Abstract: The aim of this work is to present a low cost adsorbent
for removing toxic heavy metals from aqueous solutions. Therefore,
we are interested to investigate the efficiency of natural clay minerals
collected from south Tunisia and their modified form using sulfuric
acid in the removal of toxic metal ions: Zn(II) and Pb(II) from
synthetic waste water solutions. The obtained results indicate that
metal uptake is pH-dependent and maximum removal was detected to
occur at pH 6. Adsorption equilibrium is very rapid and it was
achieved after 90 min for both metal ions studied. The kinetics results
show that the pseudo-second-order model describes the adsorption
and the intraparticle diffusion models are the limiting step. The
treatment of natural clay with sulfuric acid creates more active sites
and increases the surface area, so it showed an increase of the
adsorbed quantities of lead and zinc in single and binary systems. The
competitive adsorption study showed that the uptake of lead was
inhibited in the presence of 10 mg/L of zinc. An antagonistic binary
adsorption mechanism was observed. These results revealed that clay
is an effective natural material for removing lead and zinc in single
and binary systems from aqueous solution.
Abstract: This study presents three different approaches to
estimate bubble point pressures for the binary system of CO2 and
ethyl palmitate fatty acid ethyl ester. The first method involves the
Peng-Robinson (PR) Equation of State (EoS) with the conventional
mixing rule of Van der Waals. The second approach involves the PR
EOS together with the Wong Sandler (WS) mixing rule, coupled with
the UNIQUAC GE model. In order to model the bubble point
pressures with this approach, the volume and area parameter for ethyl
palmitate were estimated by the Hansen group contribution method.
The last method involved the Peng-Robinson, combined with the
Wong-Sandler method, but using NRTL as the GE model. Results
using the Van der Waals mixing rule clearly indicated that this
method has the largest errors among all three methods, with errors in
the range of 3.96-6.22%. The PR-WS-UNIQUAC method exhibited
small errors, with average absolute deviations between 0.95 to 1.97
percent. The PR-WS-NRTL method led to the least errors, where
average absolute deviations ranged between 0.65-1.7%.
Abstract: A theoretical approach to consider formation of chemical compound layer at the interface between initial substances A and B due to the interfacial interaction and diffusion is developed. It is considered situation when speed of interfacial interaction is large enough and diffusion of A-atoms through AB-layer is much more then diffusion of B-atoms. Atoms from A-layer diffuse toward B-atoms and form AB-atoms on the surface of B-layer. B-atoms are assumed to be immobile. The growth kinetics of the AB-layer is described by two differential equations with non-linear coupling, producing a good fit to the experimental data. It is shown that growth of the thickness of the AB-layer determines by dependence of chemical reaction rate on reactants concentration. In special case the thickness of the AB-layer can grow linearly or parabolically depending on that which of processes (interaction or the diffusion) controls the growth. The thickness of AB-layer as function of time is obtained. The moment of time (transition point) at which the linear growth are changed by parabolic is found.
Abstract: Efficient modulo 2n+1 adders are important for
several applications including residue number system, digital signal
processors and cryptography algorithms. In this paper we present a
novel modulo 2n+1 addition algorithm for a recently represented
number system. The proposed approach is introduced for the
reduction of the power dissipated. In a conventional modulo 2n+1
adder, all operands have (n+1)-bit length. To avoid using (n+1)-bit
circuits, the diminished-1 and carry save diminished-1 number
systems can be effectively used in applications. In the paper, we also
derive two new architectures for designing modulo 2n+1 adder, based
on n-bit ripple-carry adder. The first architecture is a faster design
whereas the second one uses less hardware. In the proposed method,
the special treatment required for zero operands in Diminished-1
number system is removed. In the fastest modulo 2n+1 adders in
normal binary system, there are 3-operand adders. This problem is
also resolved in this paper. The proposed architectures are compared
with some efficient adders based on ripple-carry adder and highspeed
adder. It is shown that the hardware overhead and power
consumption will be reduced. As well as power reduction, in some
cases, power-delay product will be also reduced.
Abstract: In this paper, vapour-liquid critical locus for the
binary system acetone + chloroform was determined experimentally
over the whole range of composition. The critical property
measurements were carried out using a dynamic-synthetic apparatus,
employed in the dynamic mode. The critical points are visually
determined by observing the critical opalescence and the
simultaneous disappearance and reappearance of the meniscus in the
middle of a high-pressure view cell which withstands operations up
to 673K and 20MPa. The experimental critical points measured in
this work were compared to those available in literature.
Abstract: In this study a neural network (NN) was proposed to
predict the sorption of binary mixture of copper-cobalt ions into
clinoptilolite as ion-exchanger. The configuration of the
backpropagation neural network giving the smallest mean square
error was three-layer NN with tangent sigmoid transfer function at
hidden layer with 10 neurons, linear transfer function at output layer
and Levenberg-Marquardt backpropagation training algorithm.
Experiments have been carried out in the batch reactor to obtain
equilibrium data of the individual sorption and the mixture of coppercobalt
ions. The obtained modeling results have shown that the used
of neural network has better adjusted the equilibrium data of the
binary system when compared with the conventional sorption
isotherm models.