Abstract: ZnO+Ga2O3 functionally graded thin films (FGTFs)
were examined for their potential use as Solar cell and organic light
emitting diodes (OLEDs). FGTF transparent conducting oxides (TCO)
were fabricated by combinatorial RF magnetron sputtering. The
composition gradient was controlled up to 10% by changing the
plasma power of the two sputter guns. A Ga2O3+ZnO graded region
was placed on the top layer of ZnO. The FGTFs showed up to 80%
transmittance. Their surface resistances were reduced to < 10% by
increasing the Ga2O3: pure ZnO ratio in the TCO. The FGTFs- work
functions could be controlled within a range of 0.18 eV. The
controlled work function is a very promising technology because it
reduces the contact resistance between the anode and Hall transport
layers of OLED and solar cell devices.
Abstract: This paper discusses a qualitative simulator QRiOM
that uses Qualitative Reasoning (QR) technique, and a process-based
ontology to model, simulate and explain the behaviour of selected
organic reactions. Learning organic reactions requires the application
of domain knowledge at intuitive level, which is difficult to be
programmed using traditional approach. The main objective of
QRiOM is to help learners gain a better understanding of the
fundamental organic reaction concepts, and to improve their
conceptual comprehension on the subject by analyzing the multiple
forms of explanation generated by the software. This paper focuses
on the generation of explanation based on causal theories to explicate
various phenomena in the chemistry subject. QRiOM has been tested
with three classes problems related to organic chemistry, with
encouraging results. This paper also presents the results of
preliminary evaluation of QRiOM that reveal its explanation
capability and usefulness.
Abstract: In recent years, the underground water sources in
southern Taiwan have become salinized because of saltwater
intrusions. This study explores the adsorption characteristics of
activated carbon on salinizing inorganic salts using isothermal
adsorption experiments and provides a model analysis. The
temperature range for the isothermal adsorption experiments ranged
between 5 to 45 ℃, and the amount adsorbed varied between 28.21 to
33.87 mg/g. All experimental data of adsorption can be fitted to both
the Langmuir and the Freundlich models. The thermodynamic
parameters for per chlorate onto granular activated carbon were
calculated as -0.99 to -1.11 kcal/mol for DG°, -0.6 kcal/mol for DH°,
and 1.21 to 1.84 kcal/mol for DS°. This shows that the adsorption
process of granular activated carbon is spontaneously exothermic. The
observation of adsorption behaviors under low ionic strength, low pH
values, and low temperatures is beneficial to the adsorption removal of
perchlorate with granular activated carbon.
Abstract: The effects of upflow liquid velocity (ULV) on
performance of expanded granular sludge bed (EGSB) system were
investigated. The EGSB reactor, made from galvanized steel pipe
0.10 m diameter and 5 m height, had been used to treat piggery
wastewater, after passing through acidification tank. It consisted of
39.3 l working volume in reaction zone and 122 l working volume in
sedimentation zone, at the upper part. The reactor was seeded with
anaerobically digested sludge and operated at the ULVs of 4, 8, 12
and 16 m/h, consecutively, corresponding to organic loading rates of
9.6 – 13.0 kg COD/ (m3.d). The average COD concentrations in the
influent were 9,601 – 13,050 mg/l. The COD removal was not
significantly different, i.e. 93.0% - 94.0%, except at ULV 12 m/h where
SS in the influent was exceptionally high so that VSS washout had
occurred, leading to low COD removal. The FCOD and VFA
concentrations in the effluent of all experiments were not much
different, indicating the same range of treatment performance. The
biogas production decreased at higher ULV and ULV of 4 m/h is
suggested as design criterion for EGSB system.
