Abstract: The aim of this work was to apply extractive
distillation for acetonitrile removal from water solutions, to validate
thermodynamic criterion based on excess Gibbs energy to entrainer
selection process for acetonitrile – water mixture separation and show
its potential efficiency at isothermal conditions as well as at isobaric
(conditions of real distillation process), to simulate and analyze an
extractive distillation process with chosen entrainers: optimize
amount of trays and feeds, entrainer/original mixture and reflux
ratios. Equimolar composition of the feed stream was chosen for the
process, comparison of the energy consumptions was carried out.
Glycerol was suggested as the most energetically and ecologically
suitable entrainer.
Abstract: In order to better understand the long term
implications of the grout wear failure mode in large-diameter plainsided
grouted connections, a numerical model has been developed
and calibrated that can take advantage of existing operational plant
data to predict the wear accumulation for the actual load conditions
experienced over a given period, thus limiting the requirement for
expensive monitoring systems. This model has been derived and
calibrated based on site structural condition monitoring (SCM) data
and supervisory control and data acquisition systems (SCADA) data
for two operational wind turbine generator substructures afflicted
with this challenge, along with experimentally derived wear rates.
Abstract: Heavy rare earth (HRE) oxalate concentrates were
prepared from the Egyptian crude monazite sand (graded about 47%).
The concentrates were specified quantitatively for their constituents
of individual rare earth elements using ion chromatograph (IC) and
qualitatively by scanning electron microscope (SEM) for the other
major constituents. The 1st concentrate was composed of 10.5%
HREE where 7.25% of them represented yttrium. The 2nd concentrate
contained about 41.7% LREE, 17.5% HREE and 13.6% Th. The
LREE involved 18.3% Ce, 10.5% La and 8% Nd while the HREE
were 8.7% Y, 3.5% Gd and 2.9% Dy. The 3rd concentrate was
containing about 8.0% LREE (3.7% Ce, 2.0% La and 1.5% Nd),
10.2% HREE (6.4% yttrium and 2.0% Dy) and 2.1% uranium. The
final concentrate comprised 0.84% uranium beside iron, chromium
and traces of REE.
Abstract: This study presents a cost-effective approach for rapid
fabricating modeling platforms utilized in fused deposition modeling
system. A small-batch production of modeling platforms about 20
pieces can be obtained economically through silicone rubber mold
using vacuum casting without applying the plastic injection molding.
The air venting systems is crucial for fabricating modeling platform
using vacuum casting. Modeling platforms fabricated can be used for
building rapid prototyping model after sandblasting. This study offers
industrial value because it has both time-effectiveness and
cost-effectiveness.
Abstract: Soil erosion is a very complex phenomenon, resulting
from detachment and transport of soil particles by erosion agents.
The kinetic energy of raindrop is the energy available for detachment
and transport by splashing rain. The soil erodibility is defined as the
ability of soil to resist to erosion. For this purpose, an experimental
study was conducted in the laboratory using rainfall simulator to
study the effect of the kinetic energy of rain (Ec) on the soil
erodibility (K). The soil used was a sandy agricultural soil of 62.08%
coarse sand, 19.14% fine sand, 6.39% fine silt, 5.18% coarse silt and
7.21% clay. The obtained results show that the kinetic energy of
raindrops evolves as a power law with soil erodibility.
Abstract: This work is focused on the study of valuation of
recycled concrete aggregates, by measuring certain properties of
concrete in the fresh and hardened state. In this study, rheological
tests and physic-mechanical characterization on concretes and
mortars were conducted with recycled concrete whose geometric
properties were identified aggregates. Mortars were elaborated with
recycled fine aggregate (0/5mm) and concretes were manufactured
using recycled coarse aggregates (5/12.5 mm and 12.5/20 mm). First,
a study of the mortars was conducted to determine the effectiveness
of polycarboxylate superplasticizer on the workability of these and
their action deflocculating of the recycled sand. The rheological
behavior of mortars based on fine aggregate recycled was
characterized. The results confirm that the mortars composed of
different fractions of recycled sand (0 /5) have a better mechanical
properties (compressive and flexural strength) compared to normal
mortar. Also, the mechanical strengths of concretes made with
recycled aggregates (5/12.5 mm and 12.5/20 mm), are comparable to
those of conventional concrete with conventional aggregates,
provided that the implementation can be improved by the addition of
a superplasticizer.
Abstract: Series of laboratory tests were carried out to study the
extent of scour caused by a three-dimensional wall jets exiting from a
square cross-section nozzle and into a non-cohesive sand beds.
