Abstract: Two freshwater fishes, Rasbora sumatrana
(Cyprinidae) and Poecilia reticulata (guppy) (Poeciliidae) were
exposed for a four-day period in the laboratory condition to a range
of copper (Cu) and cadmium (Cd) concentrations. Mortality was
assessed and median lethal concentrations (LC50) were calculated.
LC50 increased with decrease in mean exposure times for both metals.
For R. sumatrana, LC50s for 24, 48, 72 and 96 hours for Cu were
54.2, 30.3, 18.9 and 5.6 μg/L and for Cd 1440.2, 459.3, 392.3 and
101.6 μg/L respectively. For P. reticulata, LC50s for 24, 48, 72 and
96 hours for Cu were 348.9, 145.4, 61.3 and 37.9 μg/L and for Cd
8205.6, 2827.1, 405.8 and 168.1 μg/L, respectively. Results indicated
that the Cu was more toxic than Cd to both fishes (Cu>Cd) and R.
sumatrana was more sensitive than P. reticulata to the metals.
Abstract: This paper reports the tensile fracture location
characterizations of dissimilar friction stir welds between 5754
aluminium alloy and C11000 copper. The welds were produced using
three shoulder diameter tools; namely, 15, 18 and 25 mm by varying
the process parameters. The rotational speeds considered were 600,
950 and 1200 rpm while the feed rates employed were 50, 150 and
300 mm/min to represent the low, medium and high settings
respectively. The tensile fracture locations were evaluated using the
optical microscope to identify the fracture locations and were
characterized. It was observed that 70% of the tensile samples failed
in the Thermo Mechanically Affected Zone (TMAZ) of copper at the
weld joints. Further evaluation of the fracture surfaces of the pulled
tensile samples revealed that welds with low Ultimate Tensile
Strength either have defects or intermetallics present at their joint
interfaces.
Abstract: This paper presents the results of the experimental
tests of the cooling performance of a 12,000-Btu/h modified air
conditioner (referred to as M-AC) that use the ground as a heat sink
of a condenser. In the tests, cooling capacity of M-AC with an
optimal length of a condensing coil as well as life expectancy of
copper coil buried underground were investigated. The lengths of
copper coil fabricated and used as condenser coil of M-AC were set
at 67, 50, 40 and 30 m whereas that of a 12,000-Btu/h conventional
split-type air conditioner (referred to as C-AC) was about 22 m. The
results showed that the ground can absorb heat rejected from a
condenser of M-AC. The coefficient of performance (COP) of C-AC
was about 2.5 whereas those of M-AC were found to be higher. It
was found that the values of COP of M-AC with condensing coils of
67, 50 and 40 m long were about 6.9, 5.5 and 3.3, respectively, while
that of 30-m-long one was found to be about 2.1. The electrical
consumptions of M-AC were found lower than that of C-AC in the
range of 11.5 – 15.5%. Additionally, life expectancy of underground
condensing coil of M-AC was found to be over 7 years.
Abstract: The excellent suitability of the externally excited synchronous
machine (EESM) in automotive traction drive applications
is justified by its high efficiency over the whole operation range and
the high availability of materials. Usually, maximum efficiency is
obtained by modelling each single loss and minimizing the sum of all
losses. As a result, the quality of the optimization highly depends on
the precision of the model. Moreover, it requires accurate knowledge
of the saturation dependent machine inductances. Therefore, the
present contribution proposes a method to minimize the overall losses
of a salient pole EESM and its inverter in steady state operation based
on measurement data only. Since this method does not require any
manufacturer data, it is well suited for an automated measurement
data evaluation and inverter parametrization. The field oriented control
(FOC) of an EESM provides three current components resp. three
degrees of freedom (DOF). An analytic minimization of the copper
losses in the stator and the rotor (assuming constant inductances) is
performed and serves as a first approximation of how to choose the
optimal current reference values. After a numeric offline minimization
of the overall losses based on measurement data the results are
compared to a control strategy that satisfies cos (ϕ) = 1.
Abstract: Copper sulfide nanoparticles (CuS) were successfully synthesized by the pulsed plasma in liquid method, using two copper rod electrodes submerged in molten sulfur. Low electrical energy and no high temperature were applied for synthesis. Obtained CuS nanoparticles were then analyzed by means of X-ray diffraction, Low and High Resolution Transmission Electron Microscopy, Electron Diffraction, X-ray Photoelectron, Raman Spectroscopies and Field Emission Scanning Electron Microscopy. XRD analysis revealed peaks for CuS with hexagonal phase composition. TEM and HRTEM studies showed that sizes of CuS nanoparticles ranged between 10-60 nm, with the average size of about 20 nm. Copper sulfide nanoparticles have short nanorod-like structure. Raman spectroscopy found peak for CuS at 474.2cm-1of Raman region.
