Abstract: The photoluminescence (PL) at 1.55 μm from
semiconducting β-FeSi2 has attracted a noticeable interest for
silicon-based optoelectronic applications. Moreover, its high optical
absorption coefficient (higher than 105 cm-1 above 1.0 eV) allows this
semiconducting material to be used as photovoltanics devices.
A clear PL spectrum for β-FeSi2 was observed by Cu or Au coating
on Si(001). High-crystal-quality β-FeSi2 with a low-level nonradiative
center was formed on a Cu- or Au- reated Si layer. This method of
deposition can be applied to other materials requiring high crystal
quality.
Abstract: Commercial hydroxyapatite (HA) was reinforced by
adding 2, 5, and 10 wt % of 28.5%CaO-28.5%P2O5-38%Na2 O-
5%CaF2 based glass and then sintered. Although HA shows good
biocompatibility with the human body, its applications are limited to
non load-bearing areas and coatings due to its poor mechanical
properties. These mechanical properties can be improved
substantially with addition of glass ceramics by sintering. In this
study, the effects of sintering hydroxyapatite with above specified
phosphate glass additions are quantified. Each composition was
sintered over a range of temperatures. Scanning electron microscopy
and x-ray diffraction were used to characterize the microstructure and
phases of the composites. The density, microhardness, and
compressive strength were measured using Archimedes Principle,
Vickers Microhardness Tester (at 0.98 N), and Instron Universal
Testing Machine (cross speed of 0.5 mm/min) respectively. These
results were used to indicate which composition provided suitable
material for use in hard tissue replacement. Composites containing 10
wt % glass additions formed dense HA/TCP (tricalcium phosphate)
composite materials possessing good compressive strength and
hardness than HA. In-vitro bioactivity was assessed by evaluating
changes in pH and Ca2+ ion concentration of SBF-simulated body
fluid on immersion of these composites in it for two weeks.
Abstract: Controlled release urea has become popular in agricultural industry as it helps to solve environmental issues and increase crop yield. Recently biomass was identified to replace the polymer used as a coating material in the conventional coated urea. In this paper spreading and contact angle of biomass droplet (lignin, cellulose and clay) on urea surface are investigated experimentally. There were two tests were conducted, sessile drop for contact angle measurement and pendant drop for contact angle measurement. A different concentration of biomass droplet was released from 30 mm above a substrate. Glass was used as a controlled substrate. Images were recorded as soon as the droplet impacted onto the urea before completely adsorb into the urea. Digitized droplets were then used to identify the droplet-s surface tension and contact angle. There is large difference observed between the low surface tension and high surface tension liquids, where the wetting and spreading diameter is higher for lower surface tension. From the contact angle results, the data showed that the biomass coating films were possible as wetting liquid (θ < 90º). Contact angle of biomass coating material gives good indication for the wettablity of a liquid on urea surface.
Abstract: An organic bulk heterojunction (BHJ) was fabricated using a blended film containing Copper (II) tetrakis(4-acumylphenoxy) phthalocyanine (Tc-CuPc) along with [6,6]-Phenyl C61 butyric acid methyl ester (PCBM). Weight ratio between Tc-CuPc and PCBM was 1:1. The electrical properties of Tc-CuPc: PCBM BHJ were examined. Rectifying nature of the BHJ was displayed by current-voltage (I-V) curves, recorded in dark and at various temperatures. At low voltages, conduction was ohmic succeeded by space-charge limiting current (SCLC) conduction at higher voltages in which exponential trap distribution was dominant. Series resistance, shunt resistance, ideality factor, effective barrier height and mobility at room temperature were found to be 526 4, 482 k4, 3.7, 0.17 eV and 2×10-7 cm2V-1s-1 respectively. Temperature effect towards different BHJ parameters was observed under dark condition.
Abstract: The purpose of this research is to reduce the amount of incomplete coating of stainless steel washers in the electrodeposition painting process by using an experimental design technique. The surface preparation was found to be a major cause of painted surface quality. The influence of pretreating and painting process parameters, which are cleaning time, chemical concentration and shape of hanger were studied. A 23 factorial design with two replications was performed. The analysis of variance for the designed experiment showed the great influence of cleaning time and shape of hanger. From this study, optimized cleaning time was determined and a newly designed electrical conductive hanger was proved to be superior to the original one. The experimental verification results showed that the amount of incomplete coating defects decreased from 4% to 1.02% and operation cost decreased by 10.5%.
