Abstract: The world crude oil demand is projected to rise to 108.5 million bbl/d by the year 2035. With reserves estimated at 869 billion tonnes worldwide, coal remains an abundant resource. The aim of this work was to produce a high value hydrocarbon liquid product using a Direct Coal Liquefaction (DCL) process at, relatively mild operating conditions. Via hydrogenation, the temperature-staged approach was investigated in a dual reactor lab-scale pilot plant facility. The objectives included maximising thermal dissolution of the coal in the presence of tetralin as the hydrogen donor solvent in the first stage with 2:1 and 3:1 solvent: coal ratios. Subsequently, in the second stage, hydrogen saturation, in particular, hydrodesulphurization (HDS) performance was assessed. Two commercial hydrotreating catalysts were investigated viz. NickelMolybdenum (Ni-Mo) and Cobalt-Molybdenum (Co-Mo). GC-MS results identified 77 compounds and various functional groups present in the first and second stage liquid product. In the first stage 3:1 ratios and liquid product yields catalysed by magnetite were favoured. The second stage product distribution showed an increase in the BTX (Benzene, Toluene, Xylene) quality of the liquid product, branched chain alkanes and a reduction in the sulphur concentration. As an HDS performer and selectivity to the production of long and branched chain alkanes, Ni-Mo had an improved performance over Co-Mo. Co-Mo is selective to a higher concentration of cyclohexane. For 16 days on stream each, Ni-Mo had a higher activity than Co-Mo. The potential to cover the demand for low–sulphur, crude diesel and solvents from the production of high value hydrocarbon liquid in the said process, is thus demonstrated.
Abstract: In this study, we demonstrate a high-resolution
refractive index sensor based on a Magnetic Photonic Crystal (MPC)
composed of a triangular lattice array of air holes embedded in Si
matrix. A microcavity is created by changing the radius of an air hole
in the middle of the photonic crystal. The cavity filled with gyrotropic
materials can serve as a refractive index sensor. The shift of the
resonant frequency of the sensor is obtained numerically using finite
difference time domain method under different ambient conditions
having refractive index from n = 1.0 to n = 1.1. The numerical results
show that a tiny change in refractive index of Δn = 0.0001 is
distinguishable. In addition, the spectral response of the MPC sensor is
studied while an external magnetic field is present. The results show
that the MPC sensor exhibits a dramatic improvement in resolution.
Abstract: In the past few years, high consumption of soft drinks
has attracted negative attention world-wide due to its possible
adverse effects, leading the health conscious people to find
alternative nutraceutical or herbal health drinks. In the present study,
a nutraceutical soft drink was developed utilizing some easily
available and well known traditional herbs having nutritional
potential. The key ingredients were selected as bael, amla, lemon
juice, ashwagandha and poppy seeds based on their household routine
use in the summer with proven refreshing, cooling and energetic
feeling since ages. After several trials made, the final composition of
nutraceutical summer soft drink was selected as most suitable
combination based on the taste, physicochemical, microbial and
organoleptic point of view. The physicochemical analysis of the
prepared drink found to contain optimum level of titratable acidity,
total soluble solids and pH which were in accordance of the
commercial recommendations. There were no bacterial colonies
found in the product therefore found within limits. During the nine
point’s hedonic scale sensory evaluation, the drink was strongly liked
for colour, taste, flavour and texture. The formulation was found to
contain flavonoids (80mg/100ml), phenolics (103mg/100ml), vitamin
C (250mg/100ml) and has antioxidant potential (75.52%) apart from
providing several other essential vitamins, minerals and healthy
components. The developed nutraceutical drink provides an
economical and feasible option for the consumers with very good
taste combined with potential health benefits. The present drink is
potentially capable to replace the synthetic soft drinks available in the
market.
Abstract: In this paper, we present a quantum statistical
mechanical formulation from our recently analytical expressions for
partial-wave transition matrix of a three-particle system. We report
the quantum reactive cross sections for three-body scattering
processes 1+(2,3)→1+(2,3) as well as recombination
1+(2,3)→1+(3,1) between one atom and a weakly-bound dimer. The
analytical expressions of three-particle transition matrices and their
corresponding cross-sections were obtained from the threedimensional
Faddeev equations subjected to the rank-two non-local
separable potentials of the generalized Yamaguchi form. The
equilibrium quantum statistical mechanical properties such partition
function and equation of state as well as non-equilibrium quantum
statistical properties such as transport cross-sections and their
corresponding transport collision integrals were formulated
analytically. This leads to obtain the transport properties, such as
viscosity and diffusion coefficient of a moderate dense gas.
