Preliminary Study for Separation of Heavy Rare Earth Concentrates from Egyptian Crude Monazite

Heavy rare earth (HRE) oxalate concentrates were
prepared from the Egyptian crude monazite sand (graded about 47%).
The concentrates were specified quantitatively for their constituents
of individual rare earth elements using ion chromatograph (IC) and
qualitatively by scanning electron microscope (SEM) for the other
major constituents. The 1st concentrate was composed of 10.5%
HREE where 7.25% of them represented yttrium. The 2nd concentrate
contained about 41.7% LREE, 17.5% HREE and 13.6% Th. The
LREE involved 18.3% Ce, 10.5% La and 8% Nd while the HREE
were 8.7% Y, 3.5% Gd and 2.9% Dy. The 3rd concentrate was
containing about 8.0% LREE (3.7% Ce, 2.0% La and 1.5% Nd),
10.2% HREE (6.4% yttrium and 2.0% Dy) and 2.1% uranium. The
final concentrate comprised 0.84% uranium beside iron, chromium
and traces of REE.





References:
[1] C. K. Gupta and N. Krishnamurthy, "Extractive metallurgy of rare
earths" CRC PRESS Boca Raton London New York Washington, D.C.
2005.
[2] M. I. Moustafa, "Mineralogical and geochemical studies on monazite –
Th, REE silicate series in the Egyptian beach monazite concentrate"
Sedimentology of Egypt, 2009, 17: 63.
[3] M. I. Moustafa, "Mineralogy and beneficiation of some economic
minerals in the Egyptian black sands" Ph. Thesis, Faculty of Science,
Mansoura University, Egypt, 1999.
[4] A. Humphries, "Rare Earth Elements" The global supply chain"
Congressional Research Service 7-5700, R41347, 2012.
[5] M. E. de Vasconcellos, S .M. R. da Rocha, W. R. Pedreira, C. A. da S.
Queiroz and Alc´ıdio Abr˜ao, "Enrichment of yttrium from rare earth
concentrate by ammonium carbonate leaching and peroxide
precipitation" Journal of Alloys and Compounds 418, 2006, 200–203.
[6] H. D. Drobek, "Separation of Y(III) complexes from Dy(III), Ho(III)
and Er(III) complexes with iminodiacetic acid on the anion-exchanger
type 1 and type 2" Hydrometallurgy 53, 1999, 89–100.
[7] C. K. Gupta and N. Krishnamurthy, "Extractive metallurgy of rare
earths" International Materials Reviews, 1992, 37(5): 204.
[8] W. D. Jamrack, "Rare metal extraction by chemical engineering
techniques" Porgamon Press, London, 1963.
[9] L. Stefan and A. Helmut, "Recovery of rare earth metals from waste
material by leaching in non-oxidizing acid and by precipitating using
sulphates" Patent EP 2444507 A1, 2012.
[10] R. Chi and Z. Xu, "A solution chemistry approach to the study of rare
earth element precipctation by oxalic acid" Metallurgical and Materials
Transactions B, 30, 2, p.189 – 195, 1999.
[11] Z. Liu, M. Li, Y. Hu, M. Wang and Z. Shi,; "Preparation of large particle
rare earth oxides by precipitation with oxalic acid" Journal of Rare
Earths, 26, 2, p. 158 – 162, 2008.
[12] Z. Marczenko "Rare Earths, In: Spectrophotometric determination of
elements" John Wiley and Sons Inc. New York, 1986.
[13] J. H. Yang, S. L. Dai, X. K. Pan, L. Liu, S. K. Zhou and J. S. Wang,
"Determination of uranium in ore with volumetry of H2SO4-TiCl3-
NH4VO3" Applied Mechanics and Materials, Vols. 511 – 512, 12 – 16
2014.
[14] O. S. Helaly, "Separation of cerium from Egyptian monazite sands using
solvent impregnated resin. Ph. D. Thesis, Chemical Eng. Dept., Faculty
of Eng., Cairo University, Egypt, 2011.