Abstract: A scaffold is necessary for tooth regeneration because of its three-dimensional geometry. For restoration of defect, it is necessary for the scaffold to be prepared in the shape of the defect. Sponges made from polyvinyl alcohol with formalin cross-linking (PVF sponge) have been used for scaffolds for bone formation in vivo. To induce osteogenesis within the sponge, methods of growing rat bone marrow cells (rBMCs) among the fiber structures in the sponge might be considered. Storage of rBMCs among the fibers in the sponge coated with dextran (10 kDa) was tried. After seeding of rBMCs to PVF sponge immersed in dextran solution at 2 g/dl concentration, osteogenesis was recognized in subcutaneously implanted PVF sponge as a scaffold in vivo. The level of osteocalcin was 25.28±5.71 ng/scaffold and that of Ca was 129.20±19.69 µg/scaffold. These values were significantly higher than those in sponges without dextran coating (p
Abstract: This paper presents a comparative study on
Vanadyl Phthalocyanine (VOPc) thin films deposited by thermal
evaporation and spin coating techniques. The samples
were prepared on cleaned glass substrates and annealed at
various temperatures ranging form 95oC to 155oC. To obtain
the morphological and structural properties of VOPc thin
films, X-ray diffraction (XRD) technique and atomic force
microscopy (AFM) have been implied. The AFM topographic
images show a very slight difference in the thermally grown
films, before and after annealing, however best results are
achieved for the spin-cast film annealed at 125oC. The XRD
spectra show no existence of the sharp peaks, suggesting the
material to be amorphous. The humps in the XRD patterns
indicate the presence of some crystallites.
Abstract: In recent times there has been a growing interest in the
development of quasi-two-dimensional niobium pentoxide (Nb2O5)
as a semiconductor for the potential electronic applications such as
capacitors, filtration, dye-sensitised solar cells and gas sensing
platforms. Therefore once the purpose is established, Nb2O5 can be
prepared in a number of nano- and sub-micron-structural
morphologies that include rods, wires, belts and tubes. In this study
films of Nb2O5 were prepared on gold plated silicon substrate using
spin-coating technique and subsequently by mechanical exfoliation.
The reason this method was employed was to achieve layers of less
than 15nm in thickness. The sintering temperature of the specimen
was 800oC. The morphology and structural characteristics of the
films were analyzed by Atomic Force Microscopy (AFM), Raman
Spectroscopy, X-ray Photoelectron Spectroscopy (XPS).
Abstract: Vickers indentation is used to measure the hardness
of materials. In this study, numerical simulation of Vickers
indentation experiment was performed for Diamond like Carbon
(DLC) coated materials. DLC coatings were deposited on stainless
steel 304 substrates with Chromium buffer layer using RF Magnetron
and T-shape Filtered Cathodic Vacuum Arc Dual system The
objective of this research is to understand the elastic plastic
properties, stress strain distribution, ring and lateral crack growth and
propagation, penetration depth of indenter and delamination of
coating from substrate with effect of buffer layer thickness. The
effect of Poisson-s ratio of DLC coating was also analyzed. Indenter
penetration is more in coated materials with thin buffer layer as
compared to thicker one, under same conditions. Similarly, the
specimens with thinner buffer layer failed quickly due to high
residual stress as compared to the coated materials with reasonable
thickness of 200nm buffer layer. The simulation results suggested the
optimized thickness of 200 nm among the prepared specimens for
durable and long service.
Abstract: Evaluation of contact pressure, surface and
subsurface contact stresses are essential to know the functional
response of surface coatings and the contact behavior mainly depends
on surface roughness, material property, thickness of layer and the
manner of loading. Contact parameter evaluation of real rough
surface contacts mostly relies on statistical single asperity contact
approaches. In this work, a three dimensional layered solid rough
surface in contact with a rigid flat is modeled and analyzed using
finite element method. The rough surface of layered solid is
generated by FFT approach. The generated rough surface is exported
to a finite element method based ANSYS package through which the
bottom up solid modeling is employed to create a deformable solid
model with a layered solid rough surface on top. The discretization
and contact analysis are carried by using the same ANSYS package.
