Abstract: This paper presents a critical study about the
application of Neural Networks to ion-exchange process. Ionexchange
is a complex non-linear process involving many factors
influencing the ions uptake mechanisms from the pregnant solution.
The following step includes the elution. Published data presents
empirical isotherm equations with definite shortcomings resulting in
unreliable predictions. Although Neural Network simulation
technique encounters a number of disadvantages including its “black
box", and a limited ability to explicitly identify possible causal
relationships, it has the advantage to implicitly handle complex
nonlinear relationships between dependent and independent
variables. In the present paper, the Neural Network model based on
the back-propagation algorithm Levenberg-Marquardt was developed
using a three layer approach with a tangent sigmoid transfer function
(tansig) at hidden layer with 11 neurons and linear transfer function
(purelin) at out layer. The above mentioned approach has been used
to test the effectiveness in simulating ion exchange processes. The
modeling results showed that there is an excellent agreement between
the experimental data and the predicted values of copper ions
removed from aqueous solutions.
Abstract: Novel Coconut oil nanofluids of various concentrations have been prepared through ultrasonically assisted sol-gel method. The structural and morphological properties of the copper oxide nanoparticle have been analyzed with respectively and it revealed the monoclinic end-centered structure of crystallite and shuttle like flake morphology of agglomerates. Ultrasonic studies have been made for the nanofluids at different temperatures. The molecular interactions responsible for the changes in acoustical parameter with respect to concentration and temperature are discussed.
Abstract: commercially produced in Malaysia granular
palm shell activated carbon (PSAC) was biomodified with
bacterial biomass (Bacillus subtilis) to produce a hybrid
biosorbent of higher efficiency. The obtained biosorbent was
evaluated in terms of adsorption capacity to remove copper
and zinc metal ions from aqueous solutions. The adsorption
capacity was evaluated in batch adsorption experiments where
concentrations of metal ions varied from 20 to 350 mg/L. A
range of pH from 3 to 6 of aqueous solutions containing metal
ions was tested. Langmuir adsorption model was used to
interpret the experimental data. Comparison of the adsorption
data of the biomodified and original palm shell activated
carbon showed higher uptake of metal ions by the hybrid
biosorbent. A trend in metal ions uptake increase with the
increase in the solution-s pH was observed. The surface
characterization data indicated a decrease in the total surface
area for the hybrid biosorbent; however the uptake of copper
and zinc by it was at least equal to the original PSAC at pH 4
and 5. The highest capacity of the hybrid biosorbent was
observed at pH 5 and comprised 22 mg/g and 19 mg/g for
copper and zinc, respectively. The adsorption capacity at the
lowest pH of 3 was significantly low. The experimental results
facilitated identification of potential factors influencing the
adsorption of copper and zinc onto biomodified and original
palm shell activated carbon.
Abstract: The aluminum bronze matrix alumina composites using hot press and resin infiltration were investigated to study their porosities, hardness, bending strengths, and microstructures. The experiment results show that the hardness of the sintered composites with the decrease of porosity increases. The composites without and with resin infiltration have about HRF 42-61 of about 34-40% of porosity and about HRF 62-83 of about 30-36% of porosity, respectively. Besides, the alumina composites contain a more amount of iron and nickel powders would cause a lower bending strength due to forming some weaker bonding among the iron, nickel, copper, aluminum under this hot pressing of shorter time.
Abstract: Conventionally the selection of parameters depends
intensely on the operator-s experience or conservative technological
data provided by the EDM equipment manufacturers that assign
inconsistent machining performance. The parameter settings given by
the manufacturers are only relevant with common steel grades. A
single parameter change influences the process in a complex way.
