Abstract: The Kinetics formation of labile Complex
Ag (I) tetra (p-carboxyphenyl) porphyrin, was investigated at 25oC
and I=0.1M (NaNO3). By spectrophotometric titration, the
composition ratio of the complex was established to be 2:1
(Ag : H2TCPP). The equilibrium constant, K, was found to be
log 10-6.53. Binding of the first Ag (I) was found to be rate
determining step with rate constant, k1= 4.67×102 . A plausible
mechanism is discussed. We discus theoretically why Ag(I)2TCPP is
unstable.
Abstract: Synthesis gas manufacturing by steam reforming of hydrocarbons is an important industrial process. High endothermic nature of the process makes it one of the most cost and heat intensive processes. In the present work, composite effect of different inert gases on synthesis gas yield, feed gas conversion and temperature distribution along the reactor length has been studied using a heterogeneous model. Mathematical model was developed as a first stage and validated against the existing process models. With the addition of inert gases, a higher yield of synthesis gas is observed. Simultaneously the rector outlet temperature drops to as low as 810 K. It was found that Xenon gives the highest yield and conversion while Helium gives the lowest temperature. Using Xenon inert gas 20 percent reduction in outlet temperature was observed compared to traditional case.
Abstract: As a result of urbanization, the unpredictable growth of industry and transport, production of chemicals, military activities, etc. the concentration of anthropogenic toxicants spread in nature exceeds all the permissible standards. Most dangerous among these contaminants are organic compounds having great persistence, bioaccumulation, and toxicity along with our awareness of their prominent occurrence in the environment and food chain. Among natural ecological tools, plants still occupying above 40% of the world land, until recently, were considered as organisms having only a limited ecological potential, accumulating in plant biomass and partially volatilizing contaminants of different structure. However, analysis of experimental data of the last two decades revealed the essential role of plants in environment remediation due to ability to carry out intracellular degradation processes leading to partial or complete decomposition of carbon skeleton of different structure contaminants. Though, phytoremediation technologies still are in research and development, their various applications have been successfully used. The paper aims to analyze mechanisms of organic contaminants uptake and detoxification in plants, being the less studied issue in evaluation and exploration of plants potential for environment remediation.
Abstract: In some real applications of Statistical Process Control
it is necessary to design a control chart to not detect small process
shifts, but keeping a good performance to detect moderate and large
shifts in the quality. In this work we develop a new quality control
chart, the synthetic T2 control chart, that can be designed to cope with
this objective. A multi-objective optimization is carried out employing
Genetic Algorithms, finding the Pareto-optimal front of
non-dominated solutions for this optimization problem.
Abstract: Fly ash is a significant waste that is released of
thermal power plants and defined as very fine particles that are drifted upward with up taken by the flue gases due to the burning of
used coal [1]. The fly-ash is capable of removing organic
contaminants in consequence of high carbon content, a large surface area per unit volume and contained heavy metals. Therefore, fly ash
is used as an effective coagulant and adsorbent by pelletization [2, 3].
In this study, the possibility of use of fly ash taken from Turkey like low-cost adsorbent for adsorption of zinc ions found in waste
water was investigated. The fly ash taken from Turkey was pelletized with bentonite and molass to evaluate the adsorption capaticity. For
this purpose; analyses such as sieve analysis, XRD, XRF, FTIR and SEM were performed. As a result, it was seen that pellets prepared
from fly ash, bentonite and molass would be used for zinc adsorption.
Abstract: This research was conducted for the first time at the
southeastern coasts of the Caspian Sea in order to evaluate the
performance of osteichthyes cooperatives through production (catch)
function. Using one of the indirect valuation methods in this research,
contributory factors in catch were identified and were inserted into
the function as independent variables. In order to carry out this
research, the performance of 25 Osteichthyes catching cooperatives
in the utilization year of 2009 which were involved in fishing in
Miankale wildlife refuge region. The contributory factors in catch
were divided into groups of economic, ecological and biological
factors. In the mentioned function, catch rate of the cooperative were
inserted into as the dependant variable and fourteen partial variables
in terms of nine general variables as independent variables. Finally,
after function estimation, seven variables were rendered significant at
99 percent reliably level. The results of the function estimation
indicated that human resource (fisherman quantity) had the greatest
positive effect on catch rate with an influence coefficient of 1.7 while
weather conditions had the greatest negative effect on the catch rate
of cooperatives with an influence coefficient of -2.07. Moreover,
factors like member's share, experience and fisherman training and
fishing effort played the main roles in the catch rate of cooperative
with influence coefficients of 0.81, 0.5 and 0.21, respectively.
