Abstract: The systematic manipulations of shapes and sizes of
inorganic compounds greatly benefit the various application fields
including optics, magnetic, electronics, catalysis and medicine.
However shape control has been much more difficult to achieve.
Hence exploration of novel method for the preparation of differently
shaped nanoparticles is challenging research area. II-VI group of
semiconductor cadmium sulphide (CdS) nanostructure with different
morphologies (such as, acicular like, mesoporous, spherical shapes)
and of crystallite sizes vary from 11 to 16 nm were successfully
synthesized by chemical aqueous precipitation of Cd2+ ions with
homogeneously released S2- ions from decomposition of cadmium
sulphate (CdSO4) and thioacetamide (CH3CSNH2) by annealing at
different radiations (microwave, ultrasonic and sunlight) with matter
and systematic research has been done for various factors affecting
the controlled growth rate of CdS nanoparticles. The obtained
nanomaterials have been characterized by X-ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FTIR),
Thermogravometric (DSC-TGA) analysis and Scanning Electron
Microscopy (SEM). The result indicates that on increasing the
reaction time particle size increases but on increasing the molar ratios
grain size decreases.
Abstract: TiO2/MgO composite films were prepared by coating
the magnesium acetate solution in the pores of mesoporous TiO2
films using a dip coating method. Concentrations of magnesium
acetate solution were varied in a range of 1x10-4 – 1x10-1 M. The
TiO2/MgO composite films were characterized by scanning electron
microscopy (SEM), transmission electron microscropy (TEM),
electrochemical impedance spectroscopy(EIS) , transient voltage
decay and I-V test. The TiO2 films and TiO2/MgO composite films
were immersed in a 0.3 mM N719 dye solution. The Dye-sensitized
solar cells with the TiO2/MgO/N719 structure showed an optimal
concentration of magnesium acetate solution of 1x10-3 M resulting in
the MgO film estimated thickness of 0.0963 nm and giving the
maximum efficiency of 4.85%. The improved efficiency of dyesensitized
solar cell was due to the magnesium oxide film as the wide
band gap coating decays the electron back transfer to the triiodide
electrolyte and reduce charge recombination.
Abstract: Deoxygenation of beef fat for the production of hydrogenated biodiesel is investigated in a high pressure continuous flow fixed bed reactor over palladium-supported mesoporous titania catalyst synthesized via a combined single-step sol-gel process with surfactant-assisted templating method (SATM). The catalyst possessed a mesoporous charactheristic with high surface area and narrow pore size distribution. The main products of all Pd/TiO2 catalysts are n-heptadecane (n-C17) and n-pentadecane (n-C15) resulting from decarbonylation reaction. Pd/TiO2 catalyst synthesized via a combined single-step sol-gel process with SATM (SSSG) gave higher activity and selectivity to the desired products when compared to IWI/SG-TiO2 and IWI/P25-TiO2, respectively. SSSG catalyst gave the average conversion up to 80-90 % and 80 % for the selectivity in diesel range hydrocarbons. This result may cause by the higher surface area and the ability in dispersion of palladium ion in mesoporous of TiO2 during sol-gel process.