Previous observations have indicated that the effect of the tail water
depth was significant for densimetric Froude number greater than ten.
However, the present results indicate that the cut off value could be
lower depending on the value of grain size-to-nozzle width ratio.
Numbers of equations are drawn out for a better scaling of numerous
scour parameters. Also suggested the empirical prediction of scour to
predict the scour centre line profile and plan view of scour profile at
any particular time.
Abstract: The crude oil in an oil well exists in various phases
such as gas, seawater, and sand, as well as oil. Therefore, a phase
separator is needed at the front of a single-phase pump for
pressurization and transfer. On the other hand, the application of a
multiphase pump can provide such advantages as simplification of the
equipment structure and cost savings, because there is no need for a
phase separation process. Therefore, the crude oil transfer method
using a multiphase pump is being applied to recently developed oil
wells. Due to this increase in demand, technical demands for the
development of multiphase pumps are sharply increasing, but the
progress of research into related technologies is insufficient, due to the
nature of multiphase pumps that require high levels of skills. This
study was conducted to verify the reliability of pump performance
evaluation using numerical analysis, which is the basis of the
development of a multiphase pump. For this study, a model was
designed by selecting the specifications of this study. The performance
of the designed model was evaluated through numerical analysis and
experiment. The results of the performance evaluation were compared
to verify the reliability of the result using numerical analysis.
Abstract: Microarray technology is universally used in the study
of disease diagnosis using gene expression levels. The main
shortcoming of gene expression data is that it includes thousands of
genes and a small number of samples. Abundant methods and
techniques have been proposed for tumor classification using
microarray gene expression data. Feature or gene selection methods
can be used to mine the genes that directly involve in the
classification and to eliminate irrelevant genes. In this paper
statistical measures like T-Statistics, Signal-to-Noise Ratio (SNR)
and F-Statistics are used to rank the genes. The ranked genes are used
for further classification. Particle Swarm Optimization (PSO)
algorithm and Shuffled Frog Leaping (SFL) algorithm are used to
find the significant genes from the top-m ranked genes. The Naïve
Bayes Classifier (NBC) is used to classify the samples based on the
significant genes. The proposed work is applied on Lung and Ovarian
datasets. The experimental results show that the proposed method
achieves 100% accuracy in all the three datasets and the results are
compared with previous works.
Abstract: Characterization of the engineering behavior of
unsaturated soil is dependent on the soil-water characteristic curve
(SWCC), a graphical representation of the relationship between water
content or degree of saturation and soil suction. A reasonable
description of the SWCC is thus important for the accurate prediction
of unsaturated soil parameters. The measurement procedures for
determining the SWCC, however, are difficult, expensive, and timeconsuming.
During the past few decades, researchers have laid a
major focus on developing empirical equations for predicting the
SWCC, with a large number of empirical models suggested. One of
the most crucial questions is how precisely existing equations can
represent the SWCC. As different models have different ranges of
capability, it is essential to evaluate the precision of the SWCC
models used for each particular soil type for better SWCC estimation.
It is expected that better estimation of SWCC would be achieved via
a thorough statistical analysis of its distribution within a particular
soil class. With this in view, a statistical analysis was conducted in
order to evaluate the reliability of the SWCC prediction models
against laboratory measurement. Optimization techniques were used
to obtain the best-fit of the model parameters in four forms of SWCC
equation, using laboratory data for relatively coarse-textured (i.e.,
sandy) soil. The four most prominent SWCCs were evaluated and
computed for each sample. The result shows that the Brooks and
Corey model is the most consistent in describing the SWCC for sand
soil type. The Brooks and Corey model prediction also exhibit
compatibility with samples ranging from low to high soil water
content in which subjected to the samples that evaluated in this study.
Abstract: A simple, accurate and precise direct spectrophotometric method has been developed for the determination of cefixime in tablets and capsules. The method is based on the reaction of cefixime with a mixture of potassium iodide and potassium iodate to form yellow coloured product in ethanol-distilled water medium at room temperature which absorbed maximally at 352 nm. The factors affecting the reaction product were carefully studied and optimized. The validation parameters based on International Conference on Harmonisation (ICH, USA) guidelines were followed. The effect of common excipients used as additives has been tested and the tolerance limit was calculated for the determination of cefixime. Beer’s law is obeyed in the concentration range of 4 – 24 ug mL-1 with apparent molar absorptivity of 1.52 × 104 L mol-1cm-1 and Sandell’s sensitivity of 0.033 ug/cm2/ 0.001 absorbance unit. The limits of detection and quantitation for the proposed method are 0.32 and 1.06 ug mL-1, respectively. The proposed method has been successfully applied for the determination of cefixime in pharmaceutical formulations. The results obtained by the proposed method were statistically compared with the reference method using t- and F- values and found no significant difference between the two methods. The proposed method can be used as an alternate method for routine quality control analysis of cefixime in pharmaceutical formulations.