Abstract: Many non-conventional adsorbent have been studied
as economic alternative to commercial activated carbon and mostly
agricultural waste have been introduced such as rubber leaf powder
and hazelnut shell. Microwave Incinerated Rice Husk Ash
(MIRHA), produced from the rice husk is one of the low-cost
materials that were used as adsorbent of heavy metal. The aim of
this research was to study the feasibility of using MIRHA500 and
MIRHA800 as adsorbent for the removal of Cu(II) metal ions from
aqueous solutions by the batch studies. The adsorption of Cu(II) into
MIRHA500 and MIRH800 favors Fruendlich isotherm and imply
pseudo – kinetic second order which applied chemisorptions
Abstract: An organic bulk heterojunction (BHJ) was fabricated using a blended film containing Copper (II) tetrakis(4-acumylphenoxy) phthalocyanine (Tc-CuPc) along with [6,6]-Phenyl C61 butyric acid methyl ester (PCBM). Weight ratio between Tc-CuPc and PCBM was 1:1. The electrical properties of Tc-CuPc: PCBM BHJ were examined. Rectifying nature of the BHJ was displayed by current-voltage (I-V) curves, recorded in dark and at various temperatures. At low voltages, conduction was ohmic succeeded by space-charge limiting current (SCLC) conduction at higher voltages in which exponential trap distribution was dominant. Series resistance, shunt resistance, ideality factor, effective barrier height and mobility at room temperature were found to be 526 4, 482 k4, 3.7, 0.17 eV and 2×10-7 cm2V-1s-1 respectively. Temperature effect towards different BHJ parameters was observed under dark condition.
Abstract: A research project dealing with the phytoremediation
of a soil polluted by some heavy metals is currently running. The
case study is represented by a mining area in Hamedan province in
the central west part of Iran. The potential of phytoextraction and
phytostabilization of plants was evaluated considering the
concentration of heavy metals in the plant tissues and also the
bioconcentration factor (BCF) and the translocation factor (TF). Also
the several established criteria were applied to define
hyperaccumulator plants in the studied area. Results showed that
none of the collected plant species were suitable for phytoextraction
of Cu, Zn, Fe and Mn, but among the plants, Euphorbia macroclada
was the most efficient in phytostabilization of Cu and Fe, while,
Ziziphora clinopodioides, Cousinia sp. and Chenopodium botrys
were the most suitable for phytostabilization of Zn and Chondrila
juncea and Stipa barbata had the potential for phytostabilization of
Mn. Using the most common criterion, Euphorbia macroclada and
Verbascum speciosum were Fe hyperaccumulator plants. Present
study showed that native plant species growing on contaminated sites
may have the potential for phytoremediation.
Abstract: To understand the material characteristics of singleand
poly-crystals of pure copper, the respective relationships between
crystallographic orientations and microstructures, and the bending
and mechanical properties were examined. And texture distribution
is also analyzed. A bending test is performed in a SEM apparatus and
while its behaviors are observed in situ. Furthermore, some
analytical results related to crystal direction maps, inverse pole
figures, and textures were obtained from EBSD analyses.
Abstract: A gold coated copper rotating electrode was used to
eliminate surface oxidation effect. This study examined the effect of
electrode rotation on the ozone generation process and showed that an
ozonizer with an electrode rotating system might be a possible way to
increase ozone-synthesis efficiency. Two new phenomena appeared
during experiments with the rotating electrode. First was that ozone
concentration increased to about two times higher than that of the case
with no rotation. Second, input power and discharge area were found
to increase with the rotation speed. Both ozone concentration and
ozone production efficiency improved in the case of rotating electrode
compared to the case with a non-rotating electrode. One possible
reason for this was the increase in discharge length of
micro-discharges during electrode rotation. The rotating electrode
decreased onset voltage, while reactor capacitance increased with
rotation. Use of a rotating-type electrode allowed earlier observation
of the ozone zero phenomena compared with a non-rotating electrode
because, during rotation, the entire electrode surface was functional,
allowing nitrogen on the electrode surface to be evenly consumed.
