Abstract: The accumulation of heavy metals in food is a constant problem in many parts of the world. Vegetable oils are widely used, both for cooking and for processing in the food industry, meeting the main dietary requirements. One of the main chemical pollutants, heavy metals, is usually found in vegetable oils. These chemical pollutants are carcinogenic, teratogenic and immunotoxic, harmful to consumption and have a negative effect on human health even in trace amounts. Residues of these substances can easily accumulate in vegetable oil during cultivation, processing and storage. In this article, the content of the concentration of heavy metal ions in vegetable oils of Kazakhstan production is studied: sunflower, rapeseed, safflower and linseed oil. Heavy metals: arsenic, cadmium, lead and nickel, were determined in three repetitions by the method of flame atomic absorption. Analysis of vegetable oil samples revealed that the largest lead contamination (Pb) was determined to be 0.065 mg/kg in linseed oil. The content of cadmium (Cd) in the largest amount of 0.009 mg/kg was found in safflower oil. Arsenic (As) content was determined in rapeseed and safflower oils at 0.003 mg/kg, and arsenic (As) was not detected in linseed and sunflower oil. The nickel (Ni) content in the largest amount of 0.433 mg/kg was in linseed oil. The heavy metal contents in the test samples complied with the requirements of regulatory documents for vegetable oils. An assessment of the health risk of vegetable oils with a daily consumption of 36 g per day shows that all samples of vegetable oils produced in Kazakhstan are safe for consumption. But further monitoring is needed, since all these metals are toxic and their harmful effects become apparent only after several years of exposure.
Abstract: Objectives/Hypotheses: The adverse health effect potential of dietary lipid oxidation products (LOPs) has evoked much clinical interest. Therefore, we employed a 1H NMR-linked Principal Component Regression (PCR) chemometrics modelling strategy to explore relationships between data matrices comprising (1) aldehydic LOP concentrations generated in culinary oils/fats when exposed to laboratory-simulated shallow frying practices, and (2) the prior saturated (SFA), monounsaturated (MUFA) and polyunsaturated fatty acid (PUFA) contents of such frying media (FM), together with their heating time-points at a standard frying temperature (180 oC). Methods: Corn, sunflower, extra virgin olive, rapeseed, linseed, canola, coconut and MUFA-rich algae frying oils, together with butter and lard, were heated according to laboratory-simulated shallow-frying episodes at 180 oC, and FM samples were collected at time-points of 0, 5, 10, 20, 30, 60, and 90 min. (n = 6 replicates per sample). Aldehydes were determined by 1H NMR analysis (Bruker AV 400 MHz spectrometer). The first (dependent output variable) PCR data matrix comprised aldehyde concentration scores vectors (PC1* and PC2*), whilst the second (predictor) one incorporated those from the fatty acid content/heating time variables (PC1-PC4) and their first-order interactions. Results: Structurally complex trans,trans- and cis,trans-alka-2,4-dienals, 4,5-epxy-trans-2-alkenals and 4-hydroxy-/4-hydroperoxy-trans-2-alkenals (group I aldehydes predominantly arising from PUFA peroxidation) strongly and positively loaded on PC1*, whereas n-alkanals and trans-2-alkenals (group II aldehydes derived from both MUFA and PUFA hydroperoxides) strongly and positively loaded on PC2*. PCR analysis of these scores vectors (SVs) demonstrated that PCs 1 (positively-loaded linoleoylglycerols and [linoleoylglycerol]:[SFA] content ratio), 2 (positively-loaded oleoylglycerols and negatively-loaded SFAs), 3 (positively-loaded linolenoylglycerols and [PUFA]:[SFA] content ratios), and 4 (exclusively orthogonal sampling time-points) all powerfully contributed to aldehydic PC1* SVs (p 10-3 to < 10-9), as did all PC1-3 x PC4 interaction ones (p 10-5 to < 10-9). PC2* was also markedly dependent on all the above PC SVs (PC2 > PC1 and PC3), and the interactions of PC1 and PC2 with PC4 (p < 10-9 in each case), but not the PC3 x PC4 contribution. Conclusions: NMR-linked PCR analysis is a valuable strategy for (1) modelling the generation of aldehydic LOPs in heated cooking oils and other FM, and (2) tracking their unsaturated fatty acid (UFA) triacylglycerol sources therein.
Abstract: Increased energy demand and the concern about
environment friendly technology, renewable bio-fuels are better
alternative to petroleum products. In the present study linseed oil was
used as alternative source for diesel engine fuel and the results were
compared with baseline data of neat diesel. Performance parameters
such as brake thermal efficiency (BTE) and brake specific fuel
consumption (BSFC) and emissions parameters such as CO,
unburned hydro carbon (UBHC), NOx, CO2 and exhaust temperature
were compared. BTE of the engine was lower and BSFC was higher
when the engine was fueled with Linseed oil compared to diesel fuel.
Emission characteristics are better than diesel fuel. NOx formation by
using linseed oil during the experiment was lower than diesel fuel.
Linseed oil is non edible oil, so it can be used as an extender of diesel
fuel energy source for small and medium energy needs.
Abstract: Theexperiment was carried out with 2x5 male Merino
lambs raised under intensive conditions to investigate the effect of
dietary calcium soap of linseed oil on the color and fatty acid
composition of longissimusdorsi muscle. Control lambs fed a basal
diet and the experimental lambs consumed a diet supplemented with
3% calcium soap of linseed oil. The color values (L*, a*, b* a*/b*
and chroma) were not influenced by dietary treatment. The MUFA
proportion reduced, SFA and PUFA content did not alter. As
expected, the linolenic (C18:3 n3) and thusthe n-3 content
significantly improved by linseed supplement (0.47 and 0.81; 0.78
and 1.16 in control and in experimental samples, respectively). Other
n-3 and n-6 fatty acids had similar valuestocontrol samples. The n-
6/n-3 ratio was significantly narrower in the experimental group (6.31
vs. 9.38) but the P/S ratio did not differ betweenthe two groups.In
conclusion calcium soap of linseed oil seems to be a suitable
supplement form of n-3 fatty acids to improve the nutritive value of
lamb meat.
Abstract: Evaluation of crop plants resistance to environmental
stresses specially in germination stage is a critical factor in their
selection in different conditions of cultivation. Therefore use of a
procedure in controllable situation can help to evaluate plants
reaction to stress quickly and precisely. In order to study germination
characteristics of flax in water and salinity stress conditions were
conducted two laboratories experimental. The two experimental were
conducted in 4-replicant completing random design for salinity and
water stress. The treatment, for salinity and water stress was three
potential (zero, 40, 80 mM) of NaCl and three potential (zero, -2, -4
bar) of PEG respectively. Germination percentage and rate, in
addition to Radical and plumule length and dry-weight and
plumule/Radical ration were measured. All of characteristics reduce
under water stress conditions. salinity stress significant reduce
germination rate and Radical and plumule length of flax seeds.
Hydropriming and osmopriming significant increased germination
rate, plumule length and plumule/Radical ration ration of flax seeds.
But germination percentage and Radical and plumule dry weight
significant increased only in hydropriming treat. Hydropriming and
osmopriming could not be used to improved germination under saline
and drought stress. But has more tolerance in salinity and drought
stress in flax by less reduce in Radical and plumule length under
saline and drought stress.