Abstract: The agriculture lignocellulosic by-products are receiving increased attention, namely in the search for filter materials that retain contaminants from water. These by-products, specifically almond and hazelnut shells are abundant in Portugal once almond and hazelnuts production is a local important activity. Hazelnut and almond shells have as main constituents lignin, cellulose and hemicelluloses, water soluble extractives and tannins. Along the adsorption of heavy metals from contaminated waters, water soluble compounds can leach from shells and have a negative impact in the environment. Usually, the chemical characterization of treated water by itself may not show environmental impact caused by the discharges when parameters obey to legal quality standards for water. Only biological systems can detect the toxic effects of the water constituents. Therefore, the evaluation of toxicity by biological tests is very important when deciding the suitability for safe water discharge or for irrigation applications.
The main purpose of the present work was to assess the potential impacts of waters after been treated for heavy metal removal by hazelnut and almond shells adsorption systems, with short term acute toxicity tests.
To conduct the study, water at pH 6 with 25 mg.L-1 of lead, was treated with 10 g of shell per litre of wastewater, for 24 hours. This procedure was followed for each bark. Afterwards the water was collected for toxicological assays; namely bacterial resistance, seed germination, Lemna minor L. test and plant grow. The effect in isolated bacteria strains was determined by disc diffusion method and the germination index of seed was evaluated using lettuce, with temperature and humidity germination control for 7 days. For aquatic higher organism, Lemnas were used with 4 days contact time with shell solutions, in controlled light and temperature. For terrestrial higher plants, biomass production was evaluated after 14 days of tomato germination had occurred in soil, with controlled humidity, light and temperature.
Toxicity tests of water treated with shells revealed in some extent effects in the tested organisms, with the test assays showing a close behaviour as the control, leading to the conclusion that its further utilization may not be considered to create a serious risk to the environment.
Abstract: In this study, effects of EGR on CO and HC emissions
of a dual fuel HCCI-DI engine are investigated. Tests were
conducted on a single-cylinder variable compression ratio (VCR)
diesel engine with compression ratio of 17.5. Premixed gasoline is
provided by a carburetor connected to intake manifold and equipped
with a screw to adjust premixed air-fuel ratio, and diesel fuel is
injected directly into the cylinder through an injector at pressure of
250 bars. A heater placed at inlet manifold is used to control the
intake charge temperature. Optimal intake charge temperature was
110-115ºC due to better formation of a homogeneous mixture
causing HCCI combustion. Timing of diesel fuel injection has a great
effect on stratification of in-cylinder charge in HCCI combustion.
Experiments indicated 35 BTDC as the optimum injection timing.
Coolant temperature was maintained 50ºC during the tests. Results
show that increasing engine speed at a constant EGR rate leads to
increase in CO and UHC emissions due to the incomplete
combustion caused by shorter combustion duration and less
homogeneous mixture. Results also show that increasing EGR
reduces the amount of oxygen and leads to incomplete combustion
and therefore increases CO emission due to lower combustion
temperature. HC emission also increases as a result of lower
combustion temperatures.
