Abstract: Useful lifetime evaluation of chevron rubber spring
was very important in design procedure to assure the safety and
reliability. It is, therefore, necessary to establish a suitable criterion
for the replacement period of chevron rubber spring. In this study, we
performed characteristic analysis and useful lifetime prediction of
chevron rubber spring. Rubber material coefficient was obtained by
curve fittings of uniaxial tension equibiaxial tension and pure shear
test. Computer simulation was executed to predict and evaluate the
load capacity and stiffness for chevron rubber spring. In order to
useful lifetime prediction of rubber material, we carried out the
compression set with heat aging test in an oven at the temperature
ranging from 50°C to 100°C during a period 180 days. By using the
Arrhenius plot, several useful lifetime prediction equations for rubber
material was proposed.
Abstract: Useful lifetime evaluation of railpads were very important in design procedure to assure the safety and reliability. It is, therefore, necessary to establish a suitable criterion for the replacement period of rail pads. In this study, we performed properties and accelerated heat aging tests of rail pads considering degradation factors and all environmental conditions including operation, and then derived a lifetime prediction equation according to changes in hardness, thickness, and static spring constants in the Arrhenius plot to establish how to estimate the aging of rail pads. With the useful lifetime prediction equation, the lifetime of e-clip pads was 2.5 years when the change in hardness was 10% at 25°C; and that of f-clip pads was 1.7 years. When the change in thickness was 10%, the lifetime of e-clip pads and f-clip pads is 2.6 years respectively. The results obtained in this study to estimate the useful lifetime of rail pads for high speed trains can be used for determining the maintenance and replacement schedule for rail pads.
Abstract: Ionic liquids are well known as green solvents, reaction media and catalysis. Here, three different sulfonic acid functional ionic liquids prepared in the laboratory are used as catalysts in alkylation of p-cresol with tert-butyl alcohol. The kinetics on each of the catalysts was compared and a kinetic model was developed based on the product distribution over these catalysts. The kinetic parameters were estimated using Marquadt's algorithm to minimize the error function. The Arrhenius plots show a curvature which is best interpreted by the extended Arrhenius equation.