The Effect of Unburned Carbon on Coal Fly Ash toward its Adsorption Capacity for Methyl Violet

Coal fly ash (CFA) generated by coal-based thermal power plants is mainly composed of quartz, mullite, and unburned carbon. In this study, the effect of unburned carbon on CFA toward its adsorption capacity was investigated. CFA with various carbon content was obtained by refluxing it with sulfuric acid having various concentration at various temperature and reflux time, by heating at 400-800°C, and by sieving into 100-mesh in particle size. To evaluate the effect of unburned carbon on CFA toward its adsorption capacity, adsorption of methyl violet solution with treated CFA was carried out. The research shows that unburned carbon leads to adsorption capacity decrease. The highest adsorption capacity of treated CFA was found 5.73 x 10-4mol.g-1.




References:
[1] J.A. Hefne, W.K. Mekhemer, N.M. Alandis, O.A. Aldayel, T. Alajyan,
"Kinetic and Thermodynamic study of the Adsorption of Pb(II) from
Aqueous solution to The Natural and Treated Bentonite", International
Journal of Physical Sciences, vol. 3, pp. 281-288, 2008.
[2] J.Y. Hwang, X. Sun, Z. Li, "Unburned Carbon from Fly Ash for
Mercury Adsorption : I. Separation and Characterization of Unburned
Carbon", Journal of Minerals and Materials Characterization &
Engineering, vol 1, no. 1, pp. 39-60, 2002.
[3] M. Dogan, Y. Ozdemir, M. Alkan, "Adsorption Kinetics and Mechanism
of Cationic Methyl Violet and Methylene Blue Dyes onto Sepiolite",
Dyes and Pigments, vol.75, pp. 701-713, 2007.
[4] P. Ricou, V. Hequet, I. Lecuyer, P. Le Cloirec, "Removal of Cu2+ and
Zn2+ in Aqueous Solutions by Sorption onto Fly Ash and Fly Ash
Mixtures (Published Conference Proceedings style)," in Proc.
International Ash Utilization Symposium, University of Kentucky,
1999.
[5] Sukandarrumidi, Batubara dan Pemanfaatannya (Book style).
Yogyakarta : Gadjah Mada University Press, 2006.
[6] Y.S. Ho, G. McKay, "Batch Lead (II) Removal from Aqueous Solution
by Peat : Equilibrium and Kinetics", Trans IChemE, vol. 77 part B, pp.
165-173, 1999.
[7] Y.S. Ho, "Review of Second-Order Models for Adsorption Systems,"
Journal of Hazardous Materials, B136, pp. 681-689, 2006.
[8] Y.S. Al-Degs, M.I. El-Barghouthi, A.H. El-Sheikh, G.M. Walker,
"Effect of Solution pH, Ionic Strength, and Temperature on Adsorption
Behaviour of Reactive Dyes on Activated Carbon", Dyes and Pigments,
vol.77,pp.16-23, 2008.