Abstract: A new, simple and highly sensitive kinetic
spectrophotometric method was developed for the determination of
trace amounts of Ru(III) in the range of 0.06-20 ng/ml .The method
is based on the inhibitory effect of ruthenium(III) on the oxidation of
Rhodamine B by bromate in acidic and micellar medium. The
reaction was monitored spectrophotometrically by measuring the
decreasing in absorbance of Rhodamine B at 554 nm with a fixedtime
method..The limit of detection is 0.04 ng/ml Ru(III).The relative
standard deviation of 5 and 10 ng/ml Ru(III) was 2.3 and 2.7 %,
respectively. The method was applied to the determination of
ruthenium in real water samples