Abstract: High speed networks provide realtime variable bit rate
service with diversified traffic flow characteristics and quality
requirements. The variable bit rate traffic has stringent delay and
packet loss requirements. The burstiness of the correlated traffic
makes dynamic buffer management highly desirable to satisfy the
Quality of Service (QoS) requirements. This paper presents an
algorithm for optimization of adaptive buffer allocation scheme for
traffic based on loss of consecutive packets in data-stream and buffer
occupancy level. Buffer is designed to allow the input traffic to be
partitioned into different priority classes and based on the input
traffic behavior it controls the threshold dynamically. This algorithm
allows input packets to enter into buffer if its occupancy level is less
than the threshold value for priority of that packet. The threshold is
dynamically varied in runtime based on packet loss behavior. The
simulation is run for two priority classes of the input traffic –
realtime and non-realtime classes. The simulation results show that
Adaptive Partial Buffer Sharing (ADPBS) has better performance
than Static Partial Buffer Sharing (SPBS) and First In First Out
(FIFO) queue under the same traffic conditions.
Abstract: The increased number of automobiles in recent years
has resulted in great demand for fossil fuel. This has led to the
development of automobile by using alternative fuels which include
gaseous fuels, biofuels and vegetables oils as fuel. Energy from
biomass and more specific bio-diesel is one of the opportunities that
could cover the future demand of fossil fuel shortage. Biomass in the
form of cashew nut shell represents a new energy source and
abundant source of energy in India. The bio-fuel is derived from
cashew nut shell oil and its blend with diesel are promising
alternative fuel for diesel engine. In this work the pyrolysis Cashew
Nut Shell Liquid (CNSL)-Diesel Blends (CDB) was used to run the
Direct Injection (DI) diesel engine. The experiments were conducted
with various blends of CNSL and Diesel namely B20, B40, B60, B80
and B100. The results are compared with neat diesel operation. The
brake thermal efficiency was decreased for blends of CNSL and
Diesel except the lower blends of B20. The brake thermal efficiency
of B20 is nearly closer to that of diesel fuel. Also the emission level
of the all CNSL and Diesel blends was increased compared to neat
diesel. The higher viscosity and lower volatility of CNSL leads to
poor mixture formation and hence lower brake thermal efficiency and
higher emission levels. The higher emission level can be reduced by
adding suitable additives and oxygenates with CNSL and Diesel
blends.
Abstract: In this paper a new approach to face recognition is
presented that achieves double dimension reduction, making the
system computationally efficient with better recognition results and
out perform common DCT technique of face recognition. In pattern
recognition techniques, discriminative information of image
increases with increase in resolution to a certain extent, consequently
face recognition results change with change in face image resolution
and provide optimal results when arriving at a certain resolution
level. In the proposed model of face recognition, initially image
decimation algorithm is applied on face image for dimension
reduction to a certain resolution level which provides best
recognition results. Due to increased computational speed and feature
extraction potential of Discrete Cosine Transform (DCT), it is
applied on face image. A subset of coefficients of DCT from low to
mid frequencies that represent the face adequately and provides best
recognition results is retained. A tradeoff between decimation factor,
number of DCT coefficients retained and recognition rate with
minimum computation is obtained. Preprocessing of the image is
carried out to increase its robustness against variations in poses and
illumination level. This new model has been tested on different
databases which include ORL , Yale and EME color database.
Abstract: Soil washing process with a surfactant solution is a potential technology for the rapid removal of hydrophobic organic compound (HOC) from soil. However, large amount of washed water would be produced during operation and this should be treated effectively by proper methods. The soil washed water for complex contaminated site with HOC and heavy metals might contain high amount of pollutants such as HOC and heavy metals as well as used surfactant. The heavy metals in the soil washed water have toxic effects on microbial activities thus these should be removed from the washed water before proceeding to a biological waste-water treatment system. Moreover, the used surfactant solutions are necessary to be recovered for reducing the soil washing operation cost. In order to simultaneously remove the heavy metals and HOC from soil-washed water, activated carbon (AC) was used in the present study. In an anionic-nonionic surfactant mixed solution, the Cd(II) and phenanthrene (PHE) were effectively removed by adsorption on activated carbon. The removal efficiency for Cd(II) was increased from 0.027 mmol-Cd/g-AC to 0.142 mmol-Cd/g-AC as the mole ratio of SDS increased in the presence of PHE. The adsorptive capacity of PHE was also increased according to the SDS mole ratio due to the decrement of molar solubilization ratios (MSR) for PHE in an anionic-nonionic surfactant mixture. The simultaneous adsorption of HOC and cationic heavy metals using activated carbon could be a useful method for surfactant recovery and the reduction of heavy metal toxicity in a surfactant-enhanced soil washing process.