Abstract: The Yasuj city stream named the Beshar supply
water for different usages such as aquaculture farms , drinking,
agricultural and industrial usages. Fish processing plants
,Agricultural farms, waste water of industrial zones and hospitals
waste water which they are generate by human activity produce a
considerable volume of effluent and when they are released in to the
stream they can effect on the water quality and down stream aquatic
systems. This study was conducted to evaluate the effects of outflow
effluent from different human activity and point and non point
pollution sources on the water quality and health of the Beshar
river next to Yasuj. Yasuj is the biggest and most important city in
the Kohkiloye and Boyerahmad province . The Beshar River is one
of the most important aquatic ecosystems in the upstream of the
Karun watershed in south of Iran which is affected by point and non
point pollutant sources . This study was done in order to evaluate the
effects of human activities on the water quality and health of the
Beshar river. This river is approximately 190 km in length and
situated at the geographical positions of 51° 20' to 51° 48' E and 30°
18' to 30° 52' N it is one of the most important aquatic ecosystems of
Kohkiloye and Boyerahmad province in south-west Iran. In this
research project, five study stations were selected to examine water
pollution in the Beshar River systems. Human activity is now one of
the most important factors affecting on hydrology and water quality
of the Beshar river. Humans use large amounts of resources to sustain
various standards of living, although measures of sustainability are
highly variable depending on how sustainability is defined. The
Beshar river ecosystems are particularly sensitive and vulnerable to
human activities. The water samples were analyzed, then some
important water quality parameters such as pH, dissolve oxygen
(DO), Biochemical Oxygen Demand (BOD5), Chemical Oxygen
Demand (COD), Total Suspended Solids (TDS),Turbidity,
Temperature, Nitrates (NO3) and Phosphates (PO4) were estimated
at the two stations. The results show a downward trend in the water
quality at the down stream of the city. The amounts of
BOD5,COD,TSS,T,Turbidity, NO3 and PO4 in the down stream
stations were considerably more than the station 1. By contrast the
amounts of DO in the down stream stations were less than to the
station 1. However when effluent discharge consequence of human
activities are released into the Beshar river near the city, the quality
of river are decreases and the environmental problems of the river
during the next years are predicted to rise.
Abstract: Since water resources of desert Naein City are very
limited, a approach which saves water resources and meanwhile
meets the needs of the greenspace for water is to use city-s sewage
wastewater. Proper treatment of Naein-s sewage up to the standards
required for green space uses may solve some of the problems of
green space development of the city. The present paper closely
examines available statistics and information associated with city-s
sewage system, and determines complementary stages of sewage
treatment facilities of the city. In the present paper, population, per
capita water use, and required discharge for various greenspace
pieces including different plants are calculated. Moreover, in order to
facilitate the application of water resources, a Crude water
distribution network apart from drinking water distribution network is
designed, and a plan for mixing municipal wells- water with sewage
wastewater in proposed mixing tanks is suggested. Hence, following
greenspace irrigation reform and complementary plan, per capita
greenspace of the city will be increased from current amount of 13.2
square meters to 32 square meters.
Abstract: Multiport diffusers are the effective engineering
devices installed at the modern marine outfalls for the steady
discharge of effluent streams from the coastal plants, such as
municipal sewage treatment, thermal power generation and seawater
desalination. A mathematical model using a two-dimensional
advection-diffusion equation based on a flat seabed and incorporating
the effect of a coastal tidal current is developed to calculate the
compounded concentration following discharges of desalination
brine from a sea outfall with multiport diffusers. The analytical
solutions are computed graphically to illustrate the merging of
multiple brine plumes in shallow coastal waters, and further
approximation will be made to the maximum shoreline's
concentration to formulate dilution of a multiport diffuser discharge.
Abstract: Scalability poses a severe threat to the existing
DRAM technology. The capacitors that are used for storing and
sensing charge in DRAM are generally not scaled beyond 42nm.
This is because; the capacitors must be sufficiently large for reliable
sensing and charge storage mechanism. This leaves DRAM memory
scaling in jeopardy, as charge sensing and storage mechanisms
become extremely difficult. In this paper we provide an overview of
the potential and the possibilities of using Phase Change Memory
(PCM) as an alternative for the existing DRAM technology. The
main challenges that we encounter in using PCM are, the limited
endurance, high access latencies, and higher dynamic energy
consumption than that of the conventional DRAM. We then provide
an overview of various methods, which can be employed to
overcome these drawbacks. Hybrid memories involving both PCM
and DRAM can be used, to achieve good tradeoffs in access latency
and storage density. We conclude by presenting, the results of these
methods that makes PCM a potential replacement for the current
DRAM technology.