Abstract: The seriously damaged structures during earthquakes
show the need and importance of design of reinforced concrete
structures with high ductility. Reinforced concrete beam-column
joints have an important function in all structures. Under seismic
excitation, the beam column joint region is subjected to horizontal
and vertical shear forces whose magnitude is many times higher than
the adjacent beam and column. Strength and ductility of structures
depends mainly on proper detailing of the reinforcement in beamcolumn
joints and the old structures were found ductility deficient.
DSP materials are obtained by using high quantities of super
plasticizers and high volumes of micro silica. In the case of High
Performance Densified Small Particle Concrete (HPDSPC), since
concrete is dense even at the micro-structure level, tensile strain
would be much higher than that of the conventional SFRC, SIFCON
& SIMCON. This in turn will improve cracking behaviour, ductility
and energy absorption capacity of composites in addition to
durability. The fine fibers used in our mix are 0.3mm diameter and 10
mm which can be easily placed with high percentage. These fibers
easily transfer stresses and act as a composite concrete unit to take up
extremely high loads with high compressive strength. HPDSPC
placed in the beam column joints helps in safety of human life due to
prolonged failure.
Abstract: This paper presents the results of a Finite Element
based vibration analysis of a solar powered Unmanned Aerial
Vehicle (UAV). The purpose of this paper was to quantify the free
vibration, forced vibration response due to differing point inputs in
order to predict the relative response magnitudes and frequencies at
various wing locations of vibration induced power generators
(magnet in coil) excited by gust and/or control surface pulse-decays
used to help power the flight of the electric UAV. A Fluid Structure
Interaction (FSI) study was performed in order to ascertain pertinent
design stresses and deflections as well as aerodynamic parameters of
the UAV airfoil. The 10 ft span airfoil is modeled using Mylar as the
primary material. Results show that the free mode in bending is 4.8
Hz while the first forced bending mode is on range of 16.2 to 16.7 Hz
depending on the location of excitation. The free torsional bending
mode is 28.3 Hz, and the first forced torsional mode is range of 26.4
to 27.8 Hz, depending on the location of excitation. The FSI results
predict the coefficients of aerodynamic drag and lift of 0.0052 and
0.077, respectively, which matches hand-calculations used to validate
the Finite Element based results. FSI based maximum von Mises
stresses and deflections were found to be 0.282 MPa and 3.4 mm,
respectively. Dynamic pressures on the airfoil range from 1.04 to
1.23 kPa corresponding to velocity magnitudes in range of 22 to 66
m/s.
Abstract: The conventional ceramic route was utilized to
prepare a hard magnetic powder (M-type strontium ferrite,
SrFe12O19). The stoichiometric mixture of iron oxide and strontium
carbonate were calcined at 1000oC and then fired at various
temperatures. The influence of various reaction parameters such as
mixing ratio, calcination temperature, firing temperature and firing
time on the magnetic behaviors of the synthesized magnetic powder
were investigated. The magnetic properties including Coercivity
(Hc), Magnetic saturation (Ms), and Magnetic remnance (Mr) were
measured by vibrating sample magnetometer. Morphologically the
produced magnetic powder has a dense hexagonal grain shape
structure.
Abstract: A teeming set of doctors that graduated from various
universities within and outside Nigeria with the hope of practicing in
the country, has their hope shattered because of poor financing, lack
of medical equipments and a very weak healthcare systems. Such
hydra headed challenges, allows room for quackery which
increasingly contributes to the cause of mortality in Nigeria. With a
view of reversing the challenges of healthcare delivery and financing
in Nigeria, African Health Market for Equity (AHME), a project
funded by the Bill and Melinda Gates foundation [With contribution
from Department For International Development (DFID)] and
currently implemented in three African Countries (Nigeria, Kenya
and Ghana) over a Five (5) year period supports the healthcare sector
via Medical credit fund (MCF). The study examines the impact of
credit policy and medical credit funding on Nigerian health market.