Abstract: Influence of octane and benzene on plant cell
ultrastructure and enzymes of basic metabolism, such as nitrogen
assimilation and energy generation have been studied. Different
plants: perennial ryegrass (Lolium perenne) and alfalfa (Medicago
sativa); crops- maize (Zea mays L.) and bean (Phaseolus vulgaris);
shrubs – privet (Ligustrum sempervirens) and trifoliate orange
(Poncirus trifoliate); trees - poplar (Populus deltoides) and white
mulberry (Morus alba L.) were exposed to hydrocarbons of different
concentrations (1, 10 and 100 mM). Destructive changes in bean and
maize leaves cells ultrastructure under the influence of benzene
vapour were revealed at the level of photosynthetic and energy
generation subcellular organells. Different deviations at the level of
subcellular organelles structure and distribution were observed in
alfalfa and ryegrass root cells under the influence of benzene and
octane, absorbed through roots. The level of destructive changes is
concentration dependent. Benzene at low 1 and 10 mM concentration
caused the increase in glutamate dehydrogenase (GDH) activity in
maize roots and leaves and in poplar and mulberry shoots, though to
higher extent in case of lower, 1mM concentration. The induction
was more intensive in plant roots. The highest tested 100mM
concentration of benzene was inhibitory to the enzyme in all plants.
Octane caused induction of GDH in all grassy plants at all tested
concentrations; however the rate of induction decreased parallel to
increase of the hydrocarbon concentration. Octane at concentration 1
mM caused induction of GDH in privet, trifoliate and white mulberry
shoots. The highest, 100mM octane was characterized by inhibitory
effect to GDH activity in all plants. Octane had inductive effect on
malate dehydrogenase in almost all plants and tested concentrations,
indicating the intensification of Trycarboxylic Acid Cycle.
The data could be suggested for elaboration of criteria for plant
selection for phytoremediation of oil hydrocarbons contaminated
soils.
Abstract: In an assessment of the extractability of metals in
green liquor dregs from the chemical recovery circuit of semichemical
pulp mill, extractable concentrations of heavy metals in
artificial gastric fluid were between 10 (Ni) and 717 (Zn) times
higher than those in artificial sweat fluid. Only Al (6.7 mg/kg; d.w.),
Ni (1.2 mg/kg; d.w.) and Zn (1.8 mg/kg; d.w.) showed extractability
in the artificial sweat fluid, whereas Al (730 mg/kg; d.w.), Ba (770
mg/kg; d.w.) and Zn (1290 mg/kg; d.w.) showed clear extractability
in the artificial gastric fluid. As certain heavy metals were clearly
soluble in the artificial gastric fluid, the careful handling of this
residue is recommended in order to prevent the penetration of green
liquor dregs across the human gastrointestinal tract.
Abstract: The main aim of this research is to study the possible
use of recycled fine aggregate made from waste rubble wall to
substitute partially for the natural sand used in the production of
cement and sand bricks. The bricks specimens were prepared by
using 100% natural sand; they were then replaced by recycled fine
aggregate at 25, 50, 75, and 100% by weight of natural sand. A series
of tests was carried out to study the effect of using recycled aggregate
on the physical and mechanical properties of bricks, such as density,
drying shrinkage, water absorption characteristic, compressive and
flexural strength. Test results indicate that it is possible to
manufacture bricks containing recycled fine aggregate with good
characteristics that are similar in physical and mechanical properties
to those of bricks with natural aggregate, provided that the percentage
of recycled fine aggregates is limited up to 50-75%.