Abstract: This paper investigates the structure and content of the
wine lists in upscale restaurants in Portugal (N=61). The respondents
considered that a wine list should be easy to use and to modify, welldesigned,
modern and varied. Respondents also stated that they
perform on average 6 revisions to the wine list per year. The
restaurant owner, the restaurant manager and the sommelier were the
main persons in charge of the wine list design. One of the most
important reasons for selecting wines across most restaurants was to
‘complement the menu’ and ‘pairing food with wine’. Restaurants
also reported to be relatively independent from suppliers and
magazine evaluations. Moreover, this work revealed that the
restaurant wine list is considered by restaurateurs as a strategic tool to
sell wine as a complement to the menu, to improve customer
satisfaction and loyalty, to increase restaurant value and to enhance a
successful positioning.
Abstract: The main purpose of this paper is to research on the
methodologies of BYD to implement the opportune innovation. BYD
is a Chinese company which has the IT component manufacture, the
rechargeable battery and the automobile businesses. The paper deals
with the innovation methodology as the same as the IPR management
BYD implements in order to obtain the rapid growth of technology
development with the reasonable cost of money and time.
Abstract: Although many researchers have studied the flow
hydraulics in compound channels, there are still many complicated problems in determination of their flow rating curves. Many different
methods have been presented for these channels but extending them
for all types of compound channels with different geometrical and
hydraulic conditions is certainly difficult. In this study, by aid of nearly 400 laboratory and field data sets of geometry and flow rating
curves from 30 different straight compound sections and using artificial neural networks (ANNs), flow discharge in compound channels was estimated. 13 dimensionless input variables including relative depth, relative roughness, relative width, aspect ratio, bed
slope, main channel side slopes, flood plains side slopes and berm
inclination and one output variable (flow discharge), have been used
in ANNs. Comparison of ANNs model and traditional method
(divided channel method-DCM) shows high accuracy of ANNs model results. The results of Sensitivity analysis showed that the relative depth with 47.6 percent contribution, is the most effective input parameter for flow discharge prediction. Relative width and
relative roughness have 19.3 and 12.2 percent of importance, respectively. On the other hand, shape parameter, main channel and
flood plains side slopes with 2.1, 3.8 and 3.8 percent of contribution, have the least importance.
Abstract: Composite nanostructures of metal
core/semiconductor shell (Au/CdS) configuration were prepared
using organometalic method. UV-Vis spectra for the Au/CdS colloids
show initially two well separated bands, corresponding to surface
plasmon of the Au core, and the exciton of CdS shell. The absorption
of CdS shell is enhanced, while the Au plasmon band is suppressed
as the shell thickness increases. The shell sizes were estimated from
the optical spectra using the effective mass approximation model
(EMA), and compared to the sizes of the Au core and CdS shell
measured by high resolution transmission electron microscope
(HRTEM). The changes in the absorption features are discussed in
terms of gradual increase in the coupling strength of the Au core
surface plasmon and the exciton in the CdS. leading to charge
transfer and modification of electron oscillation in Au core.
Abstract: Battery storage system is emerging as an essential component of hybrid power system based on renewable energy resources such as solar and wind in order to make these sources dispatchable. Accurate modeling of battery storage system is ssential in order to ensure optimal planning of hybrid power systems incorporating battery storage. Majority of the system planning studies involving battery storage assume battery charging efficiency to be constant. However a strong correlation exists between battery charging efficiency and battery state of charge. In this work a Fuzzy logic based model has been presented for determining battery charging efficiency relative to a particular SOC. In order to demonstrate the efficacy of proposed approach, reliability evaluation studies are carried out for a hypothetical autonomous hybrid power system located in Jaisalmer, Rajasthan, India. The impact of considering battery charging efficiency as a function of state of charge is compared against the assumption of fixed battery charging efficiency for three different configurations comprising of wind-storage, solar-storage and wind-solar-storage.
Abstract: In this research, Response Surface Methodology (RSM) is used to investigate the effect of four controllable input variables namely: discharge current, pulse duration, pulse off time and applied voltage Surface Roughness (SR) of on Electrical Discharge Machined surface. To study the proposed second-order polynomial model for SR, a Central Composite Design (CCD) is used to estimation the model coefficients of the four input factors, which are alleged to influence the SR in Electrical Discharge Machining (EDM) process. Experiments were conducted on AISI D2 tool steel with copper electrode. The response is modeled using RSM on experimental data. The significant coefficients are obtained by performing Analysis of Variance (ANOVA) at 5% level of significance. It is found that discharge current, pulse duration, and pulse off time and few of their interactions have significant effect on the SR. The model sufficiency is very satisfactory as the Coefficient of Determination (R2) is found to be 91.7% and adjusted R2-statistic (R2 adj ) 89.6%.
