Abstract: Environmental and sustainability concerns push the industries to manufacture alternative materials having less environmental impact. The Wood Plastic Composites (WPCs) produced by blending the biopolymers and natural fillers permit not only to tailor the desired properties of materials but also are the solution to meet the environmental and sustainability requirements. This work presents the elaboration and characterization of the fully green WPCs prepared by blending a biopolymer, BIOPLAST® GS 2189 and spruce sawdust used as filler with different amounts. Since both components are bio-based, the resulting material is entirely environmentally friendly. The mechanical, thermal, structural properties of these WPCs were characterized by different analytical methods like tensile, flexural and impact tests, Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC) and X-ray Diffraction (XRD). Their water absorption properties and resistance to the termite and fungal attacks were determined in relation with different wood filler content. The tensile and flexural moduli of WPCs increased with increasing amount of wood fillers into the biopolymer, but WPCs became more brittle compared to the neat polymer. Incorporation of spruce sawdust modified the thermal properties of polymer: The degradation, cold crystallization, and melting temperatures shifted to higher temperatures when spruce sawdust was added into polymer. The termite, fungal and water absorption resistance of WPCs decreased with increasing wood amount in WPCs, but remained in durability class 1 (durable) concerning fungal resistance and quoted 1 (attempted attack) in visual rating regarding to the termites resistance except that the WPC with the highest wood content (30 wt%) rated 2 (slight attack) indicating a long term durability. All the results showed the possibility to elaborate the easy injectable composite materials with adjustable properties by incorporation of BIOPLAST® GS 2189 and spruce sawdust. Therefore, lightweight WPCs allow both to recycle wood industry byproducts and to produce a full ecologic material.
Abstract: This work aims to investigate the structure–property
relationship in ternary nanocomposites consisting of polypropylene
as the matrix, polyamide 66 as the minor phase and treated nanoclay
DELLITE 67G as the reinforcement. All PP/PA66/Nanoclay systems
with polypropylene grafted maleic anhydride PP-g-MAH as a
compatibilizer were prepared via melt compounding and
characterized in terms of nanoclay content. Morphological structure
was investigated by scanning electron microscopy. The rheological
behavior of the nanocomposites was determined by various methods,
viz melt flow index (MFI) and parallel plate rheological
measurements. The PP/PP-g-MAH/PA66 nanocomposites showed a homogeneous
morphology supporting the compatibility improvement between PP,
PA66, and nanoclay. SEM results revealed the formation of
nanocomposites as the nanoclay was intercalated and exfoliated. In
the ternary nanocomposites, the rheological behavior showed that, the
complex viscosity is increased with increasing the nanoclay. The results showed that the use of nanoclay affects the variations
of storage modulus (G′), loss modulus (G″) and the melt elasticity.
Abstract: In this study, tapioca starch, which acts as natural polymer, was added in the blend in order to produce biodegradable product. Low density polyethylene (LDPE) and tapioca starch blends were prepared by extrusion and the test sample by injection moulding process. Ethylene vinyl acetate (EVA) acts as compatibilizer while glycerol as processing aid was added in the blend. The blends were characterized by using melt flow index (MFI), fourier transform infrared (FTIR) and the effects of water absorption to the sample. As the starch content increased, MFI of the blend was decreased. Tensile testing were conducted shows the tensile strength and elongation at break decreased while the modulus increased as the starch increased. For the biodegradation, soil burial test was conducted and the loss in weight was studied as the starch content increased. Morphology studies were conducted in order to show the distribution between LDPE and starch.