Abstract: We have developed a microfluidic device system for the continuous producting of nanoparticles, and we have clarified the relationship between the mixing performance of reactors and the particle size. First, we evaluated the mixing performance of reactors by carring out the Villermaux–Dushman reaction and determined the experimental conditions for producing AgCl nanoparticles. Next, we produced AgCl nanoparticles and evaluated the mixing performance and the particle size. We found that as the mixing performance improves the size of produced particles decreases and the particle size distribution becomes sharper. We produced AgCl nanoparticles with a size of 86 nm using the microfluidic device that had the best mixing performance among the three reactors we tested in this study; the coefficient of variation (Cv) of the size distribution of the produced nanoparticles was 26.1%.
Abstract: The purposes of this paper are to (1) promote excellence in computer science by suggesting a cohesive innovative approach to fill well documented deficiencies in current computer science education, (2) justify (using the authors' and others anecdotal evidence from both the classroom and the real world) why this approach holds great potential to successfully eliminate the deficiencies, (3) invite other professionals to join the authors in proof of concept research. The authors' experiences, though anecdotal, strongly suggest that a new approach involving visual modeling technologies should allow computer science programs to retain a greater percentage of prospective and declared majors as students become more engaged learners, more successful problem-solvers, and better prepared as programmers. In addition, the graduates of such computer science programs will make greater contributions to the profession as skilled problem-solvers. Instead of wearily rememorizing code as they move to the next course, students will have the problem-solving skills to think and work in more sophisticated and creative ways.
Abstract: Day by day technology increases and problems
associated with this technology also increase. Several researches
were carried out to investigate the deployment of such material safely
in geotechnical engineering in particular and civil engineering in
general. However, different types of waste material have such as
cement duct, fly ash and slag been proven to be suitable in several
applications. In this research cement dust mixed with different
percentages of sand will be used in some civil engineering
application as will be explained later in this paper throughout filed
and laboratory test. The used mixer (waste material with sand) prove
high performance, durability to environmental condition, low cost
and high benefits. At higher cement dust ratio, small cement ratio is
valuable for compressive strength and permeability. Also at small
cement dust ratio higher cement ratio is valuable for compressive
strength.
Abstract: Artifact rejection plays a key role in many signal processing applications. The artifacts are disturbance that can occur during the signal acquisition and that can alter the analysis of the signals themselves. Our aim is to automatically remove the artifacts, in particular from the Electroencephalographic (EEG) recordings. A technique for the automatic artifact rejection, based on the Independent Component Analysis (ICA) for the artifact extraction and on some high order statistics such as kurtosis and Shannon-s entropy, was proposed some years ago in literature. In this paper we try to enhance this technique proposing a new method based on the Renyi-s entropy. The performance of our method was tested and compared to the performance of the method in literature and the former proved to outperform the latter.
Abstract: The adsorption properties of CO and H2 on iron-based
catalyst with addition of Zr and Ni were investigated using
temperature programmed desorption process. It was found that on the
carburized iron-based catalysts, molecular state and dissociative state
CO existed together. The addition of Zr was preferential for the
molecular state adsorption of CO on iron-based catalyst and the
presence of Ni was beneficial to the dissociative adsorption of CO. On
H2 reduced catalysts, hydrogen mainly adsorbs on the surface iron
sites and surface oxide sites. On CO reduced catalysts, hydrogen
probably existed as the most stable CH and OH species. The addition
of Zr was not benefit to the dissociative adsorption of hydrogen on
iron-based catalyst and the presence of Ni was preferential for the
dissociative adsorption of hydrogen.
Abstract: Generally, administrative systems in an academic
environment are disjoint and support independent queries. The
objective in this work is to semantically connect these independent
systems to provide support to queries run on the integrated platform.
The proposed framework, by enriching educational material in the
legacy systems, provides a value-added semantics layer where
activities such as annotation, query and reasoning can be carried out
to support management requirements. We discuss the development of
this ontology framework with a case study of UAE University
program administration to show how semantic web technologies can
be used by administration to develop student profiles for better
academic program management.
Abstract: Understanding the cell's large-scale organization is an
interesting task in computational biology. Thus, protein-protein
interactions can reveal important organization and function of the
cell. Here, we investigated the correspondence between protein
interactions and function for the yeast. We obtained the correlations
among the set of proteins. Then these correlations are clustered using
both the hierarchical and biclustering methods. The detailed analyses
of proteins in each cluster were carried out by making use of their
functional annotations. As a result, we found that some functional
classes appear together in almost all biclusters. On the other hand, in
hierarchical clustering, the dominancy of one functional class is
observed. In brief, from interaction data to function, some correlated
results are noticed about the relationship between interaction and
function which might give clues about the organization of the
proteins.