The elastic, elastoplastic and plastic deformations are continuous in
the present finite element method unlike many other contact models.
The Young-s modulus to yield strength ratio of layer is varied in the
present work to observe the contact parameters effect while keeping
the surface roughness and substrate material properties as constant.
The contacting asperities attain elastic, elastoplastic and plastic states
with their continuity and asperity interaction phenomena is inherently
included. The resultant contact parameters show that neighboring
asperity interaction and the Young-s modulus to yield strength ratio
of layer influence the bulk deformation consequently affect the
interface strength.
Abstract: Inthis paper, design and fabrication of vertical
micromirror for optical switching applications of single mode optical
fibers are proposed. The structure of micromirror will be created
from negative photoresist (SU-8) on X-ray lithography using X-ray
from synchrotron light source. The properties of X-ray from
synchrotron light source are high-energy electrons which can
construct materials that have a high aspect ratio. In addition, the
technique of gold coating of reflective material has been used for
change direction of light between two pairs of optical fibers. At a
wavelength of 1310 nm with minimum average loss of 5.305 dB is
obtained.
Abstract: In this paper, we proposed the effects of Mo thickness
on the properties of AZO/Mo/AZO multilayer thin films for
opto-electronics applications. The structural, optical and electrical
properties of AZO/Mo/AZO thin films were investigated.
Optimization of the thin films coatings resulted with low resistivity of
9.98 × 10-5 )-cm, mobility of 12.75 cm2/V-s, carrier concentration of
1.05 × 1022 cm-3, maximum transmittance of 79.13% over visible
spectrum of 380 – 780 nm and Haacke figure of merit (FOM) are 5.95
× 10-2 )-1 under Mo layer thickness of 15 nm. These results indicate an
alternative candidate for use as a transparent electrode in solar cells
and various displays applications.
Abstract: Spent petroleum catalyst from Korean petrochemical
industry contains trace amount of metals such as Ni, V and Mo.
Therefore an attempt was made to recover those trace metal using
bioleaching process. Different leaching parameters such as Fe(II)
concentration, pulp density, pH, temperature and particle size of
spent catalyst particle were studied to evaluate their effects on the
leaching efficiency. All the three metal ions like Ni, V and Mo
followed dual kinetics, i.e., initial faster followed by slower rate. The
percentage of leaching efficiency of Ni and V were higher than Mo.
The leaching process followed a diffusion controlled model and the
product layer was observed to be impervious due to formation of
ammonium jarosite (NH4)Fe3(SO4)2(OH)6. In addition, the lower
leaching efficiency of Mo was observed due to a hydrophobic coating
of elemental sulfur over Mo matrix in the spent catalyst.
Abstract: A specially designed flat plate was mounted vertically
over the axial line in the wind tunnel of the Aerospace Department of
the Pusan National University. The plate is 2 m long, 0.8 m high and 8
cm thick. The measurements were performed in velocity range from
15 to 60 m/s. A sand paper turbulizer was placed close to the plate nose
to provide fully developed turbulent boundary layer over the most part
of the plate. Strain balances were mounted in the trailing part of the
plate to measure the skin friction drag over removable insertions of
0.55×0.25m2 size. A set of the insertions was designed and
manufactured: 3mm thick polished metal surface and three compliant
surfaces. The compliant surfaces were manufactured of a silicone
rubber Silastic® S2 (Dow Corning company). To modify the
viscoelastic properties of the rubber, its composition was varied: 90%
of the rubber + 10% catalyst (standard), 92.5% + 7.5% (weak), 85% +
15% (strong). Modulus of elasticity and the loss tangent were
measured accurately for these materials in the frequency range from
40 Hz to 3 KHz using the unique proposed technique.
Abstract: Tungsten trioxide has been prepared by using P-PTA
as a precursor on alumina substrates by spin coating method.
Palladium introduced on WO3 film via electrolysis deposition by
using palladium chloride as catalytic precursor. The catalytic
precursor was introduced on the series of films with different
morphologies. X-ray diffractometry (XRD), Scanning electron
microscopy (SEM) and XPS were applied to analyze structure and
morphology of the fabricated thin films. Then we measured variation
of samples- electrical conductivity of pure and Pd added films in air
and diluted hydrogen. Addition of Pd resulted in a remarkable
improvement of the hydrogen sensing properties of WO3 by detection
of Hydrogen below 1% at room temperature. Also variation of the
electrical conductivity in the presence of diluted hydrogen revealed
that response of samples depends rather strongly on the palladium
configuration on the surface.