Ordinary least square analysis, correlation and granger causality tests
were employed to measure the extent to which the Nigerian
healthcare market has been influenced. Medical credit fund
significantly and positively influenced average monthly turnover of
private healthcare providers and Commercial bank’s lending rate had
a weak relationship with access to credit/approved loans (13.46%).
The programme has so far made 13.91% progress, which is very
poor, considering the minimum targeted private health care providers
(437.6) and expected number of loan approvals (180.4) for the two
years. Medical credit policy in Nigeria should be revised to include
private healthcare providers in rural area for more positive impact
and increased returns. Good brand advert and sensitization of the
programme to stakeholders and health pressure group, and an
extension of the programme beyond five years is necessary to better
address the issues raised in the study.
Abstract: A repairable mechanical system (as agricultural
tractor) is subject to deterioration or repeated failure and needs a
repair shops and also operator’s capability for the repair and
maintenance operations. Data are based on field visits and interviews
with 48MF 285 tractor operators from 14 villages collected in north
of Khouzestan province. The results showed that most operators were
lack the technical skill to service and repair tractors due to
insufficient training, specific education and work experience.
Inadequate repair and maintenance facilities, such as workshops,
mechanics and spare parts depots cause delays in repair work in the
survey areas. Farmers do not keep accurate service records and most
of them disregard proper maintenance and service of their tractors,
such as changing engine oil without following the manufacturer’s
recommendations. Since, Repair and maintenance facilities should be
established in village areas to guarantee timely repair in case of
breakdowns and to make spare parts available at low price. The
operators should keep service records accurately and adhere to
maintenance and service schedules according to the manufacturer’s
instructions. They should also be encouraged to do the service and
maintain their tractors properly.
Abstract: Second generation military Filipino Amerasians
comprise a formidable contemporary segment of the estimated
250,000-plus biracial Amerasians in the Philippines today. Overall,
they are a stigmatized and socioeconomically marginalized diaspora;
historically, they were abandoned or estranged by U.S. military
personnel fathers assigned during the century-long Colonial, Post-
World War II and Cold War Era of permanent military basing (1898-
1992). Indeed, U.S. military personnel are assigned in smaller
numbers in the Philippines today. This inquiry is an outgrowth of two
recent small sample studies. The first surfaced the impact of the U.S.
military prostitution system on formation of the ‘Derivative
Amerasian Family Construct’ on first generation Amerasians; a
second, qualitative case study suggested the continued effect of the
prostitution systems' destructive impetuous on second generation
Amerasians. The intent of this current qualitative, multiple-case study
was to actively seek out second generation sex industry toilers. The
purpose was to focus further on this human phenomenon in the postbasing
and post-military prostitution system eras. As background, the
former military prostitution apparatus has transformed into a modern
dynamic of rampant sex tourism and prostitution nationwide. This is
characterized by hotel and resorts offering unrestricted carnal access,
urban and provincial brothels (casas), discos, bars and pickup clubs,
massage parlors, local barrio karaoke bars and street prostitution. A
small case study sample (N = 4) of female and male second
generation Amerasians were selected. Sample formation employed a
non-probability ‘snowball’ technique drawing respondents from the
notorious Angeles, Metro Manila, Olongapo City ‘AMO Amerasian
Triangle’ where most former U.S. military installations were sited
and modern sex tourism thrives. A six-month study and analysis of
in-depth interviews of female and male sex laborers, their families
and peers revealed a litany of disturbing, and troublesome
experiences. Results showed profiles of debilitating human poverty,
history of family disorganization, stigmatization, social
marginalization and the ghost of the military prostitution system and
its harmful legacy on Amerasian family units. Emerging were testimonials of wayward young people ensnared in a maelstrom of
deep economic deprivation, familial dysfunction, psychological
desperation and societal indifference. The paper recommends that
more study is needed and implications of unstudied psychosocial and
socioeconomic experiences of distressed younger generations of
military Amerasians require specific research. Heretofore apathetic or
disengaged U.S. institutions need to confront the issue and formulate
activist and solution-oriented social welfare, human services and
immigration easement policies and alternatives. These institutions
specifically include academic and social science research agencies,
corporate foundations, the U.S. Congress, and Departments of State,
Defense and Health and Human Services, and Homeland Security
(i.e. Citizen and Immigration Services) It is them who continue to
endorse a laissez-faire policy of non-involvement over the entire
Filipino Amerasian question. Such apathy, the paper concludes,
relegates this consequential but neglected blood progeny to the status
of humiliating destitution and exploitation. Amerasians; thus, remain
entrapped in their former colonial, and neo-colonial habitat.
