Abstract: Solid-state hydrogen storage using catalytically-modified porous silicon can be rapidly charged at moderate pressures (8 bar) without exothermic runaway. Discharge requires temperatures of approximately 110oC, so for larger storage vessels a means is required for thermal energy to penetrate bulk storage media. This can be realized with low-density metal foams, such as Celmet™. This study explores several material and dimensional choices of the metal foam to produce rapid heating of bulk silicon particulates. Experiments run under vacuum and in a pressurized hydrogen environment bracket conditions of empty and full hydrogen storage vessels, respectively. Curve-fitting of the heating profiles at various distances from an external heat source is used to derive both a time delay and a characteristic time constant. System performance metrics of a hydrogen storage subsystem are derived from the experimental results. A techno-economic analysis of the silicon and metal foam provides comparison with other methods of storing hydrogen for mobile and portable applications.
Abstract: This study presents how to use a high-efficiency process for producing cesium iodide (CsI) crystal columns by rapid heating method. In the past, the heating rate of the resistance wire heating furnace was relatively slow and excessive iodine and CsI vapors were therefore generated during heating. Because much iodine and CsI vapors are produced during heating process, the composition of CsI crystal columns is not correct. In order to enhance the heating rate, making CsI material in the heating process can quickly reach the melting point temperature. This study replaced the traditional type of external resistance heating furnace with halogen-type quartz heater, and then, CsI material can quickly reach the melting point. Eventually, CsI melt can solidify in the anodic aluminum template forming CsI crystal columns.
Abstract: The previous researches focused on the influence of
anthropogenic greenhouse gases exerting global warming, but not
consider whether desert sand may warm the planet, this could be
improved by accounting for sand's physical and geometric properties.
Here we show, sand particles (because of their geometry) at the desert
surface form an extended surface of up to 1 + π/4 times the planar area
of the desert that can contact sunlight, and at shallow depths of the
desert form another extended surface of at least 1 + π times the planar
area that can contact air. Based on this feature, an enhanced heat
exchange system between sunlight, desert sand, and air in the spaces
between sand particles could be built up automatically, which can
increase capture of solar energy, leading to rapid heating of the sand
particles, and then the heating of sand particles will dramatically heat
the air between sand particles. The thermodynamics of deserts may
thus have contributed to global warming, especially significant to
future global warming if the current desertification continues to
expand.