Hence, the present research proposes artificial neural network (ANN)
models for the prediction of surface roughness on first commenced
Ti-15-3 alloy in electrical discharge machining (EDM) process. The
proposed models use peak current, pulse on time, pulse off time and
servo voltage as input parameters. Multilayer perceptron (MLP) with
three hidden layer feedforward networks are applied. An assessment
is carried out with the models of distinct hidden layer. Training of the
models is performed with data from an extensive series of
experiments utilizing copper electrode as positive polarity. The
predictions based on the above developed models have been verified
with another set of experiments and are found to be in good
agreement with the experimental results. Beside this they can be
exercised as precious tools for the process planning for EDM.
Abstract: The purpose of this study was to understand the main
sources of copper (Cu) accumulation in target organs of tilapia
(Oreochromis mossambicus) and to investigate how the organism
mediate the process of Cu accumulation under prolonged conditions.
By measuring both dietary and waterborne Cu accumulation and total
concentrations in tilapia with biokinetic modeling approach, we were
able to clarify the biokinetic coping mechanisms for the long term Cu
accumulation. This study showed that water and food are both the
major source of Cu for the muscle and liver of tilapia. This implied
that control the Cu concentration in these two routes will be correlated
to the Cu bioavailability for tilapia. We found that exposure duration
and level of waterborne Cu drove the Cu accumulation in tilapia. The
ability for Cu biouptake and depuration in organs of tilapia were
actively mediated under prolonged exposure conditions. Generally,
the uptake rate, depuration rate and net bioaccumulation ability in all
selected organs decreased with the increasing level of waterborne Cu
and extension of exposure duration.Muscle tissues accounted for over
50%of the total accumulated Cu and played a key role in buffering the
Cu burden in the initial period of exposure, alternatively, the liver
acted a more important role in the storage of Cu with the extension of
exposures. We concluded that assumption of the constant biokinetic
rates could lead to incorrect predictions with overestimating the
long-term Cu accumulation in ecotoxicological risk assessments.
Abstract: A new chelating resin is prepared by coupling
Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer.
The resulting sorbent has been characterized by FT-IR, elemental
analysis and thermogravimetric analysis (TGA) and studied for
preconcentrating of Cu (II) using flame atomic absorption
spectrometry (FAAS) for metal monitoring. The optimum pH value
for sorption of the copper ions was 6.5. The resin was subjected to
evaluation through batch binding of mentioned metal ion.
Quantitative desorption occurs instantaneously with 0.5 M HNO3.
The sorption capacity was found 4.8 mmol.g-1 of resin for Cu (II) in
the aqueous solution. The chelating resin can be reused for 10 cycles
of sorption-desorption without any significant change in sorption
capacity. A recovery of 99% was obtained the metal ions with 0.5 M
HNO3 as eluting agent. The method was applied for metal ions
determination from industrial waste water sample.
Abstract: Since 2005, an SRF module of CESR type serves as the
accelerating cavity at the Taiwan Light Source in the National
Synchrotron Radiation Research Center. A 500-MHz niobium cavity
is immersed in liquid helium inside this SRF module. To reduce heat
load, the liquid helium vessel is thermally shielded by
liquid-nitrogen-cooled copper layer, and the beam chambers are also
anchored with pipes of the liquid nitrogen flow in middle of the liquid
helium vessel and the vacuum vessel. A strong correlation of the
movement of the cavity-s frequency tuner with the temperature
variation of parts cooled with liquid nitrogen was observed. A
previous study on a spare SRF module with the niobium cavity cooled
by liquid nitrogen instead of liquid helium, satisfactory suppression of
the thermal oscillation was achieved by attaching a temporary buffer
tank for the vented shielding nitrogen flow from the SRF module. In
this study, a home-made buffer tank is designed and integrated to the
spare SRF module with cavity cooled by liquid helium. Design,
construction, integration, and preliminary test results of this buffer
tank are presented.
Abstract: In this work, an organic compound 5,10,15,20-
Tetrakis(3,5-di-tertbutylphenyl)porphyrinatocopper(II) (TDTBPPCu)
is studied as an active material for thin film electronic devices. To
investigate the electrical properties of TDTBPPCu, junction of
TDTBPPCu with heavily doped n-Si and Al is fabricated.
