Abstract: The removal vanadium from aqueous solution using natural exchanger was investigated. The effects of pH, contact time and exchanger dose were studied at ambient temperature (25 0C ± 2 0C). The equilibrium process was described by the Langmuir isotherm model with adsorption capacity for vanadium. The natural exchanger i.e. tamarindus seeds powder was treated with formaldehyde and sulpuric acid to increase the adsorptivity of metals. The maximum exchange level was attained as 80.1% at pH 3 with exchanger dose 5 g and contact time 60 min. Method is applied for removal of vanadium from industrial effluents.
Abstract: Packaging for vanadium redox flow battery is one of the key elements for successful implementation of flow battery in the electrical energy storage system. Usually the bulky battery size and low energy densities make this technology not available for mobility application. ThereforeRFB with improved packaging size and energy capacity are highly desirable. This paper focuses on the study of packaging improvement for unit cell V-RFB to the application on Series Hybrid Electric Vehicle. Two different designs of 25cm2 and 100cm2 unit cell V-RFB at same current density are used for the sample in this investigation. Further suggestions on packaging improvement are highlighted.
Abstract: Low oxygen content vanadium powder was
prepared by hydrogenation dehydrogenization (HDH). The
effect of purification treatment on hydrogen absorption kinetics
of dendritic vanadium was tested, and the effects of milling
technique on powder yield and grain size were studied. The
crystal phase, oxygen and nitrgen content, and grain size of
prepared powder were characterized and analyzed by X-ray
diffraction (XRD), oxygen and nitrogen analyzer and grain size
analyzer. The results show that the alkaline cleaning can
improve the hydrogen absorption of vanadium. The yield of
vanadium hydride powder can reach as high as 90% by 4h
ball-milling, The resultant product also have an oxygen content
less than 600μg/g, and the grain size is smaller than 37μm.
Meanwhile, the XRD results show that the phase of hydride
vanadium powder is mainly VH0.81. After a hydrogen
desorption treatment in vacuum at 700Ôäâ, the phase of the
powder converts into V and a little of V2H.
Abstract: A new supported liquid membrane (SLM) system for
the selective transport of VO2
+ ions was prepared in this present
work. The SLM was a thin porous polyvinylidene difluoride
(PVDF) membrane soaked with Di-(2-ethylhexyl) phosphoric acid
(D2EHPA) as mobile carrier in Xylene as organic solvent.
D2EHPA acts as a highly selective carrier for the uphill transport of
VO2
+ ions through the SLM. The transport of VO2
+ ions reached to
64%. In the presence of P2O7-2 ion as suitable masking agent in the
feed solution, the interfering effects of other cations were eliminated.