Abstract: This paper explores competencies that managers of
small firms in Ghana use to enhance operational flexibility towards
the attainment of higher productivity. This is because the requisite
competence required of such managers to be effective performers
continues to be a challenge. Data was collected from managers of
three hundred small firms using a standardized self-completion
questionnaire and analyzed using the Amos-based structural equation
model approach. Findings from factor and confirmatory factor
analyses showed that the only competence exhibited by managers
toward effective performance is realistic practices evident at the
workplace. It is concluded that a manager’s self-confidence and
involvement in areas that he/she is good at, and his/her possession of
skills that enables performance at high capacity are indications of the
manger’s effectiveness. The study outcome provides a knowledge
base helpful to policy-makers, especially in Ghana, in determining
the requisite managerial competences required by small firm
managers for effective performance.
Abstract: A total of 150 meat type chickens comprising 50 each
of Arbor Acre, Marshall and Ross were used for this study which
lasted for 10 weeks at the Federal University of Agriculture,
Abeokuta, Nigeria. Growth performance data were collected from the
third week through week 10 and data obtained were analysed using
the Generalized Linear Model Procedure. Heritability estimates (h2)
for body dimensions carried out on the chicken strains ranged from
low to high. Marshall broiler chicken strain had the highest h2 for
body weight 0.46±0.04, followed by Arbor Acre and Ross with h2
being 0.38±0.12 and 0.26±0.06, respectively. The repeatability
estimates for body weight in the three broiler strains were high, and it
ranged from 0.70 at week 4 to 0.88 at week 10. Relationships
between the body weight and linear body measurements in the broiler
chicken strains were positive and highly significant (p > 0.05).
Abstract: The high Peak to Average Power Ratio (PAR) in Filter
Bank Multicarrier with Offset Quadrature Amplitude Modulation
(FBMC-OQAM) can significantly reduce power efficiency and
performance. In this paper, we address the problem of PAPR
reduction for FBMC-OQAM systems using Tone Reservation (TR)
technique. Due to the overlapping structure of FBMCOQAM signals,
directly applying TR schemes of OFDM systems to FBMC-OQAM
systems is not effective. We improve the tone reservation (TR)
technique by employing sliding window with Active Constellation
Extension for the PAPR reduction of FBMC-OQAM signals, called
sliding window tone reservation Active Constellation Extension
(SW-TRACE) technique. The proposed SW-TRACE technique uses
the peak reduction tones (PRTs) of several consecutive data
blocks to cancel the peaks of the FBMC-OQAM signal inside a
window, with dynamically extending outer constellation points in
active(data-carrying) channels, within margin-preserving constraints,
in order to minimize the peak magnitude. Analysis and simulation
results compared to the existing Tone Reservation (TR) technique for
FBMC/OQAM system. The proposed method SW-TRACE has better
PAPR performance and lower computational complexity.
Abstract: Artificial Neural Networks (ANN) trained using backpropagation
(BP) algorithm are commonly used for modeling
material behavior associated with non-linear, complex or unknown
interactions among the material constituents. Despite multidisciplinary
applications of back-propagation neural networks
(BPNN), the BP algorithm possesses the inherent drawback of
getting trapped in local minima and slowly converging to a global
optimum. The paper present a hybrid artificial neural networks and
genetic algorithm approach for modeling slump of ready mix
concrete based on its design mix constituents. Genetic algorithms
(GA) global search is employed for evolving the initial weights and
biases for training of neural networks, which are further fine tuned
using the BP algorithm. The study showed that, hybrid ANN-GA
model provided consistent predictions in comparison to commonly
used BPNN model. In comparison to BPNN model, the hybrid ANNGA
model was able to reach the desired performance goal quickly.
Apart from the modeling slump of ready mix concrete, the synaptic
weights of neural networks were harnessed for analyzing the relative
importance of concrete design mix constituents on the slump value.
The sand and water constituents of the concrete design mix were
found to exhibit maximum importance on the concrete slump value.