TDTBPPCu film was sandwiched between Al and n-Si electrodes.
Various electrical parameters of TDTBPPCu are determined. The
current-voltage characteristics of the junction are nonlinear,
asymmetric and show rectification behavior, which gives the clue of
formation of depletion region. This behavior indicates the potential
of TDTBPPCu for electronics applications. The current-voltage and
capacitance-voltage techniques are used to find the different
electronic parameters.
Abstract: There are few studies on eggshell of leatherback turtle
which is endangered species in Thailand. This study was focusing on
the ultrastructure and elemental composition of leatherback turtle
eggshells collected from Andaman Sea Shore, Thailand during the
nesting season using scanning electron microscope (SEM). Three
eggshell layers of leatherback turtle; the outer cuticle layer or
calcareous layer, the middle layer or middle multistrata layer and the
inner fibrous layer were recognized. The outer calcareous layer was
thick and porosity which consisted of loose nodular units of various
crystal shapes and sizes. The loose attachment between these units
resulted in numerous spaces and openings. The middle layer was
compact thick with several multistrata and contained numerous
openings connecting to both outer cuticle layer and inner fibrous
layer. The inner fibrous layer was compact and thin, and composed of
numerous reticular fibers. Energy dispersive X-ray microanalysis
detector revealed energy spectrum of X-rays character emitted from
all elements on each layer. The percentages of all elements were
found in the following order: carbon (C) > oxygen (O) > calcium
(Ca) > sulfur (S) > potassium (K) > aluminum (Al) > iodine (I) >
silicon (Si) > chlorine (Cl) > sodium (Na) > fluorine (F) >
phosphorus (P) > magnesium (Mg). Each layer consisted of high
percentage of CaCO3 (approximately 98%) implying that it was
essential for turtle embryonic development. A significant difference
was found in the percentages of Ca and Mo in the 3layers. Moreover,
transition metal, metal and toxic non-metal contaminations were
found in leatherback turtle eggshell samples. These were palladium
(Pd), molybdenum (Mo), copper (Cu), aluminum (Al), lead (Pb), and
bromine (Br). The contamination elements were seen in the outer
layers except for Mo. All elements were readily observed and
mapped using Smiling program. X-ray images which mapped the
location of all elements were showed. Calcium containing in the
eggshell appeared in high contents and was widely distributing in
clusters of the outer cuticle layer to form CaCO3 structure. Moreover,
the accumulation of Na and Cl was observed to form NaCl which was
widely distributing in 3 eggshell layers. The results from this study
would be valuable on assessing the emergent success in this
endangered species.
Abstract: The aim of this study is to compare the effect of the ultrasonic pre treatment on the removal of heavy metals (Iron, Zinc and Copper) from Acid Mine Drainage (AMD) by Denver Cell flotation. Synthetic AMD and individual metal solutions are used in the initial experiments to optimise the process conditions for real AMD. Three different process methods, ultrasound treatment followed by Denver flotation cell, Denver flotation cell alone and ultrasonic treatments run simultaneously with the Denver flotation cell were tested for every sample. Precipitation of the metal solutions by using sodium hydroxide (NaOH) and application of the optimum frother dosage followed by flotation significantly reduced the metal content of the AMD.