Ironically, they are unwitting victims of a U.S. American homeland
that fancies itself geo-politically as a strong and strategic military
treaty ally of the Philippines in the Western Pacific.
Abstract: A novel Active Flap System (AFS) has been developed
at DTU Wind Energy, as a result of a 3-year R&D project following
almost 10 years of innovative research in this field. The full scale AFS
comprises an active deformable trailing edge has been tested at the
unique rotating test facility at the Risø Campus of DTU Wind Energy
in Denmark. The design and instrumentation of the wing section and
the AFS are described. The general description and objectives of the
rotating test rig at the Risø campus of DTU are presented, along
with an overview of sensors on the setup and the test cases. The
post-processing of data is discussed and results of steady, flap step
and azimuth control flap cases are presented.
Abstract: The aim of this study was to investigate the
photocatalytic activity of polycrystalline phases of bismuth tungstate
of formula Bi2WO6. Polycrystalline samples were elaborated using a
coprecipitation technique followed by a calcination process at
different temperatures (300, 400, 600 and 900°C). The obtained
polycrystalline phases have been characterized by X-ray diffraction
(XRD), scanning electron microscopy (SEM), and transmission
electron microscopy (TEM). Crystal cell parameters and cell volume
depend on elaboration temperature. High-resolution electron
microscopy images and image simulations, associated with X-ray
diffraction data, allowed confirming the lattices and space groups
Pca21. The photocatalytic activity of the as-prepared samples was
studied by irradiating aqueous solutions of Rhodamine B, associated
with Bi2WO6 additives having variable crystallite sizes. The
photocatalytic activity of such bismuth tungstates increased as the
crystallite sizes decreased. The high specific area of the
photocatalytic particles obtained at 300°C seems to condition the
degradation kinetics of RhB.
Abstract: The purpose of this paper is to examine the effects and
relationship of stress and social support towards the quality of life
among flood victims in Malaysia. A total of 764 respondents took
part in the survey via convenience sampling. The Depression,
Anxiety and Stress scale (DASS) was utilized to measure stress while
The Multidimensional Scale of Perceived Social Support was used to
measure social support. To measure quality of life, the combination
of WHO Quality of Life – BREF (WHOQOL-BREF) and The Impact
of Event Scale – Revised (IES-R) were utilized. The findings of this
study indicate that there were significant correlations between
variables in the study. The findings showed a significant negative
relation between stress and quality of life; and significant positive
correlations between support from family as well as support from
friends with quality of life. Stress and support from family were
found to be significant predictors that influence the quality of life
among flood victims.
Abstract: Currently, planners try to have more green travel
options to decrease economic, social and environmental problems.
Therefore, this study tries to find significant urban travel factors to be
used to increase the usage of alternative urban travel modes. This
paper attempts to identify the relationship between prominent urban
mobility indicators and daily trips by public transport in 30 cities
from various parts of the world. Different travel modes,
infrastructures and cost indicators were evaluated in this research as
mobility indicators. The results of multi-linear regression analysis
indicate that there is a significant relationship between mobility
indicators and the daily usage of public transport.
Abstract: Review of studies carried out on the use of bagasse
ash for the improvement of deficient soils in Nigeria, with emphasis
on lateritic and black cotton soils is presented. Although, the bagasse
ash is mostly used as additive to the conventional soil stabilizers
(cement and lime), the studies generally showed improvement in the
geotechnical properties of the soils, either modified or stabilized with
the ash. This showed the potentials of using this agricultural waste
(bagasse ash) in the improvement of geotechnical properties of
deficient soils, thus suggesting that using this material at large scale
level in geotechnical engineering practice could help in the provision
of stable and durable structures, reduce cost of soil improvement and
also reduces environmental nuisance caused by the unused waste in
Nigeria.
