Abstract: This study investigated possible ways to improve the
efficiency of the platinum precipitation process using ammonium
chloride by reducing the platinum content reporting to the effluent.
The ore treated consist of five platinum group metals namely,
ruthenium, rhodium, iridium, platinum, palladium and a precious
metal gold. Gold, ruthenium, rhodium and iridium were extracted
prior the platinum precipitation process. Temperature, reducing
agent, flow rate and potential difference were the variables controlled
to determine the operation conditions for optimum platinum
precipitation efficiency. Hydrogen peroxide was added as the
oxidizing agent at the temperature of 85-90oC and potential
difference of 700-850mV was the variable used to check the
oxidizing state of platinum. The platinum was further purified at
temperature between 60-65oC, potential difference above 700 mV,
ammonium chloride of 200 l, and at these conditions the platinum
content reporting to the effluent was reduced to less than 300ppm,
resulting in optimum platinum precipitation efficiency and purity of
99.9%.
Abstract: The effect of a uniform magnetic field on the
formation of drops of specific size has been investigated numerically
in a T-shaped microchannel. Previous researches indicated that the
drop sizes of secondary stream decreases, with increasing main
stream flow rate and decreasing interfacial tension. In the present
study the effect of a uniform magnetic field on the main stream is
considered, and it is proposed that by increasing the Hartmann
number, the size of the drops of the secondary stream will be
decreased.
Abstract: The interaction of tunneling or mining with
groundwater has become a very relevant problem not only due to the
need to guarantee the safety of workers and to assure the efficiency of
the tunnel drainage systems, but also to safeguard water resources
from impoverishment and pollution risk. Therefore it is very
important to forecast the drainage processes (i.e., the evaluation of
drained discharge and drawdown caused by the excavation). The aim
of this study was to know better the system and to quantify the flow
drained from the Fontane mines, located in Val Germanasca (Turin,
Italy). This allowed to understand the hydrogeological local changes
in time. The work has therefore been structured as follows: the
reconstruction of the conceptual model with the geological,
hydrogeological and geological-structural study; the calculation of
the tunnel inflows (through the use of structural methods) and the
comparison with the measured flow rates; the water balance at the
basin scale. In this way it was possible to understand what are the
relationships between rainfall, groundwater level variations and the
effect of the presence of tunnels as a means of draining water.
Subsequently, it the effects produced by the excavation of the mining
tunnels was quantified, through numerical modeling. In particular,
the modeling made it possible to observe the drawdown variation as a
function of number, excavation depth and different mines linings.
Abstract: In the upstream we place a piece of ring and rotate
it with 83Hz, 166Hz, 333Hz,and 666H to find the effect of the
periodic distortion.In the experiment this type of the perturbation
will not allow since the mechanical failure of any parts of the
equipment in the upstream will destroy the blade system. This type of
study will be only possible by CFD. We use two pumps NS32
(ENSAM) and three blades pump (Tamagawa Univ). The benchmark
computations were performed without perturbation parts, and confirm
the computational results well agreement in head-flow rate. We
obtained the pressure fluctuation growth rate that is representing the
global instability of the turbo-system. The fluctuating torque
components were 0.01Nm(5000rpm), 0.1Nm(10000rmp),
0.04Nm(20000rmp), 0.15Nm( 40000rmp) respectively. Only for
10000rpm(166Hz) the output toque was random, and it implies that it
creates unsteady flow by separations on the blades, and will reduce the
pressure loss significantly
Abstract: Two-phase frictional pressure drop data were
obtained for condensation of carbon dioxide in single horizontal
micro tube of inner diameter ranged from 0.6 mm up to 1.6 mm over
mass flow rates from 2.5*10-5 to 17*10-5 kg/s and vapor qualities
from 0.0 to 1.0. The inlet condensing pressure is changed from 33.5
to 45 bars. The saturation temperature ranged from -1.5 oC up to 10
oC. These data have then been compared against three (two-phase)
frictional pressure drop prediction methods. The first method is by
Muller-Steinhagen and Heck (Muller-Steinhagen H, Heck K. A
simple friction pressure drop correlation for two-phase flow in pipes.
Chem. Eng. Process 1986;20:297–308) and that by Gronnerud R.
Investigation of liquid hold-up, flow-resistance and heat transfer in
circulation type evaporators, part IV: two-phase flow resistance in
boiling refrigerants, Annexe 1972. Then the method used by
FriedelL. Improved friction pressures drop in horizontal and vertical
two-phase pipe flow. European Two-Phase Flow Group Meeting,
Paper E2; 1979 June, Ispra, Italy. The methods are used by M.B Ould
Didi et al (2001) “Prediction of two-phase pressure gradients of
refrigerant in horizontal tubes". Int.J.of Refrigeration 25(2002) 935-
947. The best available method for annular flow was that of Muller-
Steinhagen and Heck. It was observed that the peak in the two-phase
frictional pressure gradient is at high vapor qualities.