Abstract: In the current research, neuro-fuzzy model and regression model was developed to predict Material Removal Rate in Electrical Discharge Machining process for AISI D2 tool steel with copper electrode. Extensive experiments were conducted with various levels of discharge current, pulse duration and duty cycle. The experimental data are split into two sets, one for training and the other for validation of the model. The training data were used to develop the above models and the test data, which was not used earlier to develop these models were used for validation the models. Subsequently, the models are compared. It was found that the predicted and experimental results were in good agreement and the coefficients of correlation were found to be 0.999 and 0.974 for neuro fuzzy and regression model respectively
Abstract: The objective of present work is to stimulate the
machining of material by electrical discharge machining (EDM) to
give effect of input parameters like discharge current (Ip), pulse on
time (Ton), pulse off time (Toff) which can bring about changes in the
output parameter, i.e. material removal rate. Experimental data was
gathered from die sinking EDM process using copper electrode and
Medium Carbon Steel (AISI 1040) as work-piece. The rules of
membership function (MF) and the degree of closeness to the
optimum value of the MMR are within the upper and lower range of
the process parameters. It was found that proposed fuzzy model is in
close agreement with the experimental results. By Intelligent, model
based design and control of EDM process parameters in this study
will help to enable dramatically decreased product and process
development cycle times.
Abstract: In this study the adsorption of Cu (II) ions from aqueous solutions on synthetic zeolite NaA was evaluated. The effect of solution temperature and the determination of the kinetic parameters of adsorption of Cu(II) from aqueous solution on zeolite NaA is important in understanding the adsorption mechanism. Variables of the system include adsorption time, temperature (293- 328K), initial solution concentration and pH for the system. The sorption kinetics of the copper ions were found to be strongly dependent on pH (the optimum pH 3-5), solute ion concentration and temperature (293 – 328 K). It was found, the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Cu(II) onto ziolite NaA, suggesting that the adsorption mechanism might be a chemisorptions process The activation energy of adsorption (Ea) was determined as Cu(II) 13.5 kJ mol-1. The low value of Ea shows that Cu(II) adsorption process by zeolite NaA may be an activated chemical adsorption. The thermodynamic parameters (ΔG0, ΔH0, and ΔS0) were also determined from the temperature dependence. The results show that the process of adsorption Cu(II) is spontaneous and endothermic process and rise in temperature favors the adsorption.
Abstract: The present work is concerned with sulfidation of Cu,
Zn and Ni containing plating wastewater with CaS. The sulfidation
experiments were carried out at a room temperature by adding solid
CaS to simulated metal solution containing either single-metal of Ni,
Zn and Cu, or Ni-Zn-Cu mixture. At first, the experiments were
conducted without pH adjustment and it was found that the complete
sulfidation of Zn and Ni was achieved at an equimolar ratio of CaS to a
particular metal. However, in the case of Cu, a complete copper
sulfidation was achieved at CaS to Cu molar ratio of about 2. In the
case of the selective sulfidation, a simulated plating solution
containing Cu, Zn and Ni at the concentration of 100 mg/dm3 was
treated with CaS under various pH conditions. As a result, selective
precipitation of metal sulfides was achieved by a sulfidation treatment
at different pH values. Further, the precipitation agents of NaOH,
Na2S and CaS were compared in terms of the average specific
filtration resistance and compressibility coefficients of metal sulfide
slurry. Consequently, based on the lowest filtration parameters of the
produced metal sulfides, it was concluded that CaS was the most
effective precipitation agent for separation and recovery of Cu, Zn and
Ni.
Abstract: In this study a neural network (NN) was proposed to
predict the sorption of binary mixture of copper-cobalt ions into
clinoptilolite as ion-exchanger. The configuration of the
backpropagation neural network giving the smallest mean square
error was three-layer NN with tangent sigmoid transfer function at
hidden layer with 10 neurons, linear transfer function at output layer
and Levenberg-Marquardt backpropagation training algorithm.
Experiments have been carried out in the batch reactor to obtain
equilibrium data of the individual sorption and the mixture of coppercobalt
ions. The obtained modeling results have shown that the used
of neural network has better adjusted the equilibrium data of the
binary system when compared with the conventional sorption
isotherm models.
Abstract: Fermented cassava flours (lafun) sold in Ogun and Oyo
States of Nigeria were collected from 10 markets for a period of two
months and analysed to determine their safety status. The presence of
trace metals was due to high vehicular movement around the drying
sites and markets. Cyanide and moisture contents of samples were
also determined to assess the adequacy of fermentation and drying.
