Abstract: The Niger Delta Region of Nigeria is home to about
20 million people and 40 different ethnic groups. The region has an
area of seventy thousand square kilometers (70,000 KM2) of
wetlands, formed primarily by sediments deposition and makes up
7.5 percent of Nigeria's total landmass. The notable ecological zones
in this region includes: coastal barrier islands; mangrove swamp
forests; fresh water swamps; and lowland rainforests. This incredibly
naturally-endowed ecosystem region, which contains one of the
highest concentrations of biodiversity on the planet, in addition to
supporting abundant flora and fauna, is threatened by the inhuman act
known as gas flaring. Gas flaring is the combustion of natural gas
that is associated with crude oil when it is pumped up from the
ground. In petroleum-producing areas such as the Niger Delta region
of Nigeria where insufficient investment was made in infrastructure
to utilize natural gas, flaring is employed to dispose of this associated
gas. This practice has impoverished the communities where it is
practiced, with attendant environmental, economic and health
challenges. This paper discusses the adverse environmental and
health implication associated with the practice, the role of
Government, Policy makers, Oil companies and the Local
communities aimed at bring this inhuman practice to a prompt end.
Abstract: In July 2012, an indoor/outdoor monitoring
programme was undertaken in two university sports facilities: a
fronton and a gymnasium. Comfort parameters (temperature, relative
humidity, CO and CO2) and total volatile organic compounds
(VOCs) were continuously monitored. Concentrations of NO2,
carbonyl compounds and individual VOCs were obtained. Low
volume samplers were used to collect particulate matter (PM10). The
minimum ventilation rates stipulated for acceptable indoor air quality
were observed in both sports facilities. It was found that cleaning
activities may have a large influence on the VOC levels. Acrolein
was one of the most abundant carbonyl compounds, showing
concentrations above the recommended limit. Formaldehyde was
detected at levels lower than those commonly reported for other
indoor environments. The PM10 concentrations obtained during the
occupancy periods ranged between 38 and 43μgm-3 in the fronton and
from 154 to 198μgm-3 in the gymnasium.
Abstract: The present models and simulation algorithms of intracellular stochastic kinetics are usually based on the premise that diffusion is so fast that the concentrations of all the involved species are homogeneous in space. However, recents experimental measurements of intracellular diffusion constants indicate that the assumption of a homogeneous well-stirred cytosol is not necessarily valid even for small prokaryotic cells. In this work a mathematical treatment of diffusion that can be incorporated in a stochastic algorithm simulating the dynamics of a reaction-diffusion system is presented. The movement of a molecule A from a region i to a region j of the space is represented as a first order reaction Ai k- ! Aj , where the rate constant k depends on the diffusion coefficient. The diffusion coefficients are modeled as function of the local concentration of the solutes, their intrinsic viscosities, their frictional coefficients and the temperature of the system. The stochastic time evolution of the system is given by the occurrence of diffusion events and chemical reaction events. At each time step an event (reaction or diffusion) is selected from a probability distribution of waiting times determined by the intrinsic reaction kinetics and diffusion dynamics. To demonstrate the method the simulation results of the reaction-diffusion system of chaperoneassisted protein folding in cytoplasm are shown.
Abstract: Application of nanoparticles as additives in membrane
synthesis for improving the resistance of membranes against fouling
has triggered recent interest in new membrane types. However, most
nanoparticle-enhanced membranes suffer from the tradeoff between
permeability and selectivity. In this study, nano-WS2 was explored as
the additive in membrane synthesis by non-solvent induced phase
separation. Blended PES-WS2 flat-sheet membranes with the
incorporation of ultra-low concentrations of nanoparticles (from 0.025
to 0.25%, WS2/PES ratio) were manufactured and investigated in
terms of permeability, fouling resistance and solute rejection.
Remarkably, a significant enhancement in the permeability was
observed as a result of the incorporation of ultra-low fractions of
nano-WS2 to the membrane structure. Optimal permeability values
were obtained for modified membranes with 0.10%
nanoparticle/polymer concentration ratios. Furthermore, fouling
resistance and solute rejection were significantly improved by the
incorporation of nanoparticles into the membrane matrix. Specifically,
fouling resistance of modified membrane can increase by around 50%.
Abstract: Uterine and oviducal fluids are necessary for
capacitation of the spermatozoa and early embryonic development.
The aim of the present study was to determine the effects of estrous
cycle phases (follicular and luteal) on some biological parameters
(enzymes, electrolytes and total proteins) in uterine and oviducal
secretions of ewes. Oviducal and uterine fluids were collected,
diluted and centrifuged. According to our results, concentrations of
GPT, G6PDH, total proteins, K and Na were significantly (P
Abstract: Two short sediment cores collected from mangrove
areas of Manori and Thane creeks along Mumbai coast were analysed
for sediment composition and metals (Fe, Mn, Cu, Pb, Co, Ni, Zn, Cr
and V). The statistical analysis of Pearson correlation matrix proved
that there is a significant relationship between metal concentration
and finer grain size in Manori creek while poor correlation was
observed in Thane creek. Based on the enrichment factor, the present
metal to background metal ratios clearly reflected maximum
enrichment of Cu and Pb in Manori creek and Mn in Thane creek.
Geoaccumulation index calculated indicate that the study area is
unpolluted with respect to Fe, Mn, Co, Ni, Zn and Cr in both the
cores while moderately polluted with Cu and Pb in Manori creek.
Based on contamination degree, both the core sediments were found
to be considerably contaminated with metals.
Abstract: Intravitreal injection (IVI) is the most common treatment for eye posterior segment diseases such as endopthalmitis, retinitis, age-related macular degeneration, diabetic retinopathy, uveitis, and retinal detachment. Most of the drugs used to treat vitreoretinal diseases, have a narrow concentration range in which they are effective, and may be toxic at higher concentrations. Therefore, it is critical to know the drug distribution within the eye following intravitreal injection. Having knowledge of drug distribution, ophthalmologists can decide on drug injection frequency while minimizing damage to tissues. The goal of this study was to develop a computer model to predict intraocular concentrations and pharmacokinetics of intravitreally injected drugs. A finite volume model was created to predict distribution of two drugs with different physiochemical properties in the rabbit eye. The model parameters were obtained from literature review. To validate this numeric model, the in vivo data of spatial concentration profile from the lens to the retina were compared with the numeric data. The difference was less than 5% between the numerical and experimental data. This validation provides strong support for the numerical methodology and associated assumptions of the current study.
Abstract: The rheological properties, structure and potential synergistic interactions of whey proteins (1-6%) and inulin (20%) in mixed gels in the presence of CaCl2 was the aim of this study. Whey proteins have a strong influence on inulin gel formation. At low concentrations (2%) whey proteins did not impair in inulin gel formation. At higher concentration (4%) whey proteins impaired inulin gelation and inulin impaired the formation of a Ca2+-induced whey protein network. The presence of whey proteins at a level allowing for protein gel network formation (6%) significantly increased the rheological parameters values of the gels. SEM micrographs showed that whey protein structure was coated by inulin moieties which could make the mixed gels firmer. The protein surface hydrophobicity measurements did not exclude synergistic interactions between inulin and whey proteins, however. The use of an electrophoretic technique did not show any stable inulin-whey protein complexes.