Abstract: This article deals with the perceived quality of regional products in the Moravian-Silesian region in the Czech Republic. Research was focused on finding out what do consumers perceive as a quality product and what characteristics make a quality product. The data were obtained by questionnaire survey andanalysed by IBM SPSS. From the thousands of respondents the representative sample of 719 for MS region was created based on demographic factors of gender, age, education and income. The research analysis disclosed that consumers in MS region are still price oriented and that the preference of quality over price does not depend on regional brand knowledge.
Abstract: Turbulent flow in complex geometries receives considerable attention due to its importance in many engineering applications. It has been the subject of interest for many researchers. Some of these interests include the design of storm water channels. The design of these channels requires testing through physical models. The main practical limitation of physical models is the so called “scale effect”, that is, the fact that in many cases only primary physical mechanisms can be correctly represented, while secondary mechanisms are often distorted. These observations form the basis of our study, which centered on problems associated with the design of storm water channels near the Dead Sea, in Israel. To help reach a final design decision we used different physical models. Our research showed good coincidence with the results of laboratory tests and theoretical calculations, and allowed us to study different effects of fluid flow in an open channel. We determined that problems of this nature cannot be solved only by means of theoretical calculation and computer simulation. This study demonstrates the use of physical models to help resolve very complicated problems of fluid flow through baffles and similar structures. The study applies these models and observations to different construction and multiphase water flows, among them, those that include sand and stone particles, a significant attempt to bring to the testing laboratory a closer association with reality.
Abstract: A novel new vanadium (IV) complexes incorporating the chelating diamido cyclopentadienyl {ArN(CH2)3NAr)}2-((ηn-Cp)Cp)} (Ar = 2,6-Pri2C6H3)(Cp = C5H5 and n = 1,2,3,4 and 5) have been studied with calculation of the properties of species involved in various of cyclopentadienyl reaction. These were carried out under investigation of density functional theory (DFT) calculation, and comparing together. Other methods, explicitly including electron correlation, are necessary for more accurate calculations; MB3LYP (Becke) (Lee–Yang–Parr) level of theory often being used to obtain more exact results. These complexes were estimated of electronic energy for molecular system, because it accounts for all electron correlation interactions.
The optimised of [V(ArN(CH2)3NAr)2Cl(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp= C5H5) was found to be thermally more stable than others of vanadium cyclopentadienyl. In the meantime the complex [V(ArN(CH2)3NAr)2Cl(η1-Cp)] (Ar = 2,6-Pri2C6H3 and Cp= C5H5) which is showed a low thermal stability in case of the just one carbon of cyclopentadienyl can be insertion with vanadium metal centre. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis and showed the highest occupied molecular orbital (HOMO) and lowest occupied molecular orbital LUMO.
Abstract: Flanges are widely used for connecting valves, pipes and other industrial devices such as gearboxes. Method of producing a flange has a considerable impact on the manner of their involvement with the industrial engines and gearboxes. By Using die casting instead of sand casting and machining for manufacturing flanges, production speed and dimensional accuracy of the parts increases. Also, in die casting, obtained dimensions are close to final dimensions and hence the need for machining flanges after die casting process decreases which makes a significant savings in raw materials and improves the mechanical properties of flanges. In this paper, a typical die of an industrial helical gearbox flange (size ISO 50) was designed and die casting process for producing this type of flange was simulated using ProCAST software. The results of simulation were used for optimizing die design. Finally, using the results of the analysis, optimized die was built.
Abstract: Tidal power can play a vital role in integrating as new source of renewable energy to the off-grid power connection in isolated areas, namely Sandwip, in Bangladesh. It can reduce the present energy crisis and improve the social, environmental and economic perspective of Bangladesh. Tidal energy is becoming popular around the world due to its own facilities. The development of any country largely depends on energy sector improvement. Lack of energy sector is because of hampering progress of any country development, and the energy sector will be stable by only depend on sustainable energy sources. Renewable energy having environmental friendly is the only sustainable solution of secure energy system. Bangladesh has a huge potential of tidal power at different locations, but effective measures on this issue have not been considered sincerely. This paper summarizes the current energy scenario, and Bangladesh can produce power approximately 53.19 MW across the country to reduce the growing energy demand utilizing tidal energy as well as it is shown that Sandwip is highly potential place to produce tidal power, which is estimated approximately 16.49 MW by investing only US $10.37 million. Besides this, cost management for tidal power plant has been also discussed.