The result showed that sample OWO was found to have the highest
amount of 16.02±0.12mg/kg cyanide while the lowest was found in
sample OJO with 10.51±0.10mg/kg. The results also indicated that
sample TVE had the highest moisture content of 18.50±0.20% while
sample OWO had the lowest amount of 12.46±0.47%. Copper and
lead levels were found to be highest in TVE with values 28.10mg/kg
and 1.1mg/kg respectively, while sample BTS had the lowest values
of 20.6mg/kg and 0.05mg/kg respectively. High value of cyanide
indicated inadequate fermentation.
Abstract: An innovative tri-axes micro-power receiver is
proposed. The tri-axes micro-power receiver consists of two sets 3-D
micro-solenoids and one set planar micro-coils in which iron core is
embedded. The three sets of micro-coils are designed to be orthogonal
to each other. Therefore, no matter which direction the flux is present
along, the magnetic energy can be harvested and transformed into
electric power. Not only dead space of receiving power is mostly
reduced, but also transformation efficiency of electromagnetic energy
to electric power can be efficiently raised. By employing commercial
software, Ansoft Maxwell, the preliminary simulation results verify
that the proposed micro-power receiver can efficiently pick up the
energy transmitted by magnetic power source.
As to the fabrication process, the isotropic etching technique is
employed to micro-machine the inverse-trapezoid fillister so that the
copper wire can be successfully electroplated. The adhesion between
micro-coils and fillister is much enhanced.
Abstract: This study was carried out to evaluate concentration
of micro minerals (Zn, Fe, Mn, Cu and Se) of forages and their
distribution in fiber fraction (neutral detergent fiber/NDF and acid
detergent fiber/ADF) in South Sumatra during dry and rainy seasons.
Seven species of commonly forages namely Axonopus compressus,
Panicum maximum, Pennisetum purpuphoides, Leucaena
leucocephala, Centrocema pubescens, Calopogonium mucunoides
and Acacia mangium were collected at native pasture during rainy
and dry seasons. The results showed that micro minerals
concentration of forages and their distribution in fiber fraction varied
among species and season. In general, concentration of micro
minerals was slightly higher in rainy season compared to dry season
either in grass or legumes forages. In grass, concentration of Fe and
Mn were above the critical level, while 33.3 %, 100 % and 16.7 % of
evaluated grass were deficient in Zn, Cu and Se. Data on legume
forages show that 75 % of legumes were deficient in Zn and Mn, 62.5
% deficient in Cu and 50 % deficient in Se. There was no species of
legume deficient in Fe. Distribution of micro minerals in NDF and
ADF were also significantly affected by species and season and
depends on the kinds of element measured. Generally, micro minerals
were associated in fiber fractions much higher during dry season
compared to rainy season. Iron (Fe) and selenium (Se) in forages
were the highest elements associated in NDF and ADF, while the
lowest was found in Copper (Cu).
Abstract: The present work presents the extraction of copper(II)
from sulphuric acid solutions with Sodium diethyldithiocarbamate
(SDDT), and six different organic diluents: Dichloromethane,
Chloroform, Carbon tetrachloride, Toluene, xylene and Cyclohexane,
were tested. The pair SDDT/Chloroform showed to be the most
selective in removing the copper cations, and hence was considered
throughout the experimental study.
The effects of operating parameters such as the initial concentration
of the extracting agent, the agitation time, the agitation speed and the
acid concentration were considered.
For an initial concentration of Cu (II) of 63 ppm in a 0.5 M sulphuric
acid solution, both with a mass of the extracting agent of 20 mg, an
extraction percentage of about 97.8 % and a distribution coefficient
of 44.42 were obtained, respectively, confirming the performance
of the SDDT-Chloroform pair.