Abstract: The work on indigenous binders in this paper focused on the following indigenous raw materials: red clay, red lava and pumice (as primary aluminosilicate precursors), wood ash and gypsum (as supplementary minerals), and sodium sulfate and lime (as alkali activators). The experimental methods used for evaluation of these indigenous raw materials included laser granulometry, x-ray fluorescence (XRF) spectroscopy, and chemical reactivity. Formulations were devised for transforming these raw materials into alkali aluminosilicate-based hydraulic cements. These formulations were processed into hydraulic cements via simple heating and milling actions to render thermal activation, mechanochemical and size reduction effects. The resulting hydraulic cements were subjected to laser granulometry, heat of hydration and reactivity tests. These cements were also used to prepare mortar mixtures, which were evaluated via performance of compressive strength tests. The measured values of strength were correlated with the reactivity, size distribution and microstructural features of raw materials. Some of the indigenous hydraulic cements produced in this reporting period yielded viable levels of compressive strength. The correlation trends established in this work are being evaluated for development of simple and thorough methods of qualifying indigenous raw materials for use in production of indigenous hydraulic cements.
Abstract: The main objective of the study is focused in
producing slag based geopolymer concrete obtained with the addition
of alkali activator. Test results indicated that the reaction of silicates
in slag is based on the reaction potential of sodium hydroxide and the
formation of alumino-silicates. The study also comprises on the
evaluation of the efficiency of polymer reaction in terms of the
strength gain properties for different geopolymer mixtures.
Geopolymer mixture proportions were designed for different binder
to total aggregate ratio (0.3 & 0.45) and fine to coarse aggregate ratio
(0.4 & 0.8). Geopolymer concrete specimens casted with normal
curing conditions reported a maximum 28 days compressive strength
of 54.75 MPa. The addition of glued steel fibres at 1.0% Vf in
geopolymer concrete showed reasonable improvements on the
compressive strength, split tensile strength and flexural properties of
different geopolymer mixtures. Further, comparative assessment was
made for different geopolymer mixtures and the reinforcing effects of
steel fibres were investigated in different concrete matrix.