Abstract: Recently, nanomaterials are developed in the form of nano-films, nano-crystals and nano-pores. Lanthanide phosphates as a material find extensive application as laser, ceramic, sensor, phosphor, and also in optoelectronics, medical and biological labels, solar cells and light sources. Among the different kinds of rare-earth orthophosphates, yttrium orthophosphate has been shown to be an efficient host lattice for rare earth activator ions, which have become a research focus because of their important role in the field of light display systems, lasers, and optoelectronic devices. It is in this context that the 4fn- « 4fn-1 5d transitions of rare earth in insulating materials, lying in the UV and VUV, are the aim of large number of studies .Though there has been a few reports on Eu3+, Nd3+, Pr3+,Er3+, Ce3+, Tm3+ doped YPO4. The 4fn- « 4fn-1 5d transitions of the rare earth dependent to the host-matrix, several matrices ions were used to study these transitions, in this work we are suggesting to study on a very specific class of inorganic material that are orthophosphate doped with rare earth ions. This study focused on the effect of Ce3+ concentration on the structural and optical properties of Ce3+ doped YPO4 yttrium orthophosphate with powder form prepared by the Sol Gel method.
Abstract: A study was undertaken to assess the potential of an
Algal Turf Scrubber to remove nitrogen from aquaculture effluent to
reduce environmental pollution. High total ammonia nitrogen
concentrations were introduced to an Algal Turf Scrubber developed
under varying hydraulic surface loading rates of African catfish
(Clarius gariepinus) effluent in a recirculating aquaculture system.
Nutrient removal rates were not affected at total suspended solids
concentration of up to 0.04g TSS/l (P > 0.05). Nitrogen removal
rates 0.93-0.99g TAN/m²/d were recorded at very high loading rates
3.76-3.81 g TAN/m²/d. Total ammonia removal showed ½ order
kinetics between 1.6 to 2.3mg/l Total Ammonia Nitrogen
concentrations. Nitrogen removal increased with its loading, which
increased with hydraulic surface loading rate. Total Ammonia
Nitrogen removal by Algal turf scrubber was higher than reported
values for fluidized bed filters and trickling filters. The algal turf
scrubber also effectively removed nitrate thereby reducing the need
for water exchange.
Abstract: As global industry developed rapidly, the energy
demand also rises simultaneously. In the production process, there’s a
lot of energy consumed in the process. Formally, the energy used in
generating the heat in the production process. In the total energy
consumption, 40% of the heat was used in process heat, mechanical
work, chemical energy and electricity. The remaining 50% were
released into the environment. It will cause energy waste and
environment pollution. There are many ways for recovering the waste
heat in factory. Organic Rankine Cycle (ORC) system can produce
electricity and reduce energy costs by recovering the waste of low
temperature heat in the factory. In addition, ORC is the technology
with the highest power generating efficiency in low-temperature heat
recycling. However, most of factories executives are still hesitated
because of the high implementation cost of the ORC system, even a lot
of heat are wasted. Therefore, this study constructs a nonlinear
mathematical model of waste heat recovery equipment configuration
to maximize profits. A particle swarm optimization algorithm is
developed to generate the optimal facility installation plan for the ORC
system.
Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.
Abstract: A piston cylinder based high pressure differential
thermal analyzer system is developed to investigate phase
transformations, melting, glass transitions, crystallization behavior of
inorganic materials, glassy systems etc., at ambient to 4 GPa and at
room temperature to 1073 K. The pressure is calibrated by the phase
transition of bismuth and ytterbium and temperature is calibrated
by using thermocouple data chart. The system developed is
calibrated using benzoic acid, ammonium nitrate and it has a
pressure and temperature control of ± 8.9 x 10 -4 GPa , ± 2 K
respectively. The phase transition of Asx Te100-x chalcogenides,
ferrous oxide and strontium boride are studied using the
indigenously developed system.