Abstract: This paper is focused on issues of process modeling
and two model based control strategies of a fed-batch sugar
crystallization process applying the concept of artificial neural
networks (ANNs). The control objective is to force the operation into
following optimal supersaturation trajectory. It is achieved by
manipulating the feed flow rate of sugar liquor/syrup, considered as
the control input. The control task is rather challenging due to the
strong nonlinearity of the process dynamics and variations in the
crystallization kinetics. Two control alternatives are considered –
model predictive control (MPC) and feedback linearizing control
(FLC). Adequate ANN process models are first built as part of the
controller structures. MPC algorithm outperforms the FLC approach
with respect to satisfactory reference tracking and smooth control
action. However, the MPC is computationally much more involved
since it requires an online numerical optimization, while for the FLC
an analytical control solution was determined.
Abstract: Nowadays, a passenger car suspension must has high
performance criteria with light weight, low cost, and low energy
consumption. Pilot controlled proportional valve is designed and
analyzed to get small pressure change rate after blow-off, and to get a
fast response of the damper, a reverse damping mechanism is adapted.
The reverse continuous variable damper is designed as a HS-SH
damper which offers good body control with reduced transferred input
force from the tire, compared with any other type of suspension
system. The damper structure is designed, so that rebound and
compression damping forces can be tuned independently, of which the
variable valve is placed externally. The rate of pressure change with
respect to the flow rate after blow-off becomes smooth when the fixed
orifice size increases, which means that the blow-off slope is
controllable using the fixed orifice size. Damping forces are measured
with the change of the solenoid current at the different piston
velocities to confirm the maximum hysteresis of 20 N, linearity, and
variance of damping force. The damping force variance is wide and
continuous, and is controlled by the spool opening, of which scheme is
usually adapted in proportional valves. The reverse continuous
variable damper developed in this study is expected to be utilized in
the semi-active suspension systems in passenger cars after its
performance and simplicity of the design is confirmed through a real
car test.
Abstract: Ethanol has become more attractive in fuel industry
either as fuel itself or an additive that helps enhancing the octane
number and combustibility of gasoline. This research studied a
pressure swing adsorption using cassava-based adsorbent prepared
from mixture of cassava starch and cassava pulp for dehydration of
ethanol vapor. The apparatus used in the experiments consisted of
double adsorption columns, an evaporator, and a vacuum pump. The
feed solution contained 90-92 %wt of ethanol. Three process
variables: adsorption temperatures (110, 120 and 130°C), adsorption
pressures (1 and 2 bar gauge) and feed vapor flow rate (25, 50 and 75
% valve opening of the evaporator) were investigated. According to
the experimental results, the optimal operating condition for this
system was found to be at 2 bar gauge for adsorption pressure, 120°C
for adsorption temperature and 25% valve opening of the evaporator.
Production of 1.48 grams of ethanol with concentration higher than
99.5 wt% per gram of adsorbent was obtained. PSA with cassavabased
adsorbent reported in this study could be an alternative method
for production of nearly anhydrous ethanol. Dehydration of ethanol
vapor achieved in this study is due to an interaction between free
hydroxyl group on the glucose units of the starch and the water
molecules.
Abstract: In this paper, a set of experimental data has been used to assess the influence of abrasive water jet (AWJ) process parameters in cutting 6063-T6 aluminum alloy. The process variables considered here include nozzle diameter, jet traverse rate, jet pressure and abrasive flow rate. The effects of these input parameters are studied on depth of cut (h); one of most important characteristics of AWJ. The Taguchi method and regression modeling are used in order to establish the relationships between input and output parameters. The adequacy of the model is evaluated using analysis of variance (ANOVA) technique. In the next stage, the proposed model is embedded into a Simulated Annealing (SA) algorithm to optimize the AWJ process parameters. The objective is to determine a suitable set of process parameters that can produce a desired depth of cut, considering the ranges of the process parameters. Computational results prove the effectiveness of the proposed model and optimization procedure.
Abstract: Two commercial proteases from Bacillus
licheniformis (Alcalase 2.4 L FG and Alcalase 2.5 L, Type DX) were
screened for the production of Z-Ala-Phe-NH2 in batch reaction.