Nitrogen demand increased with increasing rotation s
Abstract: Simultaneous recovery of copper and DCA from
simulated MEUF concentrated stream was investigated. Effects of
surfactant (DCA) and metal (copper) concentrations, surfactant to
metal molar ratio (S/M ratio), electroplating voltage, EDTA
concentration, solution pH, and salt concentration on metal recovery
and current efficiency were studied. Electric voltage of -0.5 V was
shown to be optimum operation condition in terms of Cu recovery,
current efficiency, and surfactant recovery. Increasing Cu recovery and
current efficiency were observed with increases of Cu concentration
while keeping concentration of DCA constant. However, increasing
both Cu and DCA concentration while keeping S/M ratio constant at
2.5 showed detrimental effect on Cu recovery at DCA concentration
higher than 15 mM. Cu recovery decreases with increasing pH while
current efficiency showed an opposite trend. It is believed that
conductivity is the main cause for discrepancy of Cu recovery and
current efficiency observed at different pH. Finally, it was shown that
EDTA had adverse effect on both Cu recovery and current efficiency
while addition of NaCl salt had negative impact on current efficiency
at concentration higher than 8000 mg/L.
Abstract: The operating control parameters of injection
flushing type of electrical discharge machining process on stainless
steel 304 workpiece using copper tools are being optimized
according to its individual machining characteristic i.e. Electrode
Wear Ratio (EWR). Higher EWR would give bad dimensional
precision for the EDM machined workpiece because of high
electrode wear. Hence, the quality characteristic for EWR is set to
lower-the-better to achieve the optimum dimensional precision for
the machined workpiece. Taguchi method has been used for the
construction, layout and analysis of the experiment for EWR
machining characteristic. The use of Taguchi method in the
experiment saves a lot of time and cost of preparing and machining
the experiment samples. Therefore, an L18 Orthogonal array
which was the fundamental component in the statistical design of
experiments has been used to plan the experiments and Analysis of
Variance (ANOVA) is used to determine the optimum machining
parameters for this machining characteristic. The control
parameters selected for this optimization experiments are polarity,
pulse on duration, discharge current, discharge voltage, machining
depth, machining diameter and dielectric liquid pressure. The
result had shown that negative polarity machining parameter
setting will decreases EWR.
Abstract: The controllable electrical loss which consists of the
copper loss and iron loss can be minimized by the optimal control of
the armature current vector. The control algorithm of current vector
minimizing the electrical loss is proposed and the optimal current
vector can be decided according to the operating speed and the load
conditions. The proposed control algorithm is applied to the
experimental PM motor drive system and this paper presents a
modern approach of speed control for permanent magnet
synchronous motor (PMSM) applied for Electric Vehicle using a
nonlinear control. The regulation algorithms are based on the
feedback linearization technique. The direct component of the current
is controlled to be zero which insures the maximum torque operation.
The near unity power factor operation is also achieved. More over,
among EV-s motor electric propulsion features, the energy efficiency
is a basic characteristic that is influenced by vehicle dynamics and
system architecture. For this reason, the EV dynamics are taken into
account.
Abstract: A self-association model has been used to understand
the concentration dependence of free energy of mixing (GM), heat of
mixing (HM), entropy of mixing (SM), activity (a) and microscopic
structures, such as concentration fluctuation in long wavelength limit
(Scc(0)) and Warren-Cowley short range order parameter ( 1
α )for Cu-
Tl molten alloys at 1573K. A comparative study of surface tension of
the alloys in the liquid state at that temperature has also been carried
out theoretically as function of composition in the light of Butler-s
model, Prasad-s model and quasi-chemical approach. Most of the
computed thermodynamic properties have been found in agreement
with the experimental values. The analysis reveals that the Cu-Tl
molten alloys at 1573K represent a segregating system at all
concentrations with moderate interaction. Surface tensions computed
from different approaches have been found to be comparable to each
other showing increment with the composition of copper.
Abstract: The innovative intelligent fuzzy weighted input
estimation method (FWIEM) can be applied to the inverse heat
transfer conduction problem (IHCP) to estimate the unknown
time-varying heat flux of the multilayer materials as presented in this
paper. The feasibility of this method can be verified by adopting the
temperature measurement experiment. The experiment modular may
be designed by using the copper sample which is stacked up 4
aluminum samples with different thicknesses. Furthermore, the
bottoms of copper samples are heated by applying the standard heat
source, and the temperatures on the tops of aluminum are measured by
using the thermocouples. The temperature measurements are then
regarded as the inputs into the presented method to estimate the heat
flux in the bottoms of copper samples. The influence on the estimation
caused by the temperature measurement of the sample with different
thickness, the processing noise covariance Q, the weighting factor γ ,
the sampling time interval Δt , and the space discrete interval Δx ,
will be investigated by utilizing the experiment verification. The
results show that this method is efficient and robust to estimate the
unknown time-varying heat input of the multilayer materials.