Abstract: Lipases are enzymes particularly amenable for
immobilization by entrapment methods, as they can work equally
well in aqueous or non-conventional media and long-time stability of
enzyme activity and enantioselectivity is needed to elaborate more
efficient bioprocesses. The improvement of Pseudomonas
fluorescens (Amano AK) lipase characteristics was investigated by
optimizing the immobilization procedure in hybrid organic-inorganic
matrices using ionic liquids as additives. Ionic liquids containing a
more hydrophobic alkyl group in the cationic moiety are beneficial
for the activity of immobilized lipase. Silanes with alkyl- or aryl
nonhydrolizable groups used as precursors in combination with
tetramethoxysilane could generate composites with higher
enantioselectivity compared to the native enzyme in acylation
reactions of secondary alcohols. The optimal effect on both activity
and enantioselectivity was achieved for the composite made from
octyltrimethoxysilane and tetramethoxysilane at 1:1 molar ratio (60%
increase of total activity following immobilization and enantiomeric
ratio of 30). Ionic liquids also demonstrated valuable properties as
reaction media for the studied reactions, comparable with the usual
organic solvent, hexane.
Abstract: This paper discuss the separation of the miscible
liquids by means of fractional distillation. For complete separation of
liquids, the process of heating, condensation, separation and storage
is done automatically to achieve the objective. PIC micro-controller
has been used to control each and every process of the work. The
controller also controls the storage process by activating and deactivating
the conveyors. The liquids are heated which on reaching
their respective boiling points evaporate and enter the condensation
chamber where they convert into liquid. The liquids are then directed
to their respective tanks by means of stepper motor which moves in
three directions, each movement into different tank. The tank on
filling sends the signal to controller which then opens the solenoid
valves. The tank is emptied into the beakers below the nozzle. As the
beaker filled, the nozzle closes and the conveyors come into
operation. The filled beaker is replaced by an empty beaker from
behind. The work can be used in oil industries, chemical industries
and paint industries.
Abstract: This paper reviews the objectives, methods and results of previous studies on biodrying of solid waste in several countries. Biodrying of solid waste is a novel technology in developing countries such as in Malaysia where high moisture content in organic waste makes the segregation process for recycling purposes complicated and diminishes the calorific value for the use of fuel source. In addition, the high moisture content also encourages the breeding of vectors and disease-bearing animals. From the laboratory results, the average moisture content of organic waste, paper, plastics and metals are 58.17%, 37.93%, 29.79% and 1.03% respectively for UKM campus. Biodrying of solid waste is a simple method of waste treatment as well as a cost-efficient technology to dry the solid waste. The process depends on temperature monitoring and air flow control along with the natural biodegradable process of organic waste. This review shows that the biodrying of solid waste method has high potential in treatment and recycling of solid waste, be useful for biodrying study and implementation in Malaysia.
Abstract: Studies were carried out to determine the in vitro
susceptibility of the typhoid pathogens to combined action of Euphorbia hirta, Euphorbia heterophylla and Phyllanthus niruri. Clinical isolates of the typhoid bacilli were subjected to susceptibility testing using agar diffusion technique and the minimum inhibitory
concentration (MIC) determined with tube dilution technique. These
isolates, when challenged with doses of the extracts from the three
medicinal plants showed zones of inhibition as wide as 26±0.2mm, 22±0.1mm and 18±0.0mm respectively. The minimum inhibitory concentration (MIC) revealed organisms inhibited at varying
concentrations of extracts: E. hirta (S. typhi 0.250mg/ml, S. paratyphi A 0.125mg/ml, S. paratyphi B 0.185mg/ml and S. paratyphi C 0.225mg/ml), E. heterophylla (S. typhi 0.280mg/ml, S. paratyphi A
0.150mg/ml, S. paratyphi B 0.200mg/ml and S. paratyphi C 0.250mg/ml) and P. niruri (S. typhi 0.150mg/ml, S. paratyphi A 0.100mg/ml, S. paratyphi B 0.115mg/ml and S. paratyphi C 0.125mg/ml). The results of the synergy between the three plants in
the ration of 1:1:1 showed very low MICs for the test pathogens as follows S. typhi 0.025mg/ml, S. paratyphi A 0.080mg/ml, S. paratyphi B 0.015mg/ml and S. paratyphi C 0.10mg/ml with the
diameter zone of inhibition (DZI) ranging from 35±0.2mm,
28±0.4mm, 20±0.1mm and 32±0.3mm respectively. The secondary
metabolites were identified using simple methods and HPLC. Organic components such as anthroquinones, different alkaloids,
tannins, 6-ethoxy-1,2,3,4-tetrahydro-2,2,4-trimethyl and steroids were identified. The prevalence of Salmonellae, a deadly infectious disease, is still very high in parts of Nigeria. The synergistic action of these three plants is very high. It is concluded that pharmaceutical companies should take advantage of these findings to develop new
anti-typhoid drugs from these plants.