Alcalase 2.4 L FG was the most efficient enzyme for the C-terminal
amidation of Z-Ala-Phe-OMe using ammonium carbamate as
ammonium source. Immobilization of protease has been achieved by
the sol-gel method, using dimethyldimethoxysilane (DMDMOS) and
tetramethoxysilane (TMOS) as precursors (unpublished results). In
batch production, about 95% of Z-Ala-Phe-NH2 was obtained at
30°C after 24 hours of incubation. Reproducibility of different
batches of commercial Alcalase 2.4 L FG preparations was also
investigated by evaluating the amidation activity and the entrapment
yields in the case of immobilization. A packed-bed reactor (0.68 cm
ID, 15.0 cm long) was operated successfully for the continuous
synthesis of peptide amides. The immobilized enzyme retained the
initial activity over 10 cycles of repeated use in continuous reactor at
ambient temperature. At 0.75 mL/min flow rate of the substrate
mixture, the total conversion of Z-Ala-Phe-OMe was achieved after 5
hours of substrate recycling. The product contained about 90%
peptide amide and 10% hydrolysis byproduct.
Abstract: Experimental investigations were made on the instability of supercritical kerosene flowing in active cooling channels. Two approaches were used to control the pressure in the channel. One is the back-pressure valve while the other is the venturi. In both conditions, a kind of low-frequency oscillation of pressure and temperature is observed. And the oscillation periods are calculated. By comparison with the flow time, it is concluded that the instability occurred in active cooling channels is probably one kind of density wave instability. And its period has no relationship with the cooling channel geometry, nor the pressure, but only depends on the flow time of kerosene in active cooling channels. When the mass flow rate, density and pressure drop couple with each other, the density wave instability will appear.
Abstract: This paper is focused on issues of nonlinear dynamic process modeling and model-based predictive control of a fed-batch sugar crystallization process applying the concept of artificial neural networks as computational tools. The control objective is to force the operation into following optimal supersaturation trajectory. It is achieved by manipulating the feed flow rate of sugar liquor/syrup, considered as the control input. A feed forward neural network (FFNN) model of the process is first built as part of the controller structure to predict the process response over a specified (prediction) horizon. The predictions are supplied to an optimization procedure to determine the values of the control action over a specified (control) horizon that minimizes a predefined performance index. The control task is rather challenging due to the strong nonlinearity of the process dynamics and variations in the crystallization kinetics. However, the simulation results demonstrated smooth behavior of the control actions and satisfactory reference tracking.
Abstract: This paper presents the experimental as well as the
simulated performance studies on the transcritical CO2 heat pumps
for simultaneous water cooling and heating; effects of water mass
flow rates and water inlet temperatures of both evaporator and gas
cooler on the cooling and heating capacities, system COP and water
outlets temperatures are investigated. Study shows that both the
water mass flow rate and inlet temperature have significant effect on
system performances. Test results show that the effect of evaporator
water mass flow rate on the system performances and water outlet
temperatures is more pronounced (COP increases 0.6 for 1 kg/min)
compared to the gas cooler water mass flow rate (COP increases 0.4
for 1 kg/min) and the effect of gas cooler water inlet temperature is
more significant (COP decreases 0.48 for given ranges) compared to
the evaporator water inlet temperature (COP increases 0.43 for given
ranges). Comparisons of experimental values with simulated results
show the maximum deviation of 5% for cooling capacity, 10% for
heating capacity, 16% for system COP. This study offers useful
guidelines for selecting appropriate water mass flow rate to obtain
required system performance.
Abstract: In this article the investigation about installation heat
recovery steam generation (HRSG) on the exhaust of turbo generators of phases 2&3 at South Pars Gas Complex is presented.
The temperature of exhaust gas is approximately 665 degree centigrade, Installation of heat recovery boiler was simulated in
ThermoFlow 17.0.2 software, based on test operation data and the
equipments site operation conditions in Pars exclusive economical energy area, the affect of installation HRSG package on the available
gas turbine and its operation parameters, ambient temperature, the
exhaust temperatures steam flow rate were investigated. Base on the results recommended HRSG package should have the capacity for 98
ton per hour high pressure steam generation this refinery, by use of
exhaust of three gas turbines for each package in operation condition of each refinery at 30 degree centigrade. Besides saving energy this
project will be an Environment-Friendly project. The Payback Period
is estimated approximately 1.8 year, with considering Clean Development Mechanism.
Abstract: The control of oxygen flow rate during growth of
titanium dioxide by mass flow controller in DC plasma sputtering
growth system is studied. The impedance of TiO2 films for inductance
effect is influenced by annealing time and oxygen flow rate. As
annealing time is increased, the inductance of TiO2 film is the more.
The growth condition of optimum and maximum inductance for TiO2
film to serve as sensing device are oxygen flow rate of 15 sccm and
large annealing time. The large inductance of TiO2 film will be
adopted to fabricate the biosensor to obtain the high sensitivity of
sensing in biology.