Abstract: We have considered an unmagnetized dusty plasma system consisting of ions obeying superthermal distribution and strongly coupled negatively charged dust. We have used reductive perturbation method and derived the Kordeweg-de Vries-Burgers (KdV-Burgers) equation. The behavior of the shock waves in the plasma has been investigated.
Abstract: Wall-surface jet induced by the dielectric barrier
discharge (DBD) has been proposed as an actuator for active flow
control in aerodynamic applications. Discharge plasma evolution of
the DBD plasma actuator was simulated based on a simple fluid model,
in which the electron, one type of positive ion and negative ion were
taken into account. Two-dimensional simulation was conducted, and
the results are in agreement with the insights obtained from
experimental studies. The simulation results indicate that the discharge
mode changes depending on applied voltage slope; when the applied
voltage is positive-going with high applied voltage slope, the
corona-type discharge mode turns into the streamer-type discharge
mode and the threshold voltage slope is around 300 kV/ms in this
simulation. The characteristics of the electrohydrodynamic (EHD)
force, which is the source of the wall-surface jet, also change
depending on the discharge mode; the tentative peak value of the EHD
force during the positive-going voltage phase is saturated by the
periodical formation of the streamer-type discharge.
Abstract: A new strategy for oriented immobilization of proteins was proposed. The strategy contains two steps. The first step is to search for a docking site away from the active site on the protein surface. The second step is trying to find a ligand that is able to grasp the targeted site of the protein. To avoid ligand binding to the active site of protein, the targeted docking site is selected to own opposite charges to those near the active site. To enhance the ligand-protein binding, both hydrophobic and electrostatic interactions need to be included. The targeted docking site should therefore contain hydrophobic amino acids. The ligand is then selected through the help of molecular docking simulations. The enzyme α-amylase derived from Aspergillus oryzae (TAKA) was taken as an example for oriented immobilization. The active site of TAKA is surrounded by negatively charged amino acids. All the possible hydrophobic sites on the surface of TAKA were evaluated by the free energy estimation through benzene docking. A hydrophobic site on the opposite side of TAKA-s active site was found to be positive in net charges. A possible ligand, 3,3-,4,4- – Biphenyltetra- carboxylic acid (BPTA), was found to catch TAKA by the designated docking site. Then, the BPTA molecules were grafted onto silica gels and measured the affinity of TAKA adsorption and the specific activity of thereby immobilized enzymes. It was found that TAKA had a dissociation constant as low as 7.0×10-6 M toward the ligand BPTA on silica gel. The increase in ionic strength has little effect on the adsorption of TAKA, which indicated the existence of hydrophobic interaction between ligands and proteins. The specific activity of the immobilized TAKA was compared with the randomly adsorbed TAKA on primary amine containing silica gel. It was found that the orderly immobilized TAKA owns a specific activity twice as high as the one randomly adsorbed by ionic interaction.
Abstract: In the present study, development of salbutamol
sulphate nanoparticles that adhere to gastric mucus was investigated.
Salbutamol sulphate has low bioavailability due to short transit time in
gastric. It also has a positive surface charge that provides hurdles to be
encapsulated by the positively strong mucoadhesive polymer of
chitosan. To overcome the difficulties, the surface charge of active
ingredient was modified using several nonionic and anionic
stomach-specific polymers. The nanoparticles were prepared using
ionotropic gelation technique. The evaluation involved determination
of particle size, zeta potential, entrapment efficiency, in vitro drug
release and in vitro mucoadhesion test. Results exhibited that the use
of anionic alginate polymer was more satisfactory than that of
nonionic polymer. Characteristics of the particles was nano-size, high
encapsulation efficiency, fulfilled the drug release requirements and
adhesive towards stomach for around 11 hours. This result shows that
the salbutamol sulphate nanoparticles can be utilized for improvement
its delivery.
