, and weed management. Crops that are
not colonized by AMF (non-mycorrhizal) can decrease colonization
of a following crop. An experiment was performed to quantify soil P
cycling in four cropping sequences under organic management and
determine if mustard (non-mycorrhizal) was delaying the
colonization of subsequent wheat. Soils from the four cropping
sequences were measured for inorganic soil P (Pi), AMF spore
density (SD), phospholipid fatty acid analysis (PLFA, for AMF
biomarker counts), and alkaline phosphatase activity (ALPase,
related to AMF metabolic activity). Plants were measured for AMF
colonization and P content and uptake of above-ground biomass. A
lack of difference in AMF activity indicated that mustard was not
depressing colonization. Instead, AMF colonization was largely
determined by crop type and crop rotation.
Abstract: The effects of irrigation with dairy factory wastewater
on soil properties were investigated at two sites that had received
irrigation for > 60 years. Two adjoining paired sites that had never
received DFE were also sampled as well as another seven fields from
a wider area around the factory. In comparison with paired sites that
had not received effluent, long-term wastewater irrigation resulted in
an increase in pH, EC, extractable P, exchangeable Na and K and
ESP. These changes were related to the use of phosphoric acid,
NaOH and KOH as cleaning agents in the factory. Soil organic C
content was unaffected by DFE irrigation but the size (microbial
biomass C and N) and activity (basal respiration) of the soil
microbial community were increased. These increases were
attributed to regular inputs of soluble C (e.g. lactose) present as milk
residues in the wastewater. Principal component analysis (PCA) of
the soils data from all 11sites confirmed that the main effects of DFE
irrigation were an increase in exchangeable Na, extractable P and
microbial biomass C, an accumulation of soluble salts and a liming
effect. PCA analysis of soil bacterial community structure, using
PCR-DGGE of 16S rDNA fragments, generally separated individual
sites from one another but did not group them according to irrigation
history. Thus, whilst the size and activity of the soil microbial
community were increased, the structure and diversity of the
bacterial community remained unaffected.
Abstract: In medical therapy, laser has been widely used to conduct cosmetic, tumor and other treatments. During the process of laser irradiation, there may be thermal damage caused by excessive laser exposure. Thus, the establishment of a complete thermal analysis model is clinically helpful to physicians in reference data. In this study, porcine liver in place of tissue was subjected to laser irradiation to set up the experimental data considering the explored impact on surface thermal field and thermal damage region under different conditions of power, laser irradiation time, and distance between laser and porcine liver. In the experimental process, the surface temperature distribution of the porcine lever was measured by the infrared thermal imager. In the part of simulation, the bio heat transfer Pennes-s equation was solved by software SYSWELD applying in welding process. The double ellipsoid function as a laser source term is firstly considered in the prediction for surface thermal field and internal tissue damage. The simulation results are compared with the experimental data to validate the mathematical model established here in.
Abstract: This paper presents the stabilization potential of Class
F pond ash (PA) from a coal fired thermal power station on tropical
peat soil. Peat or highly organic soils are well known for their high
compressibility, natural moisture content, low shear strength and
long-term settlement. This study investigates the effect of different
amount (i.e., 5, 10, 15 and 20%) of PA on peat soil, collected from
Sarawak, Malaysia, mainly compaction and unconfined compressive
strength (UCS) properties. The amounts of PA added to the peat soil
sample as percentage of the dry peat soil mass. With the increase in
PA content, the maximum dry density (MDD) of peat soil increases,
while the optimum moisture content (OMC) decreases. The UCS
value of the peat soils increases significantly with the increase of PA
content and also with curing periods. This improvement on
compressive strength of tropical peat soils indicates that PA has the
potential to be used as a stabilizer for tropical peat soil. Also, the use
of PA in soil stabilization helps in reducing the pond volume and
achieving environment friendly as well as a sustainable development
of natural resources.