Abstract: Xanthan gum (XG) an eco-friendly biopolymer has been recently explicitly investigated for ground improvement approaches. Rheological behavior of this additive strongly depends on electrochemical condition such as pH, ionic strength and also its content in aqueous solution. So, the effects of these factors have been studied in this paper considering various XG contents as 0.25, 0.5, 1, and 2% of water. Moreover, adjusting pH values such as 3, 5, 7 and 9 in addition to increasing ionic strength to 0.1 and 0.2 in the molar scale has covered a practical range of electrochemical condition. The viscosity of grouts shows an apparent upward trend with an increase in ionic strength and XG content. Also, pH affects the polymerization as much as other parameters. As a result, XG behavior is severely influenced by electrochemical settings
Abstract: The rapid industrialisation and population growth have led to a steady fall in freshwater supplies worldwide. As a result, water systems are affected by modern methods upon use due to secondary contamination. The application of novel adsorbents derived from natural polymer holds a great promise in addressing challenges in water treatment. In this study, the UV irradiation technique was used to prepare acrylamide (AAm) monomer, and acrylic acid (AA) monomer grafted xanthan gum (XG) copolymer. Furthermore, the factors affecting rhodamine B (RhB) adsorption from aqueous media, such as pH, dosage, concentration, and time were also investigated. The FTIR results confirmed the formation of graft copolymer by the strong vibrational bands at 1709 cm-1 and 1612 cm-1 for AA and AAm, respectively. Additionally, more irregular, porous and wrinkled surface observed from SEM of XG-g-AAm/AA indicated copolymerization interaction of monomers. The optimum conditions for removing RhB dye with a maximum adsorption capacity of 313 mg/g at 25 0C from aqueous solution were pH approximately 5, initial dye concentration = 200 ppm, adsorbent dose = 30 mg. Also, the detailed investigation of the isothermal and adsorption kinetics of RhB from aqueous solution showed that the adsorption of the dye followed a Freundlich model (R2 = 0.96333) and pseudo-second-order kinetics. The results further indicated that this absorbent based on XG had the universality to remove dye through the mechanism of chemical adsorption. The outstanding adsorption potential of the grafted copolymer could be used to remove cationic dyes from aqueous solution as a low-cost product.
Abstract: The performance of airlift bioreactors are closely related with their geometry, especially the gas-liquid separator design. In this study, the influence of the gas-liquid separator geometry on oxygen transfer and gas hold-up was evaluated in 10-L concentric-tube airlift bioreactor operating with distilled water and xanthan gum solution. The specific airflow rate (ɸAIR) exhibited the higher effect on the oxygen transfer coefficient (kLa) for both fluids. While the gas-liquid separator openness angle (α) and liquid volume fraction on the gas-liquid separator (VGLS) have presented opposite effects on oxygen mass transfer, they affected negatively the global gas hold-up of distilled water system. The best degassing zone geometry corresponded to a 90° openness angle with 10% of the liquid on it.
Abstract: Interaction effects of xanthan gum (XG), carboxymethyl
cellulose (CMC), and locust bean gum (LBG) on the flow properties
of oil-in-water emulsions were investigated by a mixture design
experiment. Blends of XG, CMC and LBG were prepared according
to an augmented simplex-centroid mixture design (10 points) and used
at 0.5% (wt/wt) in the emulsion formulations. An appropriate
mathematical model was fitted to express each response as a function
of the proportions of the blend components that are able to
empirically predict the response to any blend of combination of the
components. The synergistic interaction effect of the ternary
XG:CMC:LBG blends at approximately 33-67% XG levels was
shown to be much stronger than that of the binary XG:LBG blend at
50% XG level (p < 0.05). Nevertheless, an antagonistic interaction
effect became significant as CMC level in blends was more than 33%
(p < 0.05). Yield stress and apparent viscosity (at 10 s-1) responses
were successfully fitted with a special quartic model while flow
behaviour index and consistency coefficient were fitted with a full
quartic model (R2
adjusted ≥ 0.90). This study found that a mixture
design approach could serve as a valuable tool in better elucidating
and predicting the interaction effects beyond the conventional twocomponent
blends.
Abstract: Xanthan gum is one of the major commercial
biopolymers. Due to its excellent rheological properties xanthan gum
is used in many applications, mainly in food industry. Commercial
production of xanthan gum uses glucose as the carbon substrate;
consequently the price of xanthan production is high. One of the
ways to decrease xanthan price, is using cheaper substrate like
agricultural wastes. Iran is one of the biggest date producer countries.
However approximately 50% of date production is wasted annually.
The goal of this study is to produce xanthan gum from waste date
using Xanthomonas campestris PTCC1473 by submerged
fermentation. In this study the effect of three variables including
phosphor and nitrogen amount and agitation rate in three levels using
response surface methodology (RSM) has been studied. Results
achieved from statistical analysis Design Expert 7.0.0 software
showed that xanthan increased with increasing level of phosphor.
Low level of nitrogen leaded to higher xanthan production. Xanthan
amount, increasing agitation had positive influence. The statistical
model identified the optimum conditions nitrogen amount=3.15g/l,
phosphor amount=5.03 g/l and agitation=394.8 rpm for xanthan. To
model validation, experiments in optimum conditions for xanthan
gum were carried out. The mean of result for xanthan was 6.72±0.26.
The result was closed to the predicted value by using RSM.
Abstract: Xanthan gum is a microbial polysaccharide of great
commercial significance. The purpose of this study was to select the
optimum fermentation time for xanthan gum production by
Xanthomonas campestris (NRRL-B-1459) using 10% sugar beet
molasses as a carbon source. The pre-heating of sugar beet molasses
and the supplementation of the medium were investigated in order to
improve xanthan gum production. Maximum xanthan gum
production in fermentation media (9.02 g/l) was observed after 4 days
shaking incubation at 25°C and 240 rpm agitation speed. A solution
of 10% sucrose was used as a control medium. Results indicated that
the optimum period for xanthan gum production in this condition was
4 days.