Abstract: The Chichiawan stream in the Wulin catchment in
Taiwan is the natural habitat of Formosan landlocked salmon. Human
and agriculture activities gradually worsen water quality and impact
the fish habitat negatively. To protect and manage Formosan
landlocked salmon habitat, it is important to understand a variety
land-uses affect on the watershed responses to storms. This study
discusses watershed responses to the dry-day before a storm event and
a variety of land-uses in the Wulin catchment. Under the land-use
planning in the Wulin catchment, the peak flows during typhoon
events do not have noticeable difference. However, the nutrient
exports can be highly reduced under the strategies of restraining
agriculture activities. Due to the higher affinity of P for soil than that
of N, the exports of TN from overall Wuling catchment were much
greater than Ortho-P. Agriculture mainly centralized in subbasin A,
which is the important source of nutrients in nonpoint source discharge.
The subbasin A supplied about 26% of the TN and 32% of the Ortho-P
discharge in 2004, despite the fact it only covers 19% area of the
Wuling catchment. The subbasin analysis displayed that the
agricultural subbasin A exports higher nutrients per unit area than
other forest subbasins. Additionally, the agricultural subbasin A
contributed a higher percentage to total Ortho-P exports compares to
TN. The results of subbasin analysis might imply the transport of
Ortho-P was similar to the particulate matter which was mainly
influenced by the runoff and affected by the desorption from soil
particles while the TN (dominated as nitrate-N) was mainly influenced
by base-flow.
Abstract: Nonlinear propagation of ion-acoustic waves in a selfgravitating
dusty plasma consisting of warm positive ions,
isothermal two-temperature electrons and negatively charged dust
particles having charge fluctuations is studied using the reductive
perturbation method. It is shown that the nonlinear propagation of
ion-acoustic waves in such plasma can be described by an uncoupled
third order partial differential equation which is a modified form of
the usual Korteweg-deVries (KdV) equation. From this nonlinear
equation, a new type of solution for the ion-acoustic wave is
obtained. The effects of two-temperature electrons, gravity and dust
charge fluctuations on the ion-acoustic solitary waves are discussed
with possible applications.
Abstract: The effect of the blade tip geometry of a high pressure
gas turbine is studied experimentally and computationally for high
speed leakage flows. For this purpose two simplified models are
constructed, one models a flat tip of the blade and the second models
a cavity tip of the blade. Experimental results are obtained from a
transonic wind tunnel to show the static pressure distribution along
the tip wall and provide flow visualization. RANS computations
were carried to provide further insight into the mean flow behavior
and to calculate the discharge coefficient which is a measure of the
flow leaking over the tip. It is shown that in both geometries of tip
the flow separates over the tip to form a separation bubble. The
bubble is higher for the cavity tip while a complete shock wave
system of oblique waves ending with a normal wave can be seen for
the flat tip. The discharge coefficient for the flat tip shows less
dependence on the pressure ratio over the blade tip than the cavity
tip. However, the discharge coefficient for the cavity tip is lower than
that of the flat tip, showing a better ability to reduce the leakage flow
and thus increase the turbine efficiency.
Abstract: Measurements of capacitance C and dissipation
factor tand of the stator insulation system provide useful information
about internal defects within the insulation. The index k is defined as
the proportionality constant between the changes at high voltage of
capacitance DC and of the dissipation factor Dtand . DC and
Dtand values were highly correlated when small flat defects were
within the insulation and that correlation was lost in the presence of
large narrow defects like electrical treeing. The discrimination
between small and large defects is made resorting to partial discharge
PD phase angle analysis. For the validation of the results, C and tand
measurements were carried out in a 15MVA 4160V steam turbine
turbogenerator placed in a sugar mill. In addition, laboratory test
results obtained by other authors were analyzed jointly. In such
laboratory tests, model coil bars subjected to thermal cycling resulted
highly degraded and DC and Dtand values were not correlated. Thus,
the index k could not be calculated.