Abstract: The main objective of this research is to synthesize silk fibroin fiber for indoor air particulate removal. Silk cocoons were de-gummed using 0.5 wt % Na2CO3 alkaline solutions at 90 Ó╣ìC for 60 mins, washed with distilled water, and dried at 80 Ó╣ìC for 3 hrs in a vacuum oven. Two sets of experiment were conducted to investigate the impacts of initial particulate matter (PM) concentration and that of air flow rate on the removal efficiency. Rice bran collected from a local rice mill in Ubonratchathani province was used as indoor air contaminant in this work. The morphology and physical properties of silk fibroin (SF) fiber were measured. The SEM revealed the deposition of PM on the used fiber. The PM removal efficiencies of 72.29 ± 3.03 % and 39.33 ± 1.99 % were obtained of PM10 and PM2.5, respectively, when using the initial PM concentration at 0.040 mg/m3 and 0.020 mg/m3 of PM10 and PM2.5, respectively, with the air flow rate of 5 L/min.
Abstract: In the process of polyethylene extrusion polymer
material similar to powder or granule is under compression, melting
and transmission operation and on base of special form, extrudate has
been produced. Twin-screw extruders are applicable in industries
because of their high capacity. The powder mixing with chemical
additives and melting with thermal and mechanical energy in three
zones (feed, compression and metering zone) and because of gear
pump and screw's pressure, converting to final product in latest plate.
Extruders with twin-screw and short distance between screws are
better than other types because of their high capacity and good
thermal and mechanical stress.
In this paper, process of polyethylene extrusion and various tapes
of extruders are studied. It is necessary to have an exact control on
process to producing high quality products with safe operation and
optimum energy consumption.
The granule size is depending on granulator motor speed. Results
show at constant feed rate a decrease in granule size was found whit
Increase in motor speed. Relationships between HDPE feed rate and
speed of granulator motor, main motor and gear pump are calculated
following as:
x = HDPE feed flow rate, yM = Main motor speed
yM = (-3.6076e-3) x^4+ (0.24597) x^3+ (-5.49003) x^2+ (64.22092)
x+61.66786 (1)
x = HDPE feed flow rate, yG = Gear pump speed
yG = (-2.4996e-3) x^4+ (0.18018) x^3+ (-4.22794) x^2+ (48.45536)
x+18.78880 (2)
x = HDPE feed flow rate, y = Granulator motor speed
10th Degree Polynomial Fit: y = a+bx+cx^2+dx^3... (3)
a = 1.2751, b = 282.4655, c = -165.2098,
d = 48.3106, e = -8.18715, f = 0.84997
g = -0.056094, h = 0.002358, i = -6.11816e-5
j = 8.919726e-7, k = -5.59050e-9
Abstract: In countries with hot climates, air-conditioning forms
a large proportion of annual peak electrical demand, requiring
expansion of power plants to meet the peak demand, which goes
unused most of the time. Use of well-designed cool storage can offset
the peak demand to a large extent. In this study, an air conditioning
system with naturally stratified storage tank was designed,
constructed and tested. A new type of diffuser was designed and used
in this study. Factors that influence the performance of chilled water
storage tanks were investigated. The results indicated that stratified
storage tank consistently stratified well without any physical barrier.
Investigation also showed that storage efficiency decreased with
increasing flow rate due to increased mixing of warm and chilled
water. Diffuser design and layout primarily affected the mixing near
the inlet diffuser and the extent of this mixing had primary influence
on the shape of the thermocline. The heat conduction through tank
walls and through the thermocline caused widening of mixed volume.
Thermal efficiency of stratified storage tanks was as high as 90
percent, which indicates that stratified tanks can effectively be used
as a load management technique.
Abstract: Efficient and safe plant operation can only be
achieved if the operators are able to monitor all key process
parameters. Instrumentation is used to measure many process
variables, like temperatures, pressures, flow rates, compositions or
other product properties. Therefore Performance monitoring is a
suitable tool for operators. In this paper, we integrate rigorous
simulation model, data reconciliation and parameter estimation to
monitor process equipments and determine key performance
indicator (KPI) of them. The applied method here has been
implemented in two case studies.
Abstract: In a pilot plant scale of a fluidized bed reactor, a
reduction reaction of sodium sulfate by natural gas has been
investigated. Natural gas is applied in this study as a reductant. Feed
density, feed mass flow rate, natural gas and air flow rate
(independent parameters)and temperature of bed and CO
concentration in inlet and outlet of reactor (dependent parameters)
were monitored and recorded at steady state. The residence time was
adjusted close to value of traditional reaction [1]. An artificial neural
network (ANN) was established to study dependency of yield and
carbon gradient on operating parameters. Resultant 97% accuracy of
applied ANN is a good prove that natural gas can be used as a
reducing agent. Predicted ANN model for relation between other
sources carbon gradient (accuracy 74%) indicates there is not a
meaningful relation between other sources carbon variation and
reduction process which means carbon in granule does not have
significant effect on the reaction yield.