Abstract: Due to the interference effects, the intrinsic
aerodynamic parameters obtained from the individual component
testing are always fundamentally different than those obtained for
complete model testing. Consideration and limitation for such testing
need to be taken into account in any design work related to the
component buildup method. In this paper, the scaled model of a
straight rectangular canard of a hybrid buoyant aircraft is tested at 50
m/s in IIUM-LSWT (Low Speed Wind Tunnel). Model and its
attachment with the balance are kept rigid to have results free from
the aeroelastic distortion. Based on the velocity profile of the test
section’s floor; the height of the model is kept equal to the
corresponding boundary layer displacement. Balance measurements
provide valuable but limited information of overall aerodynamic
behavior of the model. Zero lift coefficient is obtained at -2.2o and
the corresponding drag coefficient was found to be less than that at
zero angle of attack. As a part of the validation of low fidelity tool,
plot of lift coefficient plot was verified by the experimental data and
except the value of zero lift coefficients, the overall trend has under
predicted the lift coefficient. Based on this comparative study, a
correction factor of 1.36 is proposed for lift curve slope obtained
from the panel method.
Abstract: The purpose of this research was to investigate the
creep behaviour of the heterogeneous Timber-UHPFRC beams. New
developments have been done to further improve the structural
performance, such as strengthening of the timber (glulam) beam by
bonding composite material combine with an ultra-high performance
fibre reinforced concrete (UHPFRC) internally reinforced with or
without carbon fibre reinforced polymer (CFRP) bars. However, in
the design of wooden structures, in addition to the criteria of
strengthening and stiffness, deformability due to the creep of wood,
especially in horizontal elements, is also a design criterion. Glulam,
UHPFRC and CFRP may be an interesting composite mix to respond
to the issue of creep behaviour of composite structures made of
different materials with different rheological properties. In this paper,
we describe an experimental and analytical investigation of the creep
performance of the glulam-UHPFRC-CFRP beams assembled by
bonding. The experimental investigations creep behaviour was
conducted for different environments: in- and outside under constant
loading for approximately a year. The measured results are compared
with numerical ones obtained by an analytical model. This model was
developed to predict the creep response of the glulam-UHPFRCCFRP
beams based on the creep characteristics of the individual
components. The results show that heterogeneous glulam-UHPFRC
beams provide an improvement in both the strengthening and
stiffness, and can also effectively reduce the creep deflection of
wooden beams.
Abstract: Chitosan polyacrylic acid composite membranes were
prepared by a bulk polymerization method in presence of N, N'-
methylene bisacrylamide (crosslinker) and ammonium persulphate as
initiator. Membranes prepared from this copolymer in presence and
absence of Ag nanoparticles were characterized by measuring
mechanical and physical properties, water up-take and antibacterial
properties. The results obtained indicated that the prepared
membranes have antibacterial properties which increase with adding
Ag nanoparticles.
Abstract: In this paper we present the design of an optical
device based on a Herriott multi-pass cell fabricated on a small sized
acrylic slab for heat flux measurements using the deflection of a laser
beam propagating inside the cell. The beam deflection is produced by
the heat flux conducted to the acrylic slab due to a gradient in the
refractive index. The use of a long path cell as the sensitive element
in this measurement device, gives the possibility of high sensitivity
within a small size device. We present the optical design as well as
some experimental results in order to validate the device’s operation
principle.
Abstract: The main idea of this work is to investigate the effect
of knitted fabrics characteristics on moisture management properties.
Wetting and transport properties of single jersey, Rib 1&1 and
English Rib fabrics made out of cotton and blended Cotton/Polyester
yarns were studied. The dynamic water sorption of fabrics was
investigated under same isothermal and terrestrial conditions at
20±2°C-65±4% by using the Moisture Management Tester (MMT)
which can be used to quantitatively measure liquid moisture transfer
in one step in a fabric in multidirections: Absorption rate, moisture
absorbing time of the fabric's inner and outer surfaces, one-way
transportation capability, the spreading/drying rate, the speed of
liquid moisture spreading on fabric's inner and outer surfaces are
measured, recorded and discussed. The results show that fabric’s
composition and knit’s structure have a significant influence on those
phenomena.