Abstract: Coal fly ash (CFA) generated by coal-based thermal
power plants is mainly composed of some oxides having high
crystallinity, like quartz and mullite. In this study, the effect of CFA
crystallinity toward lead adsorption capacity was investigated. To get
solid with various crystallinity, the solution of sodium hydroxide
(NaOH) of 1-7 M was used to treat CFA at various temperature and
reflux time. Furthermore, to evaluate the effect of NaOH-treated CFA
with respect to adsorption capacity, the treated CFA were examine as
adsorbent for removing lead in the solution. The result shows that
using NaOH to treat CFA causes crystallinity of quartz and mullite
decrease. At higher NaOH concentration (>3M), in addition the
damage of quartz and mullite crystallinity is followed by crystal
formation called hydroxysodalite. The lower crystalllinity, the higher
adsorption capacity.
Abstract: Coal fly ash (CFA) generated by coal-based thermal
power plants is mainly composed of quartz, mullite, and unburned
carbon. In this study, the effect of unburned carbon on CFA toward
its adsorption capacity was investigated. CFA with various carbon
content was obtained by refluxing it with sulfuric acid having various
concentration at various temperature and reflux time, by heating at
400-800°C, and by sieving into 100-mesh in particle size. To
evaluate the effect of unburned carbon on CFA toward its adsorption
capacity, adsorption of methyl violet solution with treated CFA was
carried out. The research shows that unburned carbon leads to
adsorption capacity decrease. The highest adsorption capacity of
treated CFA was found 5.73 x 10-4mol.g-1.
Abstract: To reduce the carbon dioxide emission into the
atmosphere, adsorption is believed to be one of the most attractive
methods for post-combustion treatment of flue gas. In this work,
activated carbon (AC) was modified by polyethylenimine (PEI) via
impregnation in order to enhance CO2 adsorption capacity. The
adsorbents were produced at 0.04, 0.16, 0.22, 0.25, and 0.28 wt%
PEI/AC. The adsorption was carried out at a temperature range from
30 °C to 75 °C and five different gas pressures up to 1 atm. TG-DTA,
FT-IR, UV-visible spectrometer, and BET were used to characterize
the adsorbents. Effects of PEI loading on the AC for the CO2
adsorption were investigated. Effectiveness of the adsorbents on the
CO2 adsorption including CO2 adsorption capacity and adsorption
temperature was also investigated. Adsorption capacities of CO2 were
enhanced with the increase in the amount of PEI from 0.04 to 0.22
wt% PEI before the capacities decreased onwards from0.25 wt% PEI
at 30 °C. The 0.22 wt% PEI/AC showed higher adsorption capacity
than the AC for adsorption at 50 °C to 75 °C.