Abstract: Petroleum refineries discharged large amount of
wastewater -during the refining process- that contains hazardous
constituents that is hard to degrade. Anaerobic treatment process is
well known as an efficient method to degrade high strength
wastewaters. Up-flow Anaerobic Sludge Blanker (UASB) is a
common process used for various wastewater treatments. Two UASB
reactors were set up and operated in parallel to evaluate the treatment
efficiency of petroleum refinery wastewater. In this study four
organic volumetric loading rates were applied (i.e. 0.58, 0.89, 1.21
and 2.34 kg/m3·d), two loads to each reactor. Each load was applied
for a period of 60 days for the reactor to acclimatize and reach steady
state, and then the second load applied. The chemical oxygen demand
(COD) removals were satisfactory with the removal efficiencies at the
loadings applied were 78, 82, 83 and 81 % respectively.
Abstract: In order to evaluation the effects of soil organic
matter and biofertilizer on chickpea quality and biological
nitrogen fixation, field experiments were carried out in 2007
and 2008 growing seasons. In this research the effects of
different strategies for soil fertilization were investigated on
grain yield and yield component, minerals, organic compounds
and cooking time of chickpea. Experimental units were
arranged in split-split plots based on randomized complete
blocks with three replications. Main plots consisted of (G1):
establishing a mixed vegetation of Vicia panunica and
Hordeum vulgare and (G2): control, as green manure levels.
Also, five strategies for obtaining the base fertilizer
requirement including (N1): 20 t.ha-1 farmyard manure; (N2):
10 t.ha-1 compost; (N3): 75 kg.ha-1 triple super phosphate;
(N4): 10 t.ha-1 farmyard manure + 5 t.ha-1 compost and (N5):
10 t.ha-1 farmyard manure + 5 t.ha-1 compost + 50 kg.ha-1
triple super phosphate were considered in sub plots.
Furthermoree four levels of biofertilizers consisted of (B1):
Bacillus lentus + Pseudomonas putida; (B2): Trichoderma
harzianum; (B3): Bacillus lentus + Pseudomonas putida +
Trichoderma harzianum; and (B4): control (without
biofertilizers) were arranged in sub-sub plots. Results showed
that integrating biofertilizers (B3) and green manure (G1)
produced the highest grain yield. The highest amounts of yield
were obtained in G1×N5 interaction. Comparison of all 2-way
and 3-way interactions showed that G1N5B3 was determined
as the superior treatment. Significant increasing of N, P2O5,
K2O, Fe and Mg content in leaves and grains emphasized on
superiority of mentioned treatment because each one of these
nutrients has an approved role in chlorophyll synthesis and
photosynthesis abilities of the crops. The combined application
of compost, farmyard manure and chemical phosphorus (N5)
in addition to having the highest yield, had the best grain
quality due to high protein, starch and total sugar contents, low
crude fiber and reduced cooking time.
