Abstract: Many sustainable approaches to generate electric energy have emerged in the last few decades; one of them is through solar cells. Yet, this also has the disadvantage of highly polluting inorganic semiconductor manufacturing processes. Therefore, the use of molecular semiconductors must be considered. In this work, allene compounds C24H26O4 and C24H26O5 were used as dopants to manufacture semiconductor films based on PbPc by high-vacuum evaporation technique. IR spectroscopy was carried out to determine the phase and any significant chemical changes which may occur during the thermal evaporation. According to UV-visible spectroscopy and Tauc’s model, the deposition process generated thin films with an activation energy range of 1.47 eV to 1.55 eV for direct transitions and 1.29 eV to 1.33 eV for indirect transitions. These values place the manufactured films within the range of low bandgap semiconductors. The flexible devices were manufactured: polyethylene terephthalate (PET), Indium tin oxide (ITO)/organic semiconductor/Cubic Close Packed (CCP). The characterization of the devices was carried out by evaluating electrical conductivity using the four-probe collinear method. I-V curves were obtained under different lighting conditions at room temperature. OS1 (PbPc/C24H26O4) showed an Ohmic behavior, while OS2 (PbPc/C24H26O5) reached higher current values at lower voltages. The results obtained show that the semiconductor devices doped with allene compounds can be used in the manufacture of optoelectronic devices.
Abstract: The voltage/current characteristics and the effect of
NO2 gas on the electrical conductivity of a PbPc gas sensor array is
investigated. The gas sensor is manufactured using vacuum
deposition of gold electrodes on sapphire substrate with the leadphathalocyanine
vacuum sublimed on the top of the gold electrodes.
Two versions of the PbPc gas sensor array are investigated. The
tested types differ in the gap sizes between the deposited gold
electrodes. The sensors are tested at different temperatures to account
for conductivity changes as the molecular adsorption/desorption rate
is affected by heat. The obtained results found to be encouraging as
the sensors shoed stability and sensitivity towards low concentration
of applied NO2 gas.