Abstract: The high temperature degree and uniform
Temperature Distribution (TD) on surface of cookware which contact
with food are effective factors for improving cookware application.
Additionally, the ability of pan material in retaining the heat and nonreactivity
with foods are other significant properties. It is difficult for
single material to meet a wide variety of demands such as superior
thermal and chemical properties. Multi-Layer Plate (MLP) makes
more regular TD. In this study the main objectives are to find the best
structure (single or multi-layer) and materials to provide maximum
temperature degree and uniform TD up side surface of pan. And also
heat retaining of used metals with goal of improving the thermal
quality of pan to economize the energy. To achieve this aim were
employed Finite Element Method (FEM) for analyzing transient
thermal behavior of applied materials. The analysis has been
extended for different metals, we achieved the best temperature
profile and heat retaining in Copper/ Stainless Steel MLP.
Abstract: The Želazny Most tailing pond is one of the largest
facilities worldwide for waste disposal from the copper mines located
in South-West Poland. A potential failure of the dam would allow
more than 10 million cubic meters of contaminated slurry to flow to
the valley, causing immense environmental problems to the
surrounding area. Thus, the determination of the strength properties
of the dam's soils and their variability is of utmost importance.
An extensive site investigation consisting of more than 480 cone
penetration tests (CPTs) with or without pore water pressure
measurements were conducted within a period of 13 years to study
the mechanical properties of the tailings body. The present work
investigates the point variability of the soil strength parameters
(effective friction angle
Abstract: A real time image-guided electroplating system is
proposed in this paper. Unlike previous electroplating systems, instead
of using the intermittent mode to electroplate 500um long copper
specimen, a CCD camera and a motion controller are used to adjust
anode-cathode distance to obtain better results. Since the image of the
gap distance is highly deteriorated due to complex chemical-electrical
operation inside the electrolyte, to determine the gap distance, an
image processing algorithm is developed and mainly based on the
entropy and energy values. In addition, the color and incidence
direction of light source are also discussed to help the image process in
this paper. From the experiment results, the specimens created by the
proposed system show better structure, better uniformity and better
finishing surface compared to those by previous intermittent
electroplating setup.
Abstract: The paper presents coupled electromagnetic and
thermal field analysis of busbar system (of rectangular cross-section
geometry) submitted to short circuit conditions. The laboratory model
was validated against both analytical solution and experimental
observations. The considered problem required the computation of
the detailed distribution of the power losses and the heat transfer
modes. In this electromagnetic and thermal analysis, different
definitions of electric busbar heating were considered and compared.
The busbar system is a three phase one and consists of aluminum,
painted aluminum and copper busbar. The solution to the coupled
field problem is obtained using the finite element method and the
QuickField™ program. Experiments have been carried out using two
different approaches and compared with computed results.
Abstract: In this study, the designed dual stage membrane
bioreactor (MBR) system was conceptualized for the treatment of
cyanide and heavy metals in electroplating wastewater. The design
consisted of a primary treatment stage to reduce the impact of
fluctuations and the secondary treatment stage to remove the residual
cyanide and heavy metal contaminants in the wastewater under
alkaline pH conditions. The primary treatment stage contained
hydrolyzed Citrus sinensis (C. sinensis) pomace and the secondary
treatment stage contained active Aspergillus awamori (A. awamori)
biomass, supplemented solely with C. sinensis pomace extract from
the hydrolysis process. An average of 76.37%, 95.37%, 93.26 and
94.76% and 99.55%, 99.91%, 99.92% and 99.92% degradation
efficiency for total cyanide (T-CN), including the sorption of nickel
(Ni), zinc (Zn) and copper (Cu) were observed after the first and
second treatment stages, respectively. Furthermore, cyanide
conversion by-products degradation was 99.81% and 99.75 for both
formate (CHOO-) and ammonium (NH4
+) after the second treatment
stage. After the first, second and third regeneration cycles of the C.
sinensis pomace in the first treatment stage, Ni, Zn and Cu removal
achieved was 99.13%, 99.12% and 99.04% (first regeneration cycle),
98.94%, 98.92% and 98.41% (second regeneration cycle) and 98.46
%, 98.44% and 97.91% (third regeneration cycle), respectively.
There was relatively insignificant standard deviation detected in all
the measured parameters in the system which indicated
reproducibility of the remediation efficiency in this continuous
system.