Abstract: In this investigation Salicylic acid, Sulfosalicylic acid
and Acetyl salicylic acid were chosen as a sample for thin layer
chromatography (TLC) on silica gel plates. Bicarbonate buffer at
different pH containing different amounts of boric acid was applied
as mobile phase. Specific interaction of these substances with boric
acid has effect on Rf in thin layer chromatography. Regular and
similar trend was observed in variations of Rf for mentioned
compounds in TLC by altering of percentages of boric acid in mobile
phase in pH range of 8-10. Also effect of organic solvent, mixture of
water/ organic solvent and organic solvent containing boric acid as
mobile phase was studied.
Abstract: In July 2012, an indoor/outdoor monitoring
programme was undertaken in two university sports facilities: a
fronton and a gymnasium. Comfort parameters (temperature, relative
humidity, CO and CO2) and total volatile organic compounds
(VOCs) were continuously monitored. Concentrations of NO2,
carbonyl compounds and individual VOCs were obtained. Low
volume samplers were used to collect particulate matter (PM10). The
minimum ventilation rates stipulated for acceptable indoor air quality
were observed in both sports facilities. It was found that cleaning
activities may have a large influence on the VOC levels. Acrolein
was one of the most abundant carbonyl compounds, showing
concentrations above the recommended limit. Formaldehyde was
detected at levels lower than those commonly reported for other
indoor environments. The PM10 concentrations obtained during the
occupancy periods ranged between 38 and 43μgm-3 in the fronton and
from 154 to 198μgm-3 in the gymnasium.
Abstract: Waste corn pulp was investigated as a potential feedstock during vermicomposting using Eisenia fetida. Corn pulp is the major staple food in Southern Africa and constitutes about 25% of the total organic waste. Wastecooked corn pulp was blended with cow dung in the ratio 6:1 respectively to optimize the vermicomposting process. The feedstock was allowed to vermicompost for 30 days. The vermicomposting took place in a 3- tray plastic worm bin. Moisture content, temperature, pH, and electrical conductivity were monitoreddaily. The NPK content was determined at day 30. During vermicomposting, moisture content increased from 27.68% to 52.41%, temperature ranged between 19- 25◦C, pH increased from 5.5 to 7.7, and electrical conductivity decreased from 80000μS/cm to 60000μS/cm. The ash content increased from 11.40% to 28.15%; additionally the volatile matter increased from 1.45% to 10.02%. An odorless, dark brown vermicompost was obtained. The vermicompost NPK content was 4.19%, 1.15%, and 6.18% respectively.
Abstract: In this study thermodynamic performance analysis of a
combined organic Rankine cycle and ejector refrigeration cycle is
carried out for use of low-grade heat source in the form of sensible
energy. Special attention is paid to the effects of system parameters
including the turbine inlet temperature and turbine inlet pressure on the
characteristics of the system such as ratios of mass flow rate, net work
production, and refrigeration capacity as well as the coefficient of
performance and exergy efficiency of the system. Results show that
for a given source the coefficient of performance increases with
increasing of the turbine inlet pressure. However, the exergy
efficiency has an optimal condition with respect to the turbine inlet
pressure.
Abstract: In this research, an aerobic composting method is
studied to reuse organic waste from rubber factory waste as soil fertilizer and to study the effect of cellulolytic microbial activator
(CMA) as the activator in the rubber factory waste composting. The
performance of the composting process was monitored as a function
of carbon and organic matter decomposition rate, temperature and
moisture content. The results indicate that the rubber factory waste is best composted with water hyacinth and sludge than composted
alone. In addition, the CMA is more affective when mixed with the rubber factory waste, water hyacinth and sludge since a good fertilizer is achieved. When adding CMA into the rubber factory
waste composted alone, the finished product does not achieve a
standard of fertilizer, especially the C/N ratio.
Finally, the finished products of composting rubber factory waste and water hyacinth and sludge (both CMA and without CMA), can be an environmental friendly alternative to solve the disposal problems of rubber factory waste. Since the C/N ratio, pH, moisture
content, temperature, and nutrients of the finished products are acceptable for agriculture use.