Abstract: Semiconductor materials with coatings have a wide range of applications in MEMS and NEMS. This work uses transfermatrix method for calculating the radiative properties. Dopped silicon is used and the coherent formulation is applied. The Drude model for the optical constants of doped silicon is employed. Results showed that for the visible wavelengths, more emittance occurs in greater concentrations and the reflectance decreases as the concentration increases. In these wavelengths, transmittance is negligible. Donars and acceptors act similar in visible wavelengths. The effect of wave interference can be understood by plotting the spectral properties such as reflectance or transmittance of a thin dielectric film versus the film thickness and analyzing the oscillations of properties due to constructive and destructive interferences. But this effect has not been shown at visible wavelengths. At room temperature, the scattering process is dominated by lattice scattering for lightly doped silicon, and the impurity scattering becomes important for heavily doped silicon when the dopant concentration exceeds1018cm-3 .
Abstract: PDMS (Polydimethylsiloxane) polymer is a suitable material for biological and MEMS (Microelectromechanical systems) designers, because of its biocompatibility, transparency and high resistance under plasma treatment. PDMS round channel is always been of great interest due to its ability to confine the liquid with membrane type micro valves. In this paper we are presenting a very simple way to form round shapemicrofluidic channel, which is based on reflow of positive photoresist AZ® 40 XT. With this method, it is possible to obtain channel of different height simply by varying the spin coating parameters of photoresist.
Abstract: In turning hardened steel, polycrystalline cubic boron
nitride (cBN) compacts are widely used, due to their higher hardness
and higher thermal conductivity. However, in milling hardened steel,
fracture of cBN cutting tools readily occurs because they have poor
fracture toughness. Therefore, coated cemented carbide tools, which
have good fracture toughness and wear resistance, are generally
widely used. In this study, hardened steel (ASTM D2, JIS SKD11,
60HRC) was milled with three physical vapor deposition
(PVD)-coated cemented carbide end mill cutters in order to determine
effective tool materials for cutting hardened steel at high cutting
speeds. The coating films used were (Ti,W)N/(Ti,W,Si)N and
(Ti,W)N/(Ti,W,Si,Al)N coating films. (Ti,W,Si,Al)N is a new type of
coating film. The inner layer of the (Ti,W)N/(Ti,W,Si)N and
(Ti,W)N/(Ti,W,Si,Al)N coating system is (Ti,W)N coating film, and
the outer layer is (Ti,W,Si)N and (Ti,W,Si,Al)N coating films,
respectively. Furthermore, commercial (Ti,Al)N-based coating film
was also used. The following results were obtained: (1) In milling
hardened steel at a cutting speed of 3.33 m/s, the tool wear width of the
(Ti,W)N/(Ti,W,Si,Al)N-coated tool was smaller than that of the
(Ti,W)N/(Ti,W,Si)N-coated tool. And, compared with the commercial
(Ti,Al)N, the tool wear width of the (Ti,W)N/(Ti,W,Si,Al)N-coated
tool was smaller than that of the (Ti,Al)N-coated tool. (2) The tool
wear of the (Ti,W)N/(Ti,W,Si,Al)N-coated tool increased with an
increase in cutting speed. (3) The (Ti,W)N/(Ti,W,Si,Al)N-coated
cemented carbide was an effective tool material for high-speed cutting
below a cutting speed of 3.33 m/s.
Abstract: Reciprocating compressors are flexible to handle wide capacity and condition swings, offer a very efficient method of compressing almost any gas mixture in wide range of pressure, can generate high head independent of density, and have numerous applications and wide power ratings. These make them vital component in various units of industrial plants. In this paper optimum reciprocating compressor configuration regarding interstage pressures, low suction pressure, non-lubricated cylinder, speed of machine, capacity control system, compressor valve, lubrication system, piston rod coating, cylinder liner material, barring device, pressure drops, rod load, pin reversal, discharge temperature, cylinder coolant system, performance, flow, coupling, special tools, condition monitoring (including vibration, thermal and rod drop monitoring), commercial